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Thermoelectricity is a well-known phenomenon that enables the conversion of heat into electric energy without moving parts. Its exploitation has been widely considered to contribute to the increasing need for energy along with the concerns about the environmental impact of traditional fossil energy sources. In the last few years, significant improvements in the performance of thermoelectric materials have been achieved through chemical doping, solid solution formation, and nanoengineering approaches. Furthermore, the feasibility of flexible, stretchable, and conformable thermoelectric harvesters has been demonstrated and has attracted the interest of an audience from many different fields. However, the path for practical applications of thermoelectrics is still a long one. This Special Issue of Materials intends to bridge the gap between materials science and applications of thermoelectric materials. Many topics are welcome: new thermoelectric compounds; the correlation between material structure and thermoelectric properties; bulk thermoelectric ceramics, oxides, and chalcogenides; bulk thermoelectric alloys and intermetallics; organic and polymeric thermoelectrics; thermoelectric thin films, multilayers, and nanocomposites; theory and modeling; thermal transport and thermal conductivity; applications and devices based on thermoelectric materials; standardization and metrology; and more.

Technology: general issues --- History of engineering & technology --- Materials science --- thermoelectricity --- skutterudites --- crystal structure --- powder x-ray diffraction --- thermal conductivity --- calcium cobaltite --- TE performance --- electrical properties --- composite --- redox tuning --- thermoelectric materials --- joining --- skutterudite alloy --- Co-Mo metallization layer --- Seebeck coefficient --- thin film --- oxides --- copper tin sulfide --- Cu2SnS3 --- CTS --- thermal stability --- chalcogenide --- material production --- porosity --- porous thermoelectric materials --- thermoelectricity --- skutterudites --- crystal structure --- powder x-ray diffraction --- thermal conductivity --- calcium cobaltite --- TE performance --- electrical properties --- composite --- redox tuning --- thermoelectric materials --- joining --- skutterudite alloy --- Co-Mo metallization layer --- Seebeck coefficient --- thin film --- oxides --- copper tin sulfide --- Cu2SnS3 --- CTS --- thermal stability --- chalcogenide --- material production --- porosity --- porous thermoelectric materials

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Thermoelectricity is a well-known phenomenon that enables the conversion of heat into electric energy without moving parts. Its exploitation has been widely considered to contribute to the increasing need for energy along with the concerns about the environmental impact of traditional fossil energy sources. In the last few years, significant improvements in the performance of thermoelectric materials have been achieved through chemical doping, solid solution formation, and nanoengineering approaches. Furthermore, the feasibility of flexible, stretchable, and conformable thermoelectric harvesters has been demonstrated and has attracted the interest of an audience from many different fields. However, the path for practical applications of thermoelectrics is still a long one. This Special Issue of Materials intends to bridge the gap between materials science and applications of thermoelectric materials. Many topics are welcome: new thermoelectric compounds; the correlation between material structure and thermoelectric properties; bulk thermoelectric ceramics, oxides, and chalcogenides; bulk thermoelectric alloys and intermetallics; organic and polymeric thermoelectrics; thermoelectric thin films, multilayers, and nanocomposites; theory and modeling; thermal transport and thermal conductivity; applications and devices based on thermoelectric materials; standardization and metrology; and more.

thermoelectricity --- skutterudites --- crystal structure --- powder x-ray diffraction --- thermal conductivity --- calcium cobaltite --- TE performance --- electrical properties --- composite --- redox tuning --- thermoelectric materials --- joining --- skutterudite alloy --- Co-Mo metallization layer --- Seebeck coefficient --- thin film --- oxides --- copper tin sulfide --- Cu2SnS3 --- CTS --- thermal stability --- chalcogenide --- material production --- porosity --- porous thermoelectric materials --- n/a

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This Special Issue deals with the fascinating material class of nanocomposites consisting of extremely small particles (nanoparticles) which are embedded in polymers. Such materials are of paramount interest in various disciplines, especially chemistry, physics, biomedicine and materials science. Due to the diversity of the components of nanocomposites, they provide a broad spectrum of material properties and applications. The versatility of nanocomposites is indeed reflected by the research covered in this Special Issue. The field of nanocomposites includes innovative science and a source of inspiration for currently relevant economic topics as well as for envisaged technologies of the future. Indeed, this volume alludes to strategies for the preparation of nanocomposites and possibilities for a variety of applications, such as catalytic reactions, gas barriers, high refractive index materials, corrosion protection, electromagnetic inference (EMI) shielding, lithium ion batteries, tissue engineering and plastic surgery.

