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Dissertation
Master thesis : Mineralogical and geometallurgical evaluation of the final flotation tailing at DPM-Chelopech in view of their environmental behaviour and paste to fill properties (Université de Liège)
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Year: 2019 Publisher: Liège Université de Liège (ULiège)

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Abstract

Acid mine drainage (AMD) is one of the biggest environmental issues faced by the mining industry. The concerns towards AMD rises when the waste rock and tailings are enriched in pyrite and/or pyrrhotite. The presence of trace of heavy metals bearing minerals increases the environmental hazard of such material. And the large volume of solid waste produced during operation leads to a
high pollution risk.
AMD is characterized by the release of acidic runoff water enriched in sulfate and metals. However, the impacts associated with AMD are beyond environmental, besides disturbing aquatic life and contaminating soil and water streams, the areas affected by AMD faces the visual impact associated with its characteristic “ochre” color and can have their water supply or tourism affected by the
pollution. Additionally, the expenditures to recover these sites are extremely high. A reliable AMD
assessment is crucial to design an appropriate tailings management strategy capable of preventing AMD generation and a suitable rehabilitation plan able to reduce the footprint of such operations in the surrounding areas.
The oxidation of iron-bearing sulfides (pyrite, pyrrhotite and marcasite) occurs naturally when in
contact with moister and oxygen, however, mining increases the exposure of these rocks whereas the comminution process increases the reactivity of the minerals by affecting its degree of liberation
and particle size. Hence, the oxidation process is enhanced by mining operations. Acid mine drainage generation depends mainly on the ability of neutralizing minerals to buffer the acidity produced by pyrite oxidation. Besides that, particle size and liberation degree define the reactivity of the acidproducing and acid-neutralizing phases. Hence, these parameters influence the oxidation rate and the overall geochemical evolution of the leachate released.
The traditional methods used to assess AMD does not consider particle size and liberation degree. However, to achieve a reliable AMD prediction, account to these parameters are of utmost importance. This master thesis aims to analyze the effect of liberation degree in AMD generation using tailings coming from Dundee Precious Metals Chelopech (DPM-Ch). The tailings produced by the concentration process in DPM-Ch is characterized by enrichment in pyrite. Quartz and kaolinite are the main non-sulfide gangue whereas no carbonate mineral is present in the ore. Thus, no neutralizing mineral is present in the tailing assemblage. Moreover, the presence of trace arsenic bearing minerals which are not recovered during the process increases the environmental concern toward this material. Particularly because this element is mobile under acidic conditions and can be toxic to humans, plants and animals in low concentration.
To achieve this objective an integrated approach, that combined process mineralogy techniques and geochemical testwork (static and kinetic test), was used to assess the AMD potential of the tailings from DPM-Ch processing plant. Samples from the tailings management facility (TMF) were collected and pyrite flotation was performed aiming to recover the free pyrite while the locked pyrite remained in the tailings. Thereafter, SEM-EDS analysis was done to characterize each flotation stream regarding its modal mineralogy, liberation degree and particle size. Geochemical tests (static and kinetic tests) were performed in the pre-floated samples and tailings after pyrite flotation. The results showed that the reactivity of the tailings is highly dependent on the liberation degree and that the finer fraction dictates the overall geochemical behavior of the material.
Furthermore, 40% of the tailings produced in Chelopech is used to backfill the stopes. This technique enhances the productivity of the mine, increases the safety of the underground workplace and decreases the volume of tailings being handled on the surface. In addition to that, the cemented paste has the potential of decreasing pyrite reactivity by encapsulating this mineral inside a cemented matrix. However, a proper study of the geochemical behavior of the paste should be conducted to evaluate the environmental performance of the cemented paste backfill (CPB). This was done by using monolithic leaching test (MLT) and mineralogical analysis. The results showed that the calcium phases present in the cement buffer the acidic water that percolates the stopes. Likewise, this technique may reduce pyrite oxidation.


Book
Measurement of the Environmental Impact of Materials
Authors: ---
ISBN: 3036559833 3036559841 Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Throughout their life cycles—from production, usage, through to disposal—materials and products interact with the environment (water, soil, and air). At the same time, they are exposed to environmental influences and, through their emissions, have an impact on the environment, people, and health. Accelerated experimental testing processes can be used to predict the long-term environmental consequences of innovative products before these actually enter the environment. We are living in a material world. Building materials, geosynthetics, wooden toys, soil, nanomaterials, composites, wastes and more are research subjects examined by the authors of this book. The interactions of materials with the environment are manifold. Therefore, it is important to assess the environmental impact of these interactions. Some answers to how this task can be achieved are given in this Special Issue.

