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Organic Electronics is a rapidly evolving multidisciplinary research field at the interface between Organic Chemistry and Physics. Organic Electronics is based on the use of the unique optical and electrical properties of π-conjugated materials that range from small molecules to polymers. The wide activity of researchers in Organic Electronics is testament to the fact that its potential is huge and its list of potential applications almost endless. Application of these electronic and optoelectronic devices range from Organic Field Effect Transistors (OFETs) to Organic Light Emitting Diodes (OLEDs) and Organic Solar Cells (OSCs), sensors, etc. We invited a series of colleagues to contribute to this Special Issue with respect to the aforementioned concepts and keywords. The goal for this Special Issue was to describe the recent developments of this rapidly advancing interdisciplinary research field. We thank all authors for their contributions.
Technology: general issues --- fluorene --- nitrofluorene --- Knoevenagel reaction --- near infrared absorption --- push–pull chromophore --- poly(nitro)fluorene --- organic tandem solar cell --- 3D nano-ripple pattern --- ZnO sol-gel --- charge recombination layer --- low temperature solution process --- on-surface reaction --- stepwise growth --- sequential growth --- hierarchical growth --- macromolecular organic structures --- surface covalent organic framework --- nanoribbons --- macrocycles --- coordination polymers --- silicon phthalocyanines --- n-type organic semiconductors --- organic thin-film transistors --- push-pull dyes --- chromophore --- naphthalene --- solvatochromism --- DFT --- fullerene derivative --- P3HT --- polymer solar cell --- QSPR --- TD-DFT --- fluorene --- nitrofluorene --- Knoevenagel reaction --- near infrared absorption --- push–pull chromophore --- poly(nitro)fluorene --- organic tandem solar cell --- 3D nano-ripple pattern --- ZnO sol-gel --- charge recombination layer --- low temperature solution process --- on-surface reaction --- stepwise growth --- sequential growth --- hierarchical growth --- macromolecular organic structures --- surface covalent organic framework --- nanoribbons --- macrocycles --- coordination polymers --- silicon phthalocyanines --- n-type organic semiconductors --- organic thin-film transistors --- push-pull dyes --- chromophore --- naphthalene --- solvatochromism --- DFT --- fullerene derivative --- P3HT --- polymer solar cell --- QSPR --- TD-DFT
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Organic Electronics is a rapidly evolving multidisciplinary research field at the interface between Organic Chemistry and Physics. Organic Electronics is based on the use of the unique optical and electrical properties of π-conjugated materials that range from small molecules to polymers. The wide activity of researchers in Organic Electronics is testament to the fact that its potential is huge and its list of potential applications almost endless. Application of these electronic and optoelectronic devices range from Organic Field Effect Transistors (OFETs) to Organic Light Emitting Diodes (OLEDs) and Organic Solar Cells (OSCs), sensors, etc. We invited a series of colleagues to contribute to this Special Issue with respect to the aforementioned concepts and keywords. The goal for this Special Issue was to describe the recent developments of this rapidly advancing interdisciplinary research field. We thank all authors for their contributions.
Technology: general issues --- fluorene --- nitrofluorene --- Knoevenagel reaction --- near infrared absorption --- push–pull chromophore --- poly(nitro)fluorene --- organic tandem solar cell --- 3D nano-ripple pattern --- ZnO sol-gel --- charge recombination layer --- low temperature solution process --- on-surface reaction --- stepwise growth --- sequential growth --- hierarchical growth --- macromolecular organic structures --- surface covalent organic framework --- nanoribbons --- macrocycles --- coordination polymers --- silicon phthalocyanines --- n-type organic semiconductors --- organic thin-film transistors --- push-pull dyes --- chromophore --- naphthalene --- solvatochromism --- DFT --- fullerene derivative --- P3HT --- polymer solar cell --- QSPR --- TD-DFT
Choose an application
Organic Electronics is a rapidly evolving multidisciplinary research field at the interface between Organic Chemistry and Physics. Organic Electronics is based on the use of the unique optical and electrical properties of π-conjugated materials that range from small molecules to polymers. The wide activity of researchers in Organic Electronics is testament to the fact that its potential is huge and its list of potential applications almost endless. Application of these electronic and optoelectronic devices range from Organic Field Effect Transistors (OFETs) to Organic Light Emitting Diodes (OLEDs) and Organic Solar Cells (OSCs), sensors, etc. We invited a series of colleagues to contribute to this Special Issue with respect to the aforementioned concepts and keywords. The goal for this Special Issue was to describe the recent developments of this rapidly advancing interdisciplinary research field. We thank all authors for their contributions.
