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Book
Catalytic Processes for CO2 Utilization
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Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

In addition to the avoidance and long-term storage (CCS) of anthropogenic CO2 emissions, the utilization of CO2 for the production of usable products is discussed as a possible method of reducing greenhouse gas emissions. The associated technologies are summarized under the term "Carbon Capture and Utilization" (CCU). CCU technologies have gained increasing attention in science and industry over the last decade and are considered essential for meeting the reduction goals of the Paris Agreement. The selection of research papers in this book, mostly focused on Power-to-X technologies and the catalytic conversion of CO2, are related to the most recent advancements in CCU technologies.


Book
Catalytic Processes for CO2 Utilization
Authors: --- ---
Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

In addition to the avoidance and long-term storage (CCS) of anthropogenic CO2 emissions, the utilization of CO2 for the production of usable products is discussed as a possible method of reducing greenhouse gas emissions. The associated technologies are summarized under the term "Carbon Capture and Utilization" (CCU). CCU technologies have gained increasing attention in science and industry over the last decade and are considered essential for meeting the reduction goals of the Paris Agreement. The selection of research papers in this book, mostly focused on Power-to-X technologies and the catalytic conversion of CO2, are related to the most recent advancements in CCU technologies.


Book
Catalytic Processes for CO2 Utilization
Authors: --- ---
Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

In addition to the avoidance and long-term storage (CCS) of anthropogenic CO2 emissions, the utilization of CO2 for the production of usable products is discussed as a possible method of reducing greenhouse gas emissions. The associated technologies are summarized under the term "Carbon Capture and Utilization" (CCU). CCU technologies have gained increasing attention in science and industry over the last decade and are considered essential for meeting the reduction goals of the Paris Agreement. The selection of research papers in this book, mostly focused on Power-to-X technologies and the catalytic conversion of CO2, are related to the most recent advancements in CCU technologies.


Book
Commemorative Issue to Celebrate the Life and Work of Prof. Roger W.H. Sargent
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

This book celebrates the life, work and influence of Professor Roger W.H. Sargent of Imperial College London. It does so through a range of original contributions that span the wide academic and industry interests of Professor Sargent. Roger Sargent passed away in late 2018, but his legacy lives on through his enormous academic tree, which traces to the early 1960s. That huge body of work has also had significant impacts on industrial practices. Roger was regarded as “the father of Process Systems Engineering (PSE)”. This area of Chemical Engineering continues to influence the modelling, design, control, optimization and integrated performance of industrial and related processes. This book highlights some of those impacts and the ongoing importance of PSE in helping to solve some of the grand challenges of our time.


Book
Commemorative Issue to Celebrate the Life and Work of Prof. Roger W.H. Sargent
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

This book celebrates the life, work and influence of Professor Roger W.H. Sargent of Imperial College London. It does so through a range of original contributions that span the wide academic and industry interests of Professor Sargent. Roger Sargent passed away in late 2018, but his legacy lives on through his enormous academic tree, which traces to the early 1960s. That huge body of work has also had significant impacts on industrial practices. Roger was regarded as “the father of Process Systems Engineering (PSE)”. This area of Chemical Engineering continues to influence the modelling, design, control, optimization and integrated performance of industrial and related processes. This book highlights some of those impacts and the ongoing importance of PSE in helping to solve some of the grand challenges of our time.


Book
Commemorative Issue to Celebrate the Life and Work of Prof. Roger W.H. Sargent
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

This book celebrates the life, work and influence of Professor Roger W.H. Sargent of Imperial College London. It does so through a range of original contributions that span the wide academic and industry interests of Professor Sargent. Roger Sargent passed away in late 2018, but his legacy lives on through his enormous academic tree, which traces to the early 1960s. That huge body of work has also had significant impacts on industrial practices. Roger was regarded as “the father of Process Systems Engineering (PSE)”. This area of Chemical Engineering continues to influence the modelling, design, control, optimization and integrated performance of industrial and related processes. This book highlights some of those impacts and the ongoing importance of PSE in helping to solve some of the grand challenges of our time.

