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Carbohydrates --- Rearrangements (Chemistry) --- Glucides --- Transpositions (Chimie)
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Hydrocarbon Thermal Isomerizations summarizes rearrangements which are induced by heating neutral hydrocarbons under non-catalytic conditions in the vapor phase or in non-polar solution. This subject has attracted the interest of mechanistic organic chemists and theorists in the last quarter century because it is one of the few fields workable by state of the art techniques of both camps. This work collects together most of the crucial rate and stereochemical data in a single volume, along with a critical analysis of each of these reactions.Unlike reviews or other books in th
Hydrocarbons. --- Isomerization. --- Isomerism --- Petroleum --- Rearrangements (Chemistry) --- Organic compounds --- Refining
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The general principles of polar rearrangements are brought together in this text, which deals with all the major rearrangements involving electron-deficient atoms or charged intermediates. Reactions involving migration to electron-deficient carbon, nitrogen, oxygen, and sulphur, and sigmatropic rearrangements involving polar species, are thus treated in a coherent and consistent manner. Clear discussions of the reaction mechanisms are followed by examples of synthetic applications, providing a concise yet comprehensive account of the nature and importance of these processes.
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