Keywords

Research & information: general --- Environmental economics --- environmental simulations --- polymer-based products --- artificial weathering --- degradation --- leaching --- soil contact --- carbon concrete composite --- irrigated construction elements --- environmental compatibility --- irrigated building materials --- environmental assessment --- evaluation concepts --- bio-based insulation --- earthen building materials --- volatile organic compounds --- semi-volatile organic compounds --- formaldehyde --- radon --- wooden toys --- emission test chamber --- flask method --- EN 717-3 --- microchamber --- Enchytraeids --- waterproof building materials --- ecotoxicology --- biotest --- geosynthetics --- geotextiles --- dynamic surface leaching test --- artificial ageing --- marine littering --- batch leaching test --- liquid-solid ratio --- column percolation test --- advection-dispersion model --- adsorption–desorption equilibrium --- clinoptilolite --- soil --- water --- CEC --- specific surface --- zeolitization --- hydrogen storage --- kinetics --- material life cycle assessment --- Eco-Indicator 99’ --- CML 2001 --- calcium phosphate --- calcium carbonate --- recycling --- environmental problems --- seashell --- leaching test --- equilibrium condition --- non-equilibrium condition --- modelling --- sorption kinetics --- non-linear sorption --- heterogeneity --- mineral recycling material --- compliance testing --- nano titanium dioxide (nTiO2) --- engineered nanomaterial (ENM) --- sewage sludge incineration (SSI) --- ENM containing sewage sludge ash (SSA) --- column elution --- agricultural use --- n/a --- adsorption-desorption equilibrium --- Eco-Indicator 99'


Book
Urban Hydrogeology Studies
Author:
Year: 2022 Publisher: Basel MDPI Books

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Abstract

Urbanization worldwide is a pervasive phenomenon of our time, and sustainable urban development is one of the greatest challenges faced by the contemporary world. The subsurface plays a range of roles in such developments through the complex processes of urbanization, including building development, constructing roads, and providing water supplies, drainage, sanitation, and even solid waste disposal.Urban groundwater problems are usually predictable; however, they are not predicted early enough. During recent decades, progressive advances in the scientific understanding of urban hydrogeological processes and the groundwater regimes of a substantial number of cities have been documented. This extensive array of subsurface challenges that cities have to contend with lies at the core of the sustainability of the urban water cycle. This is threatened by the increasing scale and downward extent of urban subsurface construction, including utilities (cables, sewage, and drainage), transportation (tunnels, passages), and storage (cellars, parking lots, and thermal energy). The cumulative impact of this subsurface congestion on the surrounding geology, and especially on the groundwater system, has to be constantly studied and addressed.In this volume, key connections amongst urban hydrogeology activities are identified as being consistent with scientific results and good practices in their relationship to subsurface data and knowledge on subsurface systems. The volume supports a useful dialogue between the providers and consumers of urban groundwater data and knowledge, offering new perspectives on the existing research themes.


Book
Urban Hydrogeology Studies
Author:
Year: 2022 Publisher: Basel MDPI Books

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Abstract

Urbanization worldwide is a pervasive phenomenon of our time, and sustainable urban development is one of the greatest challenges faced by the contemporary world. The subsurface plays a range of roles in such developments through the complex processes of urbanization, including building development, constructing roads, and providing water supplies, drainage, sanitation, and even solid waste disposal.Urban groundwater problems are usually predictable; however, they are not predicted early enough. During recent decades, progressive advances in the scientific understanding of urban hydrogeological processes and the groundwater regimes of a substantial number of cities have been documented. This extensive array of subsurface challenges that cities have to contend with lies at the core of the sustainability of the urban water cycle. This is threatened by the increasing scale and downward extent of urban subsurface construction, including utilities (cables, sewage, and drainage), transportation (tunnels, passages), and storage (cellars, parking lots, and thermal energy). The cumulative impact of this subsurface congestion on the surrounding geology, and especially on the groundwater system, has to be constantly studied and addressed.In this volume, key connections amongst urban hydrogeology activities are identified as being consistent with scientific results and good practices in their relationship to subsurface data and knowledge on subsurface systems. The volume supports a useful dialogue between the providers and consumers of urban groundwater data and knowledge, offering new perspectives on the existing research themes.