Keywords

Technology: general issues --- input-output model --- fuzzy optimization --- process synthesis --- preliminary stage design --- process systems engineering --- energy systems engineering --- process design --- optimization --- nonlinear programming --- process monitoring --- nonlinear principal component analysis --- parallel neural networks --- autoassociative neural network --- big data --- process scheduling --- process system engineering --- mixed-integer programming --- scheduling --- process control --- integration --- distribution --- planning --- oil supply chain --- robust optimization --- uncertainty --- bio-jet diesel --- co-hydrotreating --- hydrodesulphurisation --- hydrodeoxigenation --- reactive distillation --- coproduction --- Lurgi syngas --- cryogenic separation --- methanol synthesis --- LNG --- symmetry --- quadratic optimization --- quadratically-constrained quadratic optimization --- process modeling --- mathematical programming --- MINLP --- generalized disjunctive programming --- design --- higher education --- curricula --- visualization --- input-output model --- fuzzy optimization --- process synthesis --- preliminary stage design --- process systems engineering --- energy systems engineering --- process design --- optimization --- nonlinear programming --- process monitoring --- nonlinear principal component analysis --- parallel neural networks --- autoassociative neural network --- big data --- process scheduling --- process system engineering --- mixed-integer programming --- scheduling --- process control --- integration --- distribution --- planning --- oil supply chain --- robust optimization --- uncertainty --- bio-jet diesel --- co-hydrotreating --- hydrodesulphurisation --- hydrodeoxigenation --- reactive distillation --- coproduction --- Lurgi syngas --- cryogenic separation --- methanol synthesis --- LNG --- symmetry --- quadratic optimization --- quadratically-constrained quadratic optimization --- process modeling --- mathematical programming --- MINLP --- generalized disjunctive programming --- design --- higher education --- curricula --- visualization


Book
Catalysis for the Production of Sustainable Fuels and Chemicals
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Catalysis, in the industrial production of chemicals, fuels, and materials, accounts for more than half of gross material production worldwide. Heterogeneous catalysis enables fast and selective chemical transformations, resulting in superior product yield and facilitating catalyst separation and recovery. The synthesis of novel catalysts has emerged as a hot topic for process and product development with numerous research publications and patents. Hence, development of efficient catalysts and their applications is important for sustainable energy production and use, green chemicals production and use, and economic growth. This Special Issue discusses recent developments related to catalysis for the production of sustainable fuels and chemicals and traverses many new frontiers of catalysis including synthesis, characterization, catalytic performances, reaction kinetics and modelling, as well as applications of catalysts for the production of biofuels, synthesis gas, and other green products. This covers the current state-of-the-art catalysis research applied to bioenergy, organic transformation, carbon–carbon and carbon–heteroatoms, reforming, hydrogenation, hydrodesulfurization, hydrodenitrogenation, hydrodemetalization, Fischer–Tropsch synthesis, to name a few. This book highlights new avenues in catalysis including catalyst preparation methods, analytical tools for catalyst characterization, and techno-economic assessment to enhance a chemical or biological transformation process using catalysts for a betterment of industry, academia and society.

