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This book represents a collection of contributions in the field of the synthesis and characterization of chemical compounds, natural products, chemical reactivity, and computational chemistry. Among its contents, the reader will find high-quality, peer-reviewed research and review articles that were published in the open access journal Compounds by members of the Editorial Board and the authors invited by the Editorial Office and Editor-in-Chief.

Technology: general issues --- Chemical engineering --- atropisomerism --- 4,4′-bipyridine --- pyridine N-oxidation --- halogenation --- halogen bond --- cyanation --- Finkelstein reaction --- Suzuki coupling --- Orchis --- scent --- gas chromatography --- mass spectrometry --- solid-phase microextraction --- quantum chemistry --- computational chemistry --- molecular dynamics --- modeling --- open-source software --- proprietary software --- Himantoglossum --- solid phase microextraction --- iodination --- alkanes --- alkenes --- alkynes --- alkyl carbonyls --- elemental iodine --- iodides --- Zutano variety --- avocado oil --- Soxhlet extraction --- ultrasound-assisted extraction --- volatiles --- ripening --- over-ripe --- HS-SPME–GC–MS --- Basilicata --- Barlia robertiana --- Himantoglossum robertianum --- mantel test --- Orchidaceae --- pollination syndrome --- Italy --- volatile compounds --- solvolysis --- aryldiazonium ions --- perchlorate anions --- silicon carbide (SiC) --- 3C-SiC powder --- 4H-SiC crystal --- impurities --- photoluminescence --- pnictogen bonding --- nitrogen as pnictogen bond donor --- geometries --- crystal structure analysis --- ICSD and CSD database analyses --- MESP characterizations --- sum of the van der Waals radii concept --- Dactylorhiza --- volatile organic compounds --- thiosemicarbazone --- metal complexes --- DNA interactions --- biological activity --- thiazolidinedione --- microwave synthesis --- compound library --- rosiglitazone --- Knoevangel condensation --- biodiesel production --- crude glycerin --- carbon materials --- n/a --- 4,4'-bipyridine --- HS-SPME-GC-MS

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This book describes unconventional noncovalent interactions and analyzes their importance for crystal growth in organic and hybrid organic–inorganic systems. Several examples illustrate how the combination of theory and experiment allows rationalizing the strength and directionality of noncovalent interactions. This book elegantly describes the results of a survey of X-ray structures of main group element compounds (M = Sn, Pb As, Sb, Bi, and Te) exhibiting intermolecular M•••Se noncovalent interactions in one of its chapters. Moreover, it provides a consistent description of noncovalent interactions, covering most groups of the periodic table. The interactions are described and discussed using their trivial names. That is, a comprehensive and accurate description is provided for alkali, alkaline earth, regium, spodium, triel, tetrel, pnictogen, chalcogen, halogen, and aerogen bonding interactions. No other book is available covering such an extensive number of interactions and examples where these interactions are relevant. relevant.

non-covalent interactions --- regium bonds --- silver(I) --- coinage metals --- pyrazolates --- phosphines --- halogen bonding --- hydrogen bonding sigma-hole interactions --- theoretical studies --- characterizations --- noncovalent interactions --- Lewis acids --- Lewis bases --- spodium bonds --- σ/π-hole interactions --- EDTA --- 2,6-diaminopurine --- cadmium --- co-crystal --- H-bonding --- π–π stacking --- triazinane --- 1,3,5-Triazacyclohexane --- Hirshfeld surface analysis --- DFT study --- C–H···π interaction --- hybridization of a nitrogen atom in sulfonamides --- molecular cocrystal --- sandwiched-layer structure --- C–I···F halogen bonds --- π···π stacking interactions --- PBE0-D3(BJ) calculations --- secondary bonding --- supramolecular --- crystal engineering --- tetrel bonding --- pnictogen bonding --- chalcogen bonding --- selenium --- structural chemistry --- main group elements --- π–hole interaction --- substituent effects --- vibrational spectroscopy --- local vibrational mode theory --- direct measure for π–hole interaction strength --- noncovalent interaction --- hydrogen bonding --- nickel --- Schiff bases --- crystallography --- σ-hole --- π-hole --- crystal growth --- supramolecular chemistry --- σ-hole interactions --- self-assembly --- scanning tunneling microscopy