broadband dielectric spectroscopy --- dielectric strength --- loss factor --- magnesium oxide --- nanocomposite --- relative permittivity --- surface functionalization --- voltage response --- lithium-ion battery --- ionic-liquid-based separator --- hot-pressing --- inorganic nanoparticle --- fractal cluster --- nanostructures --- polymer matrix composites (PMCs) --- mechanical properties --- thermal properties --- elastomeric foam --- plastic reconstruction --- hydroxyapatite/polyurethane --- nanosized dispersion --- viscoelasticity --- biocompatibility --- nanoreactor --- catalyst confinement --- Flash Nanoprecipitation --- diffusion --- poly(vinyl alcohol) --- nanofiller --- film --- catalytic durability --- nanoparticle --- supported catalyst --- radical reactions --- platinum (Pt) --- H2O2 decomposition --- contact lens cleaning --- polymer brushes --- nanoparticles --- SPION --- thin magnetic films --- ATRP --- hybrid polymer/inorganic composites --- titanium oxide --- hybrid material --- anatase --- organic-inorganic hybrid --- high refractive index material --- MXene --- oxidized carbon nanotube (CNTO) --- nanoparticle decoration --- functionalization --- electromagnetic interference (EMI) shielding --- anti-corrosion --- tin sulfide (SnS) --- molybdenum disulfide (MoS2) --- electrochemical test --- composite coating --- nanocomposites --- surface-functionalization --- secondary dispersion --- hot-stretching --- metal–polymer interface --- multilayer --- structure–function correlation --- indirect band gap --- GISAXS --- GIWAXS --- UV-Vis

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The present collection of articles focuses on the mechanical strength properties at micro- and nanoscale dimensions of body-centered cubic, face-centered cubic and hexagonal close-packed crystal structures. The advent of micro-pillar test specimens is shown to provide a new dimensional scale for the investigation of crystal deformation properties. The ultra-small dimensional scale at which these properties are measured is shown to approach the atomic-scale level at which model dislocation mechanics descriptions of crystal slip and deformation twinning behaviors are proposed to be operative, including the achievement of atomic force microscopic measurements of dislocation pile-up interactions with crystal grain boundaries or with hard surface coatings. A special advantage of engineering designs made at such small crystal and polycrystalline dimensions is the achievement of an approximate order-of-magnitude increase in mechanical strength levels. Reasonable extrapolation of macro-scale continuum mechanics descriptions of crystal strength properties at micro- to nano-indentation hardness measurements are demonstrated, in addition to reports on persistent slip band observations and fatigue cracking behaviors. High-entropy alloy, superalloy and energetic crystal properties are reported along with descriptions of deformation rate sensitivities, grain boundary structures, nano-cutting, void nucleation/growth micromechanics and micro-composite electrical properties.

Technology: general issues --- crystal strength --- micro-crystals --- nano-crystals --- nano-polycrystals --- nano-wires --- whiskers --- pillars --- dislocations --- hardness --- crystal size dependencies --- fracture --- strain rate sensitivity --- temperature effect --- indentation size effect --- theoretical model --- nano-indentation --- crack growth --- dislocation models --- pile-ups --- kitagawa-takahashi diagram --- fracture mechanics --- internal stresses --- molecular dynamics simulations --- BCC Fe nanowires --- twin boundaries --- de-twinning --- micromechanical testing --- micro-pillar --- bi-crystal --- discrete dislocation pile-up --- grain boundary --- free surface --- anisotropic elasticity --- crystallographic slip --- molecular dynamics --- nanocutting --- iron --- cutting theory --- ab initio calculations --- hydrogen embrittlement --- cohesive strength --- multiaxial loading --- strain rate --- molecular dynamics simulation --- activation volume --- grain growth --- indentation creep --- size effect --- geometrically necessary dislocations --- FeCrAl --- micropillar --- dislocation --- strain hardening --- crystal plasticity simulations --- persistent slip band --- surface hard coating --- fatigue crack initiation --- fatigue --- cyclic deformation --- internal stress --- copper single crystal --- rafting behavior --- phase-field simulation --- crystal plasticity theory --- mechanical property --- ultrafine-grained materials --- intermetallic compounds --- B2 phase --- strain hardening behavior --- synchrotron radiation X-ray diffraction --- HMX --- elastic properties --- linear complexions --- strength --- lattice distortive transformations --- dislocation emission --- grain boundaries --- nanomaterials --- Hall-Petch relation --- metals and alloys --- interfacial delamination --- nucleation --- void formation --- cracking --- alloys --- nanocrystalline --- thermal stability --- IN718 alloy --- dislocation plasticity --- twinning --- miniaturised testing --- in situ electron microscopy --- magnesium --- anode --- tin sulfide --- lithium ion battery --- conversion reaction --- nanoflower --- rapid solidification --- compression --- crystal strength --- micro-crystals --- nano-crystals --- nano-polycrystals --- nano-wires --- whiskers --- pillars --- dislocations --- hardness --- crystal size dependencies --- fracture --- strain rate sensitivity --- temperature effect --- indentation size effect --- theoretical model --- nano-indentation --- crack growth --- dislocation models --- pile-ups --- kitagawa-takahashi diagram --- fracture mechanics --- internal stresses --- molecular dynamics simulations --- BCC Fe nanowires --- twin boundaries --- de-twinning --- micromechanical testing --- micro-pillar --- bi-crystal --- discrete dislocation pile-up --- grain boundary --- free surface --- anisotropic elasticity --- crystallographic slip --- molecular dynamics --- nanocutting --- iron --- cutting theory --- ab initio calculations --- hydrogen embrittlement --- cohesive strength --- multiaxial loading --- strain rate --- molecular dynamics simulation --- activation volume --- grain growth --- indentation creep --- size effect --- geometrically necessary dislocations --- FeCrAl --- micropillar --- dislocation --- strain hardening --- crystal plasticity simulations --- persistent slip band --- surface hard coating --- fatigue crack initiation --- fatigue --- cyclic deformation --- internal stress --- copper single crystal --- rafting behavior --- phase-field simulation --- crystal plasticity theory --- mechanical property --- ultrafine-grained materials --- intermetallic compounds --- B2 phase --- strain hardening behavior --- synchrotron radiation X-ray diffraction --- HMX --- elastic properties --- linear complexions --- strength --- lattice distortive transformations --- dislocation emission --- grain boundaries --- nanomaterials --- Hall-Petch relation --- metals and alloys --- interfacial delamination --- nucleation --- void formation --- cracking --- alloys --- nanocrystalline --- thermal stability --- IN718 alloy --- dislocation plasticity --- twinning --- miniaturised testing --- in situ electron microscopy --- magnesium --- anode --- tin sulfide --- lithium ion battery --- conversion reaction --- nanoflower --- rapid solidification --- compression