fluorene --- nitrofluorene --- Knoevenagel reaction --- near infrared absorption --- push–pull chromophore --- poly(nitro)fluorene --- organic tandem solar cell --- 3D nano-ripple pattern --- ZnO sol-gel --- charge recombination layer --- low temperature solution process --- on-surface reaction --- stepwise growth --- sequential growth --- hierarchical growth --- macromolecular organic structures --- surface covalent organic framework --- nanoribbons --- macrocycles --- coordination polymers --- silicon phthalocyanines --- n-type organic semiconductors --- organic thin-film transistors --- push-pull dyes --- chromophore --- naphthalene --- solvatochromism --- DFT --- fullerene derivative --- P3HT --- polymer solar cell --- QSPR --- TD-DFT
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This book describes the results of both theoretical and experimental research on many topical issues in intramolecular hydrogen bonding. Its great advantage is that the presented research results have been obtained using many different techniques. Therefore, it is an excellent review of these methods, while showing their applicability to the current scientific issues regarding intramolecular hydrogen bonds. The experimental techniques used include X-ray diffraction, infrared and Raman spectroscopy (IR), nuclear magnetic resonance spectroscopy (NMR), nuclear quadrupole resonance spectroscopy (NQR), incoherent inelastic neutron scattering (IINS), and differential scanning calorimetry (DSC). The solvatochromic and luminescent studies are also described. On the other hand, theoretical research is based on ab initio calculations and the Car–Parrinello Molecular Dynamics (CPMD). In the latter case, a description of nuclear quantum effects (NQE) is also possible. This book also demonstrates the use of theoretical methods such as Quantum Theory of Atoms in Molecules (QTAIM), Interacting Quantum Atoms (IQA), Natural Bond Orbital (NBO), Non-Covalent Interactions (NCI) index, Molecular Tailoring Approach (MTA), and many others.
Research & information: general --- intramolecular interaction --- interaction energy --- hydrogen bond --- intramolecular hydrogen bonds --- deuterium isotope effects on chemical shifts --- isotope ratios --- hydrogen bond energies --- intramolecular hydrogen bonding --- high-accuracy extrapolation methods --- QTAIM --- non-covalent interactions --- local vibrational modes --- hydrogen bond (HB) --- intramolecular hydrogen bond (IHB) --- molecular tailoring approach (MTA) --- fragmentation methods --- bond energy estimation --- noncovalent interactions --- structures and binding energies --- charge-transfer interactions --- spin–spin coupling constants --- polymorphism --- isomerization --- phase transition --- nitro group --- matrix isolation --- IINS --- FT-IR --- Raman --- X-ray --- NQR --- DSC --- DFT --- Schiff base --- N-salicylidene aniline derivative --- photophysical properties --- solvatochromism --- Hirshfeld surface analysis --- amino-alcohols --- α-substitution --- beryllium bonds --- calculated infrared spectra --- interacting quantum atoms --- resonance-assisted hydrogen bond --- Schiff bases --- inelastic incoherent neutron scattering --- isotopic effect --- excited-state intramolecular proton transfer --- photochemistry --- photobiology --- quantum chemistry --- molecular dynamics --- ultrafast processes --- gas phase --- crystalline phase --- MP2 --- CCSD --- AIM --- SAPT --- nuclear quantum effects --- CPMD --- n/a --- spin-spin coupling constants
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This book describes the results of both theoretical and experimental research on many topical issues in intramolecular hydrogen bonding. Its great advantage is that the presented research results have been obtained using many different techniques. Therefore, it is an excellent review of these methods, while showing their applicability to the current scientific issues regarding intramolecular hydrogen bonds. The experimental techniques used include X-ray diffraction, infrared and Raman spectroscopy (IR), nuclear magnetic resonance spectroscopy (NMR), nuclear quadrupole resonance spectroscopy (NQR), incoherent inelastic neutron scattering (IINS), and differential scanning calorimetry (DSC). The solvatochromic and luminescent studies are also described. On the other hand, theoretical research is based on ab initio calculations and the Car–Parrinello Molecular Dynamics (CPMD). In the latter case, a description of nuclear quantum effects (NQE) is also possible. This book also demonstrates the use of theoretical methods such as Quantum Theory of Atoms in Molecules (QTAIM), Interacting Quantum Atoms (IQA), Natural Bond Orbital (NBO), Non-Covalent Interactions (NCI) index, Molecular Tailoring Approach (MTA), and many others.
