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A collection of essential research articles and scientific reviews covering some of the most pertinent and topical areas of study that currently constitute Inorganic Chemistry in the early 21st century.
Research & information: general --- Chemistry --- Inorganic chemistry --- cyanoguanidine --- silver --- crystal structure --- chemical bonding --- CuII --- pyridine amides --- pyrazine amide --- amino benzamides --- EPR spectroscopy --- lanthanides --- Schiff base --- synthetic strategies --- single-molecule magnets --- Atomic Layer Deposition --- Ni catalyst --- reforming catalyst --- thermodynamics --- metallopharmaceuticals --- cancer stem cells --- copper --- bioinorganic chemistry --- medicinal inorganic chemistry --- reactive oxygen species --- metal-carbonyl complexes --- [FeFe]-hydrogenases --- density functional theory --- time-dependent DFT --- organometallic photochemistry --- crystalline borosilicate --- actinides --- supercritical hydrothermal synthesis --- waste forms --- thorium --- rhenium --- ruthenium --- metal–metal bonds --- uranium --- ceria --- hydrothermal --- catalysis --- nanomaterials --- crystallisation --- 4,2′:6′,4″-terpyridine --- 3,2′:6′,3″-terpyridine --- coordination polymer --- isomers --- lithium --- potassium --- Nacnac --- β-diketiminate --- tricyclohexylphenyl --- steric bulk --- silver complexes --- permanganates --- perchlorates --- perrhenate --- pyridine --- structure --- spectroscopy --- thermal behavior --- heterogenous catalyst --- metal–organic framework (MOF) --- olefin epoxidation --- carbon dioxide cycloaddition --- f-element --- lanthanide --- actinide --- multidentate ligand --- macrocycle --- ammonothermal synthesis --- fluoride --- aluminum --- speciation --- equilibria --- thermodynamic stability --- peptides --- multivariate linear regression --- poisoning effect of polar monomers --- Brookhart-type catalysts --- Zintl clusters --- X-ray crystallography --- Density Functional Theory --- n/a --- metal-metal bonds --- 4,2':6',4"-terpyridine --- 3,2':6',3"-terpyridine --- metal-organic framework (MOF)
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solar energy conversion --- n/a --- carboxylic acid --- organic salts --- 2?:6? --- Cerium --- drug delivery --- layered materials --- coordination polymer --- copper --- solid state NMR --- metal–organic frameworks --- synthesis --- coordination polymers --- in situ characterisation --- mechanochemistry --- phosphonic acids --- amorphous --- nickel(II) oxide --- heterogeneous catalysis --- phosphonic acid --- MOF --- porosity --- phosphonate ester --- proton conduction --- X-ray and electron diffraction --- gas sorption/separation --- metal phosphonate --- electron diffraction tomography --- ionic compounds --- dye-sensitized solar cell --- 2?-terpyridine --- dye --- 2 --- rechargeable batteries --- anchor --- defects --- p-type --- crystal structure --- diphosphinate --- zinc(II) --- metal phosphonates and phosphinates --- metal-organic frameworks
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Heterocycles feature widely in natural products, agrochemicals, pharmaceuticals and dyes, and their synthesis is of great interest to synthetic chemists in both academia and industry. The contributions of recent applications of new methodologies in C–H activation, photoredox chemistry, cross-coupling strategies, borrowing hydrogen catalysis, multicomponent and solvent-free reactions, regio- and stereoselective syntheses, as well as other new, attractive approaches for the construction of heterocyclic scaffolds are of great interest. This Special Issue is dedicated to featuring the latest research that is ongoing in the field of heterocyclic synthesis. It is expected that most submissions will focus on five- and six-membered oxygen and nitrogen-containing heterocycles, but structures incorporating other rings/heteroatoms will also be considered. Original research (communications, full papers and reviews) that discusses innovative methodologies for assembling heterocycles with potential application in materials, catalysis and medicine are therefore welcome.
