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Featuring a mild process and high selectivity, enzyme bioelectrocatalysis employing oxidoreductases immobilized on conductive surfaces is playing an increasingly vital role across a wide scope of applications. Enzyme bioelectrocatalysis is key for devices such as biosensors and biofuel cells, which are attracting considerable attention towards sustainable sensing and energy production. A wide range of sophisticated reactions, such as chiral compound synthesis and CO2 and N2 fixation, can be accomplished with enzyme bioelectrocatalysis. Last but not least, redox enzymes are sources of inspiration for new non-noble metal electrocatalysts. The “Enzymatic Bioelectrocatalysis” Special Issue comprises six reviews contributed by research groups from different countries, covering fundamentals and applications, as well as the recent research progress in this field.

bioelectrocatalysts --- oxidoreductases --- biocatalytic reactors --- electrochemical reactors --- bioelectrocatalysis --- nanostructured electrodes --- protein engineering --- bioelectrosynthesis --- photo-bioelectrocatalysis --- membrane protein --- electrode modification --- biofuel cells --- photosynthesis --- liposomes --- hybrid vesicles --- microbial electrosynthesis --- direct electron transfer --- orientation --- carbon nanomaterials --- surface modification --- self-assembled molecular monolayers --- electron transfer --- oxidoreductase --- gold electrode --- metallic nanostructures --- enzyme --- metalloenzyme --- catalysis --- stability --- electrochemistry --- bioelectrochemistry --- n/a

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A new science emerges at the intersection of modern physics, computer s- ence,andmaterialscience. Thestruggletofurtherminiaturizeisputtingna- technology to the verge of creating single-electron and/or single-spin devices that operate by moving a single electron (spin) and can serve as transistors, memory cells, and for logic gates. These devices take advantage of quantum physics that dominates nanometer size scales. The devices that utilize met- based hybrid nanostructures may possess signi?cant advantages over those exploiting purely semiconducting materials. First, the chemistry of metals is typically simpler than that of semiconductors. Second, the electric properties of metals are much less sensitive to the structural defects and impurities than those of semiconductors. Next, metallic devices allow better electric and th- mal contacts. Another important plus point is that in metals the electron de Broigle wavelength is smaller by many orders of magnitude as compared to that in semiconductors. This makes metallic devices more promising with respect to their size - down to the size of an atom. Further, high bulk and interface thermal conductance in metallic devices are bene?cial for the heat withdraw. And, last but by no means the least, the high electron velocity in metals promises to accelerate enormously operation rates with respect to those in semiconductor-based devices. The ?nal note is that metals can - hibit strong ferromagnetism and/or superconductivity.

Quantum theory --- Transport theory --- Nanostructured materials --- Physics. --- Quantum physics. --- Condensed matter. --- Superconductivity. --- Superconductors. --- Magnetism. --- Magnetic materials. --- Quantum computers. --- Spintronics. --- Quantum Physics. --- Condensed Matter Physics. --- Strongly Correlated Systems, Superconductivity. --- Magnetism, Magnetic Materials. --- Quantum Information Technology, Spintronics. --- Magnetoelectronics --- Spin electronics --- Microelectronics --- Nanotechnology --- Computers --- Materials --- Mathematical physics --- Physics --- Electricity --- Magnetics --- Superconducting materials --- Superconductive devices --- Cryoelectronics --- Electronics --- Solid state electronics --- Electric conductivity --- Critical currents --- Superfluidity --- Condensed materials --- Condensed media --- Condensed phase --- Materials, Condensed --- Media, Condensed --- Phase, Condensed --- Liquids --- Matter --- Solids --- Quantum dynamics --- Quantum mechanics --- Quantum physics --- Mechanics --- Thermodynamics --- Natural philosophy --- Philosophy, Natural --- Physical sciences --- Dynamics --- Quantum theory. --- Fluxtronics --- Spinelectronics --- Quantum transport --- Metallic nanostructures --- Hybrid nanostructures --- NATO