intramolecular interaction --- interaction energy --- hydrogen bond --- intramolecular hydrogen bonds --- deuterium isotope effects on chemical shifts --- isotope ratios --- hydrogen bond energies --- intramolecular hydrogen bonding --- high-accuracy extrapolation methods --- QTAIM --- non-covalent interactions --- local vibrational modes --- hydrogen bond (HB) --- intramolecular hydrogen bond (IHB) --- molecular tailoring approach (MTA) --- fragmentation methods --- bond energy estimation --- noncovalent interactions --- structures and binding energies --- charge-transfer interactions --- spin–spin coupling constants --- polymorphism --- isomerization --- phase transition --- nitro group --- matrix isolation --- IINS --- FT-IR --- Raman --- X-ray --- NQR --- DSC --- DFT --- Schiff base --- N-salicylidene aniline derivative --- photophysical properties --- solvatochromism --- Hirshfeld surface analysis --- amino-alcohols --- α-substitution --- beryllium bonds --- calculated infrared spectra --- interacting quantum atoms --- resonance-assisted hydrogen bond --- Schiff bases --- inelastic incoherent neutron scattering --- isotopic effect --- excited-state intramolecular proton transfer --- photochemistry --- photobiology --- quantum chemistry --- molecular dynamics --- ultrafast processes --- gas phase --- crystalline phase --- MP2 --- CCSD --- AIM --- SAPT --- nuclear quantum effects --- CPMD --- n/a --- spin-spin coupling constants
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This book describes the results of both theoretical and experimental research on many topical issues in intramolecular hydrogen bonding. Its great advantage is that the presented research results have been obtained using many different techniques. Therefore, it is an excellent review of these methods, while showing their applicability to the current scientific issues regarding intramolecular hydrogen bonds. The experimental techniques used include X-ray diffraction, infrared and Raman spectroscopy (IR), nuclear magnetic resonance spectroscopy (NMR), nuclear quadrupole resonance spectroscopy (NQR), incoherent inelastic neutron scattering (IINS), and differential scanning calorimetry (DSC). The solvatochromic and luminescent studies are also described. On the other hand, theoretical research is based on ab initio calculations and the Car–Parrinello Molecular Dynamics (CPMD). In the latter case, a description of nuclear quantum effects (NQE) is also possible. This book also demonstrates the use of theoretical methods such as Quantum Theory of Atoms in Molecules (QTAIM), Interacting Quantum Atoms (IQA), Natural Bond Orbital (NBO), Non-Covalent Interactions (NCI) index, Molecular Tailoring Approach (MTA), and many others.
Research & information: general --- intramolecular interaction --- interaction energy --- hydrogen bond --- intramolecular hydrogen bonds --- deuterium isotope effects on chemical shifts --- isotope ratios --- hydrogen bond energies --- intramolecular hydrogen bonding --- high-accuracy extrapolation methods --- QTAIM --- non-covalent interactions --- local vibrational modes --- hydrogen bond (HB) --- intramolecular hydrogen bond (IHB) --- molecular tailoring approach (MTA) --- fragmentation methods --- bond energy estimation --- noncovalent interactions --- structures and binding energies --- charge-transfer interactions --- spin-spin coupling constants --- polymorphism --- isomerization --- phase transition --- nitro group --- matrix isolation --- IINS --- FT-IR --- Raman --- X-ray --- NQR --- DSC --- DFT --- Schiff base --- N-salicylidene aniline derivative --- photophysical properties --- solvatochromism --- Hirshfeld surface analysis --- amino-alcohols --- α-substitution --- beryllium bonds --- calculated infrared spectra --- interacting quantum atoms --- resonance-assisted hydrogen bond --- Schiff bases --- inelastic incoherent neutron scattering --- isotopic effect --- excited-state intramolecular proton transfer --- photochemistry --- photobiology --- quantum chemistry --- molecular dynamics --- ultrafast processes --- gas phase --- crystalline phase --- MP2 --- CCSD --- AIM --- SAPT --- nuclear quantum effects --- CPMD --- intramolecular interaction --- interaction energy --- hydrogen bond --- intramolecular hydrogen bonds --- deuterium isotope effects on chemical shifts --- isotope ratios --- hydrogen bond energies --- intramolecular hydrogen bonding --- high-accuracy extrapolation methods --- QTAIM --- non-covalent interactions --- local vibrational modes --- hydrogen bond (HB) --- intramolecular hydrogen bond (IHB) --- molecular tailoring approach (MTA) --- fragmentation methods --- bond energy estimation --- noncovalent interactions --- structures and binding energies --- charge-transfer interactions --- spin-spin coupling constants --- polymorphism --- isomerization --- phase transition --- nitro group --- matrix isolation --- IINS --- FT-IR --- Raman --- X-ray --- NQR --- DSC --- DFT --- Schiff base --- N-salicylidene aniline derivative --- photophysical properties --- solvatochromism --- Hirshfeld surface analysis --- amino-alcohols --- α-substitution --- beryllium bonds --- calculated infrared spectra --- interacting quantum atoms --- resonance-assisted hydrogen bond --- Schiff bases --- inelastic incoherent neutron scattering --- isotopic effect --- excited-state intramolecular proton transfer --- photochemistry --- photobiology --- quantum chemistry --- molecular dynamics --- ultrafast processes --- gas phase --- crystalline phase --- MP2 --- CCSD --- AIM --- SAPT --- nuclear quantum effects --- CPMD
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This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as ‘chemistry beyond the molecule’ (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.