Medicine --- amine nucleophiles --- alkynoic acids --- cascade reaction --- gold catalysis --- fused N-heterocycles --- solid-phase synthesis --- ketone --- traceless synthesis --- natural products --- enol ethers --- photocatalysis --- photoredox --- visible-light-induced catalysis --- photoredox cyclization --- organic dyes --- heterocycles --- dihydrocoumarins --- synthesis --- 3-trifluoroacetyl coumarins --- phenols --- antifungal activities --- terpyridines --- 3,2′:6′,3″-terpyridine --- cyclohexanol derivative --- condensation --- heterocyclic --- 1,2,3-triazol --- triazolylmethyl phosphinate --- triazolylmethyl phosphate --- copper-catalyzed azide-alkyne cycloaddition --- click reaction --- azides --- cinnolines --- triazoles --- CuAAC --- alkynes --- cycloalkynes --- Richter cyclization --- Suzuki coupling --- fluorescence --- cytotoxicity --- coumarin --- pyrazolo[3,4-b]pyridine --- silica sulfuric acid --- 2H-pyran --- valence isomerism --- 1-oxa-triene --- dienone --- oxa-electrocyclization --- Knoevenagel --- propargyl Claisen --- cycloisomerization --- asymmetric dimeric β-carboline --- acylhydrazone group --- cytotoxic --- antitumor --- structure–activity relationship --- γ-lactam --- pyrrolidones --- multicomponent reactions --- organocatalysis --- pyridine --- CF3CO-acetylenes --- 1,3-oxazines --- fluorinated heterocycles --- saturated oxygen heterocycles --- cyclic ethers --- total synthesis --- multicomponent reaction --- α-halohydrazones --- Staudinger reaction --- aza-Wittig --- 1H-imidazole-2(3H)-thione --- 2H-imidazo[2,1-b][1,3,4]thiadiazine --- purine --- nucleobase --- aromatic substitution --- arylation --- fluoroalcohol --- α-chloroglycinates --- 5-acylamino-1,3-thiazoles --- Hantzsch reaction --- TMSBr --- propargylic alcohols --- cascade cyclization --- 4-bromo quinolines --- synthesis of benzofurans --- intra-molecular approach --- inter-molecular approach --- n/a --- 3,2':6',3"-terpyridine --- structure-activity relationship
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Heterocycles feature widely in natural products, agrochemicals, pharmaceuticals and dyes, and their synthesis is of great interest to synthetic chemists in both academia and industry. The contributions of recent applications of new methodologies in C–H activation, photoredox chemistry, cross-coupling strategies, borrowing hydrogen catalysis, multicomponent and solvent-free reactions, regio- and stereoselective syntheses, as well as other new, attractive approaches for the construction of heterocyclic scaffolds are of great interest. This Special Issue is dedicated to featuring the latest research that is ongoing in the field of heterocyclic synthesis. It is expected that most submissions will focus on five- and six-membered oxygen and nitrogen-containing heterocycles, but structures incorporating other rings/heteroatoms will also be considered. Original research (communications, full papers and reviews) that discusses innovative methodologies for assembling heterocycles with potential application in materials, catalysis and medicine are therefore welcome.
amine nucleophiles --- alkynoic acids --- cascade reaction --- gold catalysis --- fused N-heterocycles --- solid-phase synthesis --- ketone --- traceless synthesis --- natural products --- enol ethers --- photocatalysis --- photoredox --- visible-light-induced catalysis --- photoredox cyclization --- organic dyes --- heterocycles --- dihydrocoumarins --- synthesis --- 3-trifluoroacetyl coumarins --- phenols --- antifungal activities --- terpyridines --- 3,2′:6′,3″-terpyridine --- cyclohexanol derivative --- condensation --- heterocyclic --- 1,2,3-triazol --- triazolylmethyl phosphinate --- triazolylmethyl phosphate --- copper-catalyzed azide-alkyne cycloaddition --- click reaction --- azides --- cinnolines --- triazoles --- CuAAC --- alkynes --- cycloalkynes --- Richter cyclization --- Suzuki coupling --- fluorescence --- cytotoxicity --- coumarin --- pyrazolo[3,4-b]pyridine --- silica sulfuric acid --- 2H-pyran --- valence isomerism --- 1-oxa-triene --- dienone --- oxa-electrocyclization --- Knoevenagel --- propargyl Claisen --- cycloisomerization --- asymmetric dimeric β-carboline --- acylhydrazone group --- cytotoxic --- antitumor --- structure–activity relationship --- γ-lactam --- pyrrolidones --- multicomponent reactions --- organocatalysis --- pyridine --- CF3CO-acetylenes --- 1,3-oxazines --- fluorinated heterocycles --- saturated oxygen heterocycles --- cyclic ethers --- total synthesis --- multicomponent reaction --- α-halohydrazones --- Staudinger reaction --- aza-Wittig --- 1H-imidazole-2(3H)-thione --- 2H-imidazo[2,1-b][1,3,4]thiadiazine --- purine --- nucleobase --- aromatic substitution --- arylation --- fluoroalcohol --- α-chloroglycinates --- 5-acylamino-1,3-thiazoles --- Hantzsch reaction --- TMSBr --- propargylic alcohols --- cascade cyclization --- 4-bromo quinolines --- synthesis of benzofurans --- intra-molecular approach --- inter-molecular approach --- n/a --- 3,2':6',3"-terpyridine --- structure-activity relationship
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Heterocycles feature widely in natural products, agrochemicals, pharmaceuticals and dyes, and their synthesis is of great interest to synthetic chemists in both academia and industry. The contributions of recent applications of new methodologies in C–H activation, photoredox chemistry, cross-coupling strategies, borrowing hydrogen catalysis, multicomponent and solvent-free reactions, regio- and stereoselective syntheses, as well as other new, attractive approaches for the construction of heterocyclic scaffolds are of great interest. This Special Issue is dedicated to featuring the latest research that is ongoing in the field of heterocyclic synthesis. It is expected that most submissions will focus on five- and six-membered oxygen and nitrogen-containing heterocycles, but structures incorporating other rings/heteroatoms will also be considered. Original research (communications, full papers and reviews) that discusses innovative methodologies for assembling heterocycles with potential application in materials, catalysis and medicine are therefore welcome.