Book
Urban Hydrogeology Studies
Author:
Year: 2022 Publisher: Basel MDPI Books

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Abstract

Urbanization worldwide is a pervasive phenomenon of our time, and sustainable urban development is one of the greatest challenges faced by the contemporary world. The subsurface plays a range of roles in such developments through the complex processes of urbanization, including building development, constructing roads, and providing water supplies, drainage, sanitation, and even solid waste disposal.Urban groundwater problems are usually predictable; however, they are not predicted early enough. During recent decades, progressive advances in the scientific understanding of urban hydrogeological processes and the groundwater regimes of a substantial number of cities have been documented. This extensive array of subsurface challenges that cities have to contend with lies at the core of the sustainability of the urban water cycle. This is threatened by the increasing scale and downward extent of urban subsurface construction, including utilities (cables, sewage, and drainage), transportation (tunnels, passages), and storage (cellars, parking lots, and thermal energy). The cumulative impact of this subsurface congestion on the surrounding geology, and especially on the groundwater system, has to be constantly studied and addressed.In this volume, key connections amongst urban hydrogeology activities are identified as being consistent with scientific results and good practices in their relationship to subsurface data and knowledge on subsurface systems. The volume supports a useful dialogue between the providers and consumers of urban groundwater data and knowledge, offering new perspectives on the existing research themes.


Book
Polymeric Foams
Authors: ---
ISBN: 3039216333 3039216325 Year: 2019 Publisher: MDPI - Multidisciplinary Digital Publishing Institute

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Advances in nanotechnology have boosted the development of more efficient materials, with emerging sectors (electronics, energy, aerospace, etc.) demanding novel materials to fulfill the complex technical requirements of their products. This is the case of polymeric foams, which may display good structural properties alongside functional characteristics through a complex composition and (micro)structure in which a gas phase is combined with rigid ones, mainly based on nanoparticles, dispersed throughout the polymer matrix. In recent years, there has been an important impulse in the development of nanocomposite foams, extending the concept of nanocomposites to the field of cellular materials. This, alongside developments in new advanced foaming technologies which have allowed the generation of foams with micro, sub-micro, and even nanocellular structures, has extended the applications of more traditional foams in terms of weight reduction, damping, and thermal and/or acoustic insulation to novel possibilities, such as electromagnetic interference (EMI) shielding. This Special Issue, which consists of a total of 22 articles, including one review article written by research groups of experts in the field, considers recent research on novel polymer-based foams in all their aspects: design, composition, processing and fabrication, microstructure, characterization and analysis, applications and service behavior, recycling and reuse, etc.

Keywords

graphene oxide --- n/a --- microstructure --- multi-objective particle swarm optimization --- electromagnetic wave absorption --- polyamide --- lignin --- expandable microspheres --- surfactants --- aluminum microfibers --- biomaterials --- permittivity --- compression properties --- shock compression --- syntactic foams --- 1 --- impact wedge–peel test --- phenolic foams --- 3 --- foam extrusion --- energy conservation --- heat transfer --- heterogeneous nucleation --- polyurethane foam --- leaching test --- functional --- cellulose foam --- impact property --- foam injection molding --- itaconic acid --- composites --- foaming quality --- phosphorus flame retardants --- polymer waste --- metallic tube --- 5-benzene-trisamides --- polyurethane foam composites --- polyetherimide foams --- scCO2 --- Ethylene Propylene Diene Monomer --- thermal conductivity --- ethyl cellulose --- super critical CO2 --- thermal insulation --- cell nucleation --- crystalline --- polypropylene --- PZT --- burning characteristic --- foams --- quasi-static compression tests --- flame-retardant ABS microcellular foams --- nanotubes --- conductivity --- energy absorption capability --- intrinsic toughness --- ternary synergistic effect --- multilayers --- absorbent PMI foam --- semi-rigid polyurethane foams --- phosphorus --- EMI --- supramolecular additives --- MuCell® injection-molding foaming --- piezocomposite --- ultrasonication --- scCO2 foaming --- automobile structural adhesives --- thermogravimetric analysis --- rigid polyurethane foam --- failure mechanism --- mechanical properties --- multifunctional foams --- SANS --- fluoelastomer --- sound absorption coefficient --- acoustic performances --- functional foam --- foam morphology --- mechanical property --- polystyrene foams --- piezoelectric --- graphene --- Pluronic --- epoxy composite foam adhesive --- polymers --- flame retardancy --- core–shell rubber --- extrusion foaming --- equation of state --- cellulose nanofiber --- epoxy --- DOPO --- PUR --- grey relational analysis --- activation energies --- adjacent façade --- electrical conductivity --- impact wedge-peel test --- core-shell rubber --- adjacent façade

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