Keywords

History of engineering & technology --- HDO --- sulfide catalyst --- NiMo/Al2O3 --- phospholipid --- fatty acid --- choline --- oxidative desulfurization --- oxidative denitrogenation --- hydrotreating --- XPS --- activated carbon --- tert-butyl hydroperoxide --- biofuel --- biodiesel --- hydrocarbon --- waste --- glycerol hydrogenolysis --- in situ hydrogen --- methanol steam reforming --- Ni/Cu/ZnO/Al2O3 catalysts --- chilean natural zeolite --- Brønsted acid sites --- bio-oil upgrade --- catalytic pyrolysis --- nitrogen-doping --- iron nitrides --- light olefins --- CO hydrogenation --- KMnO4 pretreatment --- dry reforming methane (DRM) --- methane --- carbon dioxide --- microwave --- conversion --- catalyst --- selectivity --- thermal integration --- catalyst support --- CoMo sulfided catalyst --- deoxygenation --- cracking and polymerization --- hydrogenation and dehydrogenation --- waste cooking oil --- artificial neural network --- kinetic modeling --- cobalt-praseodymium (III) oxide --- CO-rich hydrogen --- methane dry reforming --- hydrodeoxygenation --- Ni/KIT-6 --- ethyl acetate --- CO2 activation --- methanol synthesis --- atomic layer deposition --- copper nanoparticles --- zinc oxide atomic layer --- hydroprocessing --- FeCu catalysts --- jet fuel --- oleic acid --- catalytic conversion --- catalyst acidity and basicity --- product distribution --- reaction pathways --- molybdenum phosphide --- methyl palmitate --- isomerization --- carboxylic acids upgrading --- ketonization --- deuterated acetic acid --- acetone D-isotopomers distribution --- H/D exchange --- inverse deuterium kinetic isotope effect --- kinetic parameters --- activation energy --- catalytic pyrolysis of biomass --- bio-oil --- sustainable fuels and chemicals --- hydrogenolysis --- desulfurization and denitrogenation --- CO2 utilization --- pyrolysis and cracking --- syngas and hydrogen --- biomass and bio-oil --- catalysis --- HDO --- sulfide catalyst --- NiMo/Al2O3 --- phospholipid --- fatty acid --- choline --- oxidative desulfurization --- oxidative denitrogenation --- hydrotreating --- XPS --- activated carbon --- tert-butyl hydroperoxide --- biofuel --- biodiesel --- hydrocarbon --- waste --- glycerol hydrogenolysis --- in situ hydrogen --- methanol steam reforming --- Ni/Cu/ZnO/Al2O3 catalysts --- chilean natural zeolite --- Brønsted acid sites --- bio-oil upgrade --- catalytic pyrolysis --- nitrogen-doping --- iron nitrides --- light olefins --- CO hydrogenation --- KMnO4 pretreatment --- dry reforming methane (DRM) --- methane --- carbon dioxide --- microwave --- conversion --- catalyst --- selectivity --- thermal integration --- catalyst support --- CoMo sulfided catalyst --- deoxygenation --- cracking and polymerization --- hydrogenation and dehydrogenation --- waste cooking oil --- artificial neural network --- kinetic modeling --- cobalt-praseodymium (III) oxide --- CO-rich hydrogen --- methane dry reforming --- hydrodeoxygenation --- Ni/KIT-6 --- ethyl acetate --- CO2 activation --- methanol synthesis --- atomic layer deposition --- copper nanoparticles --- zinc oxide atomic layer --- hydroprocessing --- FeCu catalysts --- jet fuel --- oleic acid --- catalytic conversion --- catalyst acidity and basicity --- product distribution --- reaction pathways --- molybdenum phosphide --- methyl palmitate --- isomerization --- carboxylic acids upgrading --- ketonization --- deuterated acetic acid --- acetone D-isotopomers distribution --- H/D exchange --- inverse deuterium kinetic isotope effect --- kinetic parameters --- activation energy --- catalytic pyrolysis of biomass --- bio-oil --- sustainable fuels and chemicals --- hydrogenolysis --- desulfurization and denitrogenation --- CO2 utilization --- pyrolysis and cracking --- syngas and hydrogen --- biomass and bio-oil --- catalysis


Book
Catalysis for the Production of Sustainable Fuels and Chemicals
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Catalysis, in the industrial production of chemicals, fuels, and materials, accounts for more than half of gross material production worldwide. Heterogeneous catalysis enables fast and selective chemical transformations, resulting in superior product yield and facilitating catalyst separation and recovery. The synthesis of novel catalysts has emerged as a hot topic for process and product development with numerous research publications and patents. Hence, development of efficient catalysts and their applications is important for sustainable energy production and use, green chemicals production and use, and economic growth. This Special Issue discusses recent developments related to catalysis for the production of sustainable fuels and chemicals and traverses many new frontiers of catalysis including synthesis, characterization, catalytic performances, reaction kinetics and modelling, as well as applications of catalysts for the production of biofuels, synthesis gas, and other green products. This covers the current state-of-the-art catalysis research applied to bioenergy, organic transformation, carbon–carbon and carbon–heteroatoms, reforming, hydrogenation, hydrodesulfurization, hydrodenitrogenation, hydrodemetalization, Fischer–Tropsch synthesis, to name a few. This book highlights new avenues in catalysis including catalyst preparation methods, analytical tools for catalyst characterization, and techno-economic assessment to enhance a chemical or biological transformation process using catalysts for a betterment of industry, academia and society.