Medicine --- amine nucleophiles --- alkynoic acids --- cascade reaction --- gold catalysis --- fused N-heterocycles --- solid-phase synthesis --- ketone --- traceless synthesis --- natural products --- enol ethers --- photocatalysis --- photoredox --- visible-light-induced catalysis --- photoredox cyclization --- organic dyes --- heterocycles --- dihydrocoumarins --- synthesis --- 3-trifluoroacetyl coumarins --- phenols --- antifungal activities --- terpyridines --- 3,2':6',3"-terpyridine --- cyclohexanol derivative --- condensation --- heterocyclic --- 1,2,3-triazol --- triazolylmethyl phosphinate --- triazolylmethyl phosphate --- copper-catalyzed azide-alkyne cycloaddition --- click reaction --- azides --- cinnolines --- triazoles --- CuAAC --- alkynes --- cycloalkynes --- Richter cyclization --- Suzuki coupling --- fluorescence --- cytotoxicity --- coumarin --- pyrazolo[3,4-b]pyridine --- silica sulfuric acid --- 2H-pyran --- valence isomerism --- 1-oxa-triene --- dienone --- oxa-electrocyclization --- Knoevenagel --- propargyl Claisen --- cycloisomerization --- asymmetric dimeric β-carboline --- acylhydrazone group --- cytotoxic --- antitumor --- structure-activity relationship --- γ-lactam --- pyrrolidones --- multicomponent reactions --- organocatalysis --- pyridine --- CF3CO-acetylenes --- 1,3-oxazines --- fluorinated heterocycles --- saturated oxygen heterocycles --- cyclic ethers --- total synthesis --- multicomponent reaction --- α-halohydrazones --- Staudinger reaction --- aza-Wittig --- 1H-imidazole-2(3H)-thione --- 2H-imidazo[2,1-b][1,3,4]thiadiazine --- purine --- nucleobase --- aromatic substitution --- arylation --- fluoroalcohol --- α-chloroglycinates --- 5-acylamino-1,3-thiazoles --- Hantzsch reaction --- TMSBr --- propargylic alcohols --- cascade cyclization --- 4-bromo quinolines --- synthesis of benzofurans --- intra-molecular approach --- inter-molecular approach --- amine nucleophiles --- alkynoic acids --- cascade reaction --- gold catalysis --- fused N-heterocycles --- solid-phase synthesis --- ketone --- traceless synthesis --- natural products --- enol ethers --- photocatalysis --- photoredox --- visible-light-induced catalysis --- photoredox cyclization --- organic dyes --- heterocycles --- dihydrocoumarins --- synthesis --- 3-trifluoroacetyl coumarins --- phenols --- antifungal activities --- terpyridines --- 3,2':6',3"-terpyridine --- cyclohexanol derivative --- condensation --- heterocyclic --- 1,2,3-triazol --- triazolylmethyl phosphinate --- triazolylmethyl phosphate --- copper-catalyzed azide-alkyne cycloaddition --- click reaction --- azides --- cinnolines --- triazoles --- CuAAC --- alkynes --- cycloalkynes --- Richter cyclization --- Suzuki coupling --- fluorescence --- cytotoxicity --- coumarin --- pyrazolo[3,4-b]pyridine --- silica sulfuric acid --- 2H-pyran --- valence isomerism --- 1-oxa-triene --- dienone --- oxa-electrocyclization --- Knoevenagel --- propargyl Claisen --- cycloisomerization --- asymmetric dimeric β-carboline --- acylhydrazone group --- cytotoxic --- antitumor --- structure-activity relationship --- γ-lactam --- pyrrolidones --- multicomponent reactions --- organocatalysis --- pyridine --- CF3CO-acetylenes --- 1,3-oxazines --- fluorinated heterocycles --- saturated oxygen heterocycles --- cyclic ethers --- total synthesis --- multicomponent reaction --- α-halohydrazones --- Staudinger reaction --- aza-Wittig --- 1H-imidazole-2(3H)-thione --- 2H-imidazo[2,1-b][1,3,4]thiadiazine --- purine --- nucleobase --- aromatic substitution --- arylation --- fluoroalcohol --- α-chloroglycinates --- 5-acylamino-1,3-thiazoles --- Hantzsch reaction --- TMSBr --- propargylic alcohols --- cascade cyclization --- 4-bromo quinolines --- synthesis of benzofurans --- intra-molecular approach --- inter-molecular approach
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The aim of this reprint is to highlight the progress and fundamental aspects for the synthesis, characterization, properties, and application of novel polymeric materials, as well as their copolymers, composites, and nanocomposites.