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The present collection of articles focuses on the mechanical strength properties at micro- and nanoscale dimensions of body-centered cubic, face-centered cubic and hexagonal close-packed crystal structures. The advent of micro-pillar test specimens is shown to provide a new dimensional scale for the investigation of crystal deformation properties. The ultra-small dimensional scale at which these properties are measured is shown to approach the atomic-scale level at which model dislocation mechanics descriptions of crystal slip and deformation twinning behaviors are proposed to be operative, including the achievement of atomic force microscopic measurements of dislocation pile-up interactions with crystal grain boundaries or with hard surface coatings. A special advantage of engineering designs made at such small crystal and polycrystalline dimensions is the achievement of an approximate order-of-magnitude increase in mechanical strength levels. Reasonable extrapolation of macro-scale continuum mechanics descriptions of crystal strength properties at micro- to nano-indentation hardness measurements are demonstrated, in addition to reports on persistent slip band observations and fatigue cracking behaviors. High-entropy alloy, superalloy and energetic crystal properties are reported along with descriptions of deformation rate sensitivities, grain boundary structures, nano-cutting, void nucleation/growth micromechanics and micro-composite electrical properties.

crystal strength --- micro-crystals --- nano-crystals --- nano-polycrystals --- nano-wires --- whiskers --- pillars --- dislocations --- hardness --- crystal size dependencies --- fracture --- strain rate sensitivity --- temperature effect --- indentation size effect --- theoretical model --- nano-indentation --- crack growth --- dislocation models --- pile-ups --- kitagawa-takahashi diagram --- fracture mechanics --- internal stresses --- molecular dynamics simulations --- BCC Fe nanowires --- twin boundaries --- de-twinning --- micromechanical testing --- micro-pillar --- bi-crystal --- discrete dislocation pile-up --- grain boundary --- free surface --- anisotropic elasticity --- crystallographic slip --- molecular dynamics --- nanocutting --- iron --- cutting theory --- ab initio calculations --- hydrogen embrittlement --- cohesive strength --- multiaxial loading --- strain rate --- molecular dynamics simulation --- activation volume --- grain growth --- indentation creep --- size effect --- geometrically necessary dislocations --- FeCrAl --- micropillar --- dislocation --- strain hardening --- crystal plasticity simulations --- persistent slip band --- surface hard coating --- fatigue crack initiation --- fatigue --- cyclic deformation --- internal stress --- copper single crystal --- rafting behavior --- phase-field simulation --- crystal plasticity theory --- mechanical property --- ultrafine-grained materials --- intermetallic compounds --- B2 phase --- strain hardening behavior --- synchrotron radiation X-ray diffraction --- HMX --- elastic properties --- linear complexions --- strength --- lattice distortive transformations --- dislocation emission --- grain boundaries --- nanomaterials --- Hall-Petch relation --- metals and alloys --- interfacial delamination --- nucleation --- void formation --- cracking --- alloys --- nanocrystalline --- thermal stability --- IN718 alloy --- dislocation plasticity --- twinning --- miniaturised testing --- in situ electron microscopy --- magnesium --- anode --- tin sulfide --- lithium ion battery --- conversion reaction --- nanoflower --- rapid solidification --- compression