Keywords

History of engineering & technology --- HDO --- sulfide catalyst --- NiMo/Al2O3 --- phospholipid --- fatty acid --- choline --- oxidative desulfurization --- oxidative denitrogenation --- hydrotreating --- XPS --- activated carbon --- tert-butyl hydroperoxide --- biofuel --- biodiesel --- hydrocarbon --- waste --- glycerol hydrogenolysis --- in situ hydrogen --- methanol steam reforming --- Ni/Cu/ZnO/Al2O3 catalysts --- chilean natural zeolite --- Brønsted acid sites --- bio-oil upgrade --- catalytic pyrolysis --- nitrogen-doping --- iron nitrides --- light olefins --- CO hydrogenation --- KMnO4 pretreatment --- dry reforming methane (DRM) --- methane --- carbon dioxide --- microwave --- conversion --- catalyst --- selectivity --- thermal integration --- catalyst support --- CoMo sulfided catalyst --- deoxygenation --- cracking and polymerization --- hydrogenation and dehydrogenation --- waste cooking oil --- artificial neural network --- kinetic modeling --- cobalt-praseodymium (III) oxide --- CO-rich hydrogen --- methane dry reforming --- hydrodeoxygenation --- Ni/KIT-6 --- ethyl acetate --- CO2 activation --- methanol synthesis --- atomic layer deposition --- copper nanoparticles --- zinc oxide atomic layer --- hydroprocessing --- FeCu catalysts --- jet fuel --- oleic acid --- catalytic conversion --- catalyst acidity and basicity --- product distribution --- reaction pathways --- molybdenum phosphide --- methyl palmitate --- isomerization --- carboxylic acids upgrading --- ketonization --- deuterated acetic acid --- acetone D-isotopomers distribution --- H/D exchange --- inverse deuterium kinetic isotope effect --- kinetic parameters --- activation energy --- catalytic pyrolysis of biomass --- bio-oil --- sustainable fuels and chemicals --- hydrogenolysis --- desulfurization and denitrogenation --- CO2 utilization --- pyrolysis and cracking --- syngas and hydrogen --- biomass and bio-oil --- catalysis


Book
Emissions Control Catalysis
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

The important advances achieved over the past years in all technological directions (industry, energy, and health) contributing to human well-being are unfortunately, in many cases, accompanied by a threat to the environment, with photochemical smog, stratospheric ozone depletion, acid rain, global warming, and finally climate change being the most well-known major issues. These are the results of a variety of pollutants emitted through these human activities. The indications show that we are already at a tipping point that might lead to non-linear and sudden environmental change on a global scale. Aiming to tackle these adverse effects in an attempt to mitigate any damage that has already occurred and to ensure that we are heading toward a cleaner (green) and sustainable future, scientists around the world are developing tools and techniques to understand, monitor, protect, and improve the environment. Emissions control catalysis is continuously advancing, providing novel, multifunctional, and optimally promoted using a variety of methods, nano-structured catalytic materials, and strategies (e.g., energy chemicals recycling, cyclic economy) that enable us to effectively control emissions, either of mobile or stationary sources, improving the quality of air (outdoor and indoor) and water and the energy economy. Representative cases include the abatement and/or recycling of CO2, CO, NOx, N2O, NH3, CH4, higher hydrocarbons, volatile organic compounds (VOCs), particulate matter, and specific industrial emissions (e.g., SOx, H2S, dioxins aromatics, and biogas). The “Emissions Control Catalysis” Special Issue has succeeded in collecting 22 high-quality contributions, included in this MDPI open access book, covering recent research progress in a variety of fields relevant to the above topics and/or applications, mainly on: (i) NOx catalytic reduction from cars (i.e., TWC) and industry (SCR) emissions; (ii) CO, CH4, and other hydrocarbons removal, and (iii) CO2 capture/recirculation combining emissions control with added-value chemicals production.

Keywords

LNT --- NSR --- NOx storage --- phosphorous --- deactivation --- poisoning --- electrochemical reduction --- CO2 --- CuO --- TiO2 --- ethanol --- cerium-doped titania --- sulfur-tolerant materials --- organic compounds purification --- diesel oxidation catalyst --- vehicle exhaust --- chemical looping reforming --- hydrogen --- oxygen carrier --- CeO2 --- nanorod --- selective catalytic reduction --- nitric oxide --- ammonia --- Cu/ZSM-5 --- cerium --- zirconium --- CO2 electroreduction --- CO2 valorization --- Cu catalyst --- particle size --- PEM --- acetaldehyde production --- methanol production --- Ce-based catalyst --- stepwise precipitation --- diesel exhaust --- nitrogen oxides abatement --- electrochemical promotion --- NEMCA --- palladium --- ionic promoter --- nanoparticles --- yttria-stabilized zirconia --- direct NO decomposition --- PGM oxide promotion --- PdO vs. PtO --- in-situ FT-IR --- NO adsorption properties --- redox properties --- sintered ore catalyst --- sulfate --- In-situ DRIFTS --- SCR --- copper-ceria catalysts --- hydrothermal method --- CO oxidation --- copper clusters --- nanoceria --- SOECs --- RWGS reaction kinetics --- Au–Mo–Fe-Ni/GDC electrodes --- high temperature H2O/CO2 co-electrolysis --- platinum --- Rhodium --- iridium --- NO --- N2O --- propene --- CO --- methane --- alkali --- alkaline earth --- platinum group metals --- deNOx chemistry --- lean burn conditions --- TWC --- catalyst promotion --- EPOC --- NH3-SCR --- nanostructure --- kinetics --- thermodynamics --- manganese oxides --- Co3O4 --- complete CH4 oxidation --- hydrothermal synthesis --- precipitation --- Pd/BEA --- Cold start --- Pd species --- NOx abatement --- ammonia oxidation --- response surface methodology --- desirability function --- Box-Behnken design --- carbon dioxide --- hydrogenation --- heterogeneous catalysis --- plasma catalysis --- value-added chemicals --- methanol synthesis --- methanation --- Catalyst --- (NH4)2SO4 --- deNOx --- H2O and SO2 poisoning --- low-temperature selective catalytic reduction --- de-NOx catalysis --- SO2/H2O tolerance --- transition metal-based catalysts --- perovskite --- catalytic coating --- cathodic sputtering method --- n/a --- Au-Mo-Fe-Ni/GDC electrodes