Technology: general issues --- anion binding --- chloride receptor --- switchable system --- hydroquinone --- redox switch --- metal-organic frameworks --- vapour sorption --- solvatochromism --- desorption kinetics --- ion-channels --- crown-ethers --- bilayer membranes --- self-assembly --- supramolecular chemistry --- host-guest chemistry --- coordination cage --- catalysis --- crystal structure --- copper chloride complexes --- H-bonding pattern --- tetrazole ligands --- X-ray diffraction --- Hirshfeld surfaces --- uranium(VI) --- carboxylates --- capsules --- structure --- luminescence --- multicomponent cocrystal --- cocrystallization mechanism --- cocrystal synthesis --- crystal engineering --- porous material --- molecular recognition --- halogen bond --- co-crystal --- molecular tecton --- binary solid --- network structure --- σ-hole --- molecular electrostatic potential --- calixarenes --- coordination clusters --- manganese --- molecular magnetism --- host-guest interaction --- cucurbit[7]uril --- 4-pyrrolidinopyridinium --- copper complexes --- chlorido ligand displacement --- catalysis regulation --- Schiff base ligands --- urea hydrolysis --- coordination chemistry --- hydrogen bonds --- metalla-assemblies --- coordination-driven self-assembly --- orthogonality --- ligands --- metal ions --- complementarity --- hydrogen bonding --- cyclotricatechylene --- metal-organic cage --- helicate --- metallosupramolecular --- chirality --- copper(II) complexes --- pyrazolato ligands --- supramolecular assembly --- X-ray crystallography --- magnetic susceptibility --- EPR spectroscopy --- isotropic exchange --- antisymmetric exchange --- dipolar interaction --- DFT calculations --- hydrogen bond --- pyrazine --- chloropyrazine --- chloropyrazin-2-amine --- copper halide --- supramolecular structure --- conformational polymorphism --- intermolecular contacts --- N,N',N",N‴-Tetraisopropylpyrophosphoramide --- pyrophosphoramide --- synthons --- supramolecular motifs --- anion binding --- chloride receptor --- switchable system --- hydroquinone --- redox switch --- metal-organic frameworks --- vapour sorption --- solvatochromism --- desorption kinetics --- ion-channels --- crown-ethers --- bilayer membranes --- self-assembly --- supramolecular chemistry --- host-guest chemistry --- coordination cage --- catalysis --- crystal structure --- copper chloride complexes --- H-bonding pattern --- tetrazole ligands --- X-ray diffraction --- Hirshfeld surfaces --- uranium(VI) --- carboxylates --- capsules --- structure --- luminescence --- multicomponent cocrystal --- cocrystallization mechanism --- cocrystal synthesis --- crystal engineering --- porous material --- molecular recognition --- halogen bond --- co-crystal --- molecular tecton --- binary solid --- network structure --- σ-hole --- molecular electrostatic potential --- calixarenes --- coordination clusters --- manganese --- molecular magnetism --- host-guest interaction --- cucurbit[7]uril --- 4-pyrrolidinopyridinium --- copper complexes --- chlorido ligand displacement --- catalysis regulation --- Schiff base ligands --- urea hydrolysis --- coordination chemistry --- hydrogen bonds --- metalla-assemblies --- coordination-driven self-assembly --- orthogonality --- ligands --- metal ions --- complementarity --- hydrogen bonding --- cyclotricatechylene --- metal-organic cage --- helicate --- metallosupramolecular --- chirality --- copper(II) complexes --- pyrazolato ligands --- supramolecular assembly --- X-ray crystallography --- magnetic susceptibility --- EPR spectroscopy --- isotropic exchange --- antisymmetric exchange --- dipolar interaction --- DFT calculations --- hydrogen bond --- pyrazine --- chloropyrazine --- chloropyrazin-2-amine --- copper halide --- supramolecular structure --- conformational polymorphism --- intermolecular contacts --- N,N',N",N‴-Tetraisopropylpyrophosphoramide --- pyrophosphoramide --- synthons --- supramolecular motifs
Choose an application
This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as ‘chemistry beyond the molecule’ (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.