Plastics & polymers technology --- poly(lactic acid) --- epoxidized natural rubber --- polymer blend --- natural additives --- antioxidant --- polymer blending --- radiation crosslinking --- polyethylene --- polyurethane --- heat resistance --- mechanical property --- aramid fiber --- ballistic test --- failure mechanism --- cyclotriphosphazane --- flame retardancy --- dielectric properties --- azo compound --- liquid crystal --- structure–property relationship --- axial behavior --- geopolymer concrete (GC) --- ferrocement --- finite element analysis (FEA) --- polyacrylonitrile --- lignin --- electrospinning --- selective chemical dissolution --- porous nanofibers --- nanofibers --- soft template --- peat soil --- cement --- stabilization --- fly ash --- polypropylene fiber --- unconfined compressive strength (UCS) --- California bearing ratio (CBR) --- scanning electron microscopy (SEM) --- bio-based polyurethanes --- jatropha oil --- algae oil --- recovered palm oil --- epoxy composite --- green composite --- corn cob --- polycarbonates --- transesterification --- polycondensation --- polymer --- hydrogen --- hydrophobic --- sensing --- nanostructures --- palladium --- polymer composite --- fibre-prestressing --- residual stresses --- PCL–SBA-15 nanocomposites --- real-time variable-temperature synchrotron measurements --- confinement --- mechanical behavior --- nanoclay --- nanocomposites --- mechanical properties --- impact properties --- hardness --- polymer composites --- graphene quantum dots --- bioactive --- biomedical --- synthesis --- PVK --- hexylthiophene --- PANI --- nanocomposite --- photovoltaic cells --- DFT --- polyhydroxyalkanoates --- fibers --- biodegradability --- packaging --- patents --- poly(aminopropyl/phenyl)silsesquioxane --- thiol-ene --- kinetics --- activation energy --- polymer characterization --- viscoelasticity --- DMA --- solution blow spinning --- polyethylene oxide --- morphology --- materials characterization --- polymer dissolution --- kaolin flocculation --- aggregate resistance --- salinity --- flocculation kinetic --- shear rate --- thermoplastic starch --- silane --- foam --- carbon dioxide --- microcapsules --- dip coating --- encapsulation --- spectroscopy --- microscopy --- antibacterial silver --- polyaniline --- dodecylbenzene sulfonic acid --- γ-Al2O3 --- in situ polymerization --- core–shell nanocomposite --- polyphosphazene --- micro-nanospheres --- species-absorbing mechanisms --- hydrophobicity --- thermochemical --- PVDF --- alkali-grafting --- α-methyl styrene --- acrylonitrile --- proton exchange membrane --- block copolymers --- random copolymers --- catalytic membranes --- esterification --- isopropyl acetate --- bioinspired bottlebrush polymers --- aqueous boundary lubrication --- friction --- wear resistance --- supramolecular hydrogel --- acrylic acid --- maleic anhydride --- terpyridine --- coordination interaction --- thermoplastic polyurethanes --- surface free energy --- dithiol --- differential scanning calorimetry --- optical properties --- arsine --- ligands --- polypropylene --- catalyst --- degradation --- sol-gel process --- 3D network hybrid materials --- nanoparticles --- nanodispersity --- ionic liquids --- n/a --- structure-property relationship --- PCL-SBA-15 nanocomposites --- core-shell nanocomposite
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