Book
Catalysis for the Production of Sustainable Fuels and Chemicals
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Catalysis, in the industrial production of chemicals, fuels, and materials, accounts for more than half of gross material production worldwide. Heterogeneous catalysis enables fast and selective chemical transformations, resulting in superior product yield and facilitating catalyst separation and recovery. The synthesis of novel catalysts has emerged as a hot topic for process and product development with numerous research publications and patents. Hence, development of efficient catalysts and their applications is important for sustainable energy production and use, green chemicals production and use, and economic growth. This Special Issue discusses recent developments related to catalysis for the production of sustainable fuels and chemicals and traverses many new frontiers of catalysis including synthesis, characterization, catalytic performances, reaction kinetics and modelling, as well as applications of catalysts for the production of biofuels, synthesis gas, and other green products. This covers the current state-of-the-art catalysis research applied to bioenergy, organic transformation, carbon–carbon and carbon–heteroatoms, reforming, hydrogenation, hydrodesulfurization, hydrodenitrogenation, hydrodemetalization, Fischer–Tropsch synthesis, to name a few. This book highlights new avenues in catalysis including catalyst preparation methods, analytical tools for catalyst characterization, and techno-economic assessment to enhance a chemical or biological transformation process using catalysts for a betterment of industry, academia and society.

Keywords

HDO --- sulfide catalyst --- NiMo/Al2O3 --- phospholipid --- fatty acid --- choline --- oxidative desulfurization --- oxidative denitrogenation --- hydrotreating --- XPS --- activated carbon --- tert-butyl hydroperoxide --- biofuel --- biodiesel --- hydrocarbon --- waste --- glycerol hydrogenolysis --- in situ hydrogen --- methanol steam reforming --- Ni/Cu/ZnO/Al2O3 catalysts --- chilean natural zeolite --- Brønsted acid sites --- bio-oil upgrade --- catalytic pyrolysis --- nitrogen-doping --- iron nitrides --- light olefins --- CO hydrogenation --- KMnO4 pretreatment --- dry reforming methane (DRM) --- methane --- carbon dioxide --- microwave --- conversion --- catalyst --- selectivity --- thermal integration --- catalyst support --- CoMo sulfided catalyst --- deoxygenation --- cracking and polymerization --- hydrogenation and dehydrogenation --- waste cooking oil --- artificial neural network --- kinetic modeling --- cobalt-praseodymium (III) oxide --- CO-rich hydrogen --- methane dry reforming --- hydrodeoxygenation --- Ni/KIT-6 --- ethyl acetate --- CO2 activation --- methanol synthesis --- atomic layer deposition --- copper nanoparticles --- zinc oxide atomic layer --- hydroprocessing --- FeCu catalysts --- jet fuel --- oleic acid --- catalytic conversion --- catalyst acidity and basicity --- product distribution --- reaction pathways --- molybdenum phosphide --- methyl palmitate --- isomerization --- carboxylic acids upgrading --- ketonization --- deuterated acetic acid --- acetone D-isotopomers distribution --- H/D exchange --- inverse deuterium kinetic isotope effect --- kinetic parameters --- activation energy --- catalytic pyrolysis of biomass --- bio-oil --- sustainable fuels and chemicals --- hydrogenolysis --- desulfurization and denitrogenation --- CO2 utilization --- pyrolysis and cracking --- syngas and hydrogen --- biomass and bio-oil --- catalysis

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