Technology: general issues --- anion binding --- chloride receptor --- switchable system --- hydroquinone --- redox switch --- metal-organic frameworks --- vapour sorption --- solvatochromism --- desorption kinetics --- ion-channels --- crown-ethers --- bilayer membranes --- self-assembly --- supramolecular chemistry --- host–guest chemistry --- coordination cage --- catalysis --- crystal structure --- copper chloride complexes --- H-bonding pattern --- tetrazole ligands --- X-ray diffraction --- Hirshfeld surfaces --- uranium(VI) --- carboxylates --- capsules --- structure --- luminescence --- multicomponent cocrystal --- cocrystallization mechanism --- cocrystal synthesis --- crystal engineering --- porous material --- molecular recognition --- halogen bond --- co-crystal --- molecular tecton --- binary solid --- network structure --- σ-hole --- molecular electrostatic potential --- calixarenes --- coordination clusters --- manganese --- molecular magnetism --- host–guest interaction --- cucurbit[7]uril --- 4-pyrrolidinopyridinium --- copper complexes --- chlorido ligand displacement --- catalysis regulation --- Schiff base ligands --- urea hydrolysis --- coordination chemistry --- hydrogen bonds --- metalla-assemblies --- coordination-driven self-assembly --- orthogonality --- ligands --- metal ions --- complementarity --- hydrogen bonding --- cyclotricatechylene --- metal–organic cage --- helicate --- metallosupramolecular --- chirality --- copper(II) complexes --- pyrazolato ligands --- supramolecular assembly --- X-ray crystallography --- magnetic susceptibility --- EPR spectroscopy --- isotropic exchange --- antisymmetric exchange --- dipolar interaction --- DFT calculations --- hydrogen bond --- pyrazine --- chloropyrazine --- chloropyrazin-2-amine --- copper halide --- supramolecular structure --- conformational polymorphism --- intermolecular contacts --- N,N′,N″,N‴-Tetraisopropylpyrophosphoramide --- pyrophosphoramide --- synthons --- supramolecular motifs --- n/a --- host-guest chemistry --- host-guest interaction --- metal-organic cage --- N,N',N",N‴-Tetraisopropylpyrophosphoramide
Choose an application
This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as ‘chemistry beyond the molecule’ (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.
anion binding --- chloride receptor --- switchable system --- hydroquinone --- redox switch --- metal-organic frameworks --- vapour sorption --- solvatochromism --- desorption kinetics --- ion-channels --- crown-ethers --- bilayer membranes --- self-assembly --- supramolecular chemistry --- host–guest chemistry --- coordination cage --- catalysis --- crystal structure --- copper chloride complexes --- H-bonding pattern --- tetrazole ligands --- X-ray diffraction --- Hirshfeld surfaces --- uranium(VI) --- carboxylates --- capsules --- structure --- luminescence --- multicomponent cocrystal --- cocrystallization mechanism --- cocrystal synthesis --- crystal engineering --- porous material --- molecular recognition --- halogen bond --- co-crystal --- molecular tecton --- binary solid --- network structure --- σ-hole --- molecular electrostatic potential --- calixarenes --- coordination clusters --- manganese --- molecular magnetism --- host–guest interaction --- cucurbit[7]uril --- 4-pyrrolidinopyridinium --- copper complexes --- chlorido ligand displacement --- catalysis regulation --- Schiff base ligands --- urea hydrolysis --- coordination chemistry --- hydrogen bonds --- metalla-assemblies --- coordination-driven self-assembly --- orthogonality --- ligands --- metal ions --- complementarity --- hydrogen bonding --- cyclotricatechylene --- metal–organic cage --- helicate --- metallosupramolecular --- chirality --- copper(II) complexes --- pyrazolato ligands --- supramolecular assembly --- X-ray crystallography --- magnetic susceptibility --- EPR spectroscopy --- isotropic exchange --- antisymmetric exchange --- dipolar interaction --- DFT calculations --- hydrogen bond --- pyrazine --- chloropyrazine --- chloropyrazin-2-amine --- copper halide --- supramolecular structure --- conformational polymorphism --- intermolecular contacts --- N,N′,N″,N‴-Tetraisopropylpyrophosphoramide --- pyrophosphoramide --- synthons --- supramolecular motifs --- n/a --- host-guest chemistry --- host-guest interaction --- metal-organic cage --- N,N',N",N‴-Tetraisopropylpyrophosphoramide
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