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This Reprint Book highlights and overviews the most important and novel aspects of chiral auxiliary and chirogenesis in different natural/physical sciences and in modern technologies. In particular, some newly emerging classes of molecules used for these purposes have been described. Furthermore, some important experimental and theoretical issues associated with the chirality field have been addressed. This book consists of one review article and six research papers and is of interest for general chemistry readership, including graduate and post-graduate students, and for researchers specializing in the fields of chirality and stereochemistry
pillar[5]arene --- planar chirality --- chiral resolution --- racemization kinetics --- supramolecular chemistry --- self-induced diastereomeric anisochronism (SIDA) --- enantiomeric analysis --- molecular association --- NMR --- diffusion --- molecular chirality --- self-disproportionation of enantiomers (SDE) --- indole --- asymmetric synthesis --- organocatalysis --- transition-metal catalysis --- C-N bond formation --- enantioselective --- heterocycles --- porphyrinoids --- multinuclear complexes --- chiral ligands --- circular dichroism --- paramagnetic NMR --- magnetochemistry --- porphyrin --- guanidine --- host–guest binding --- chirality --- DFT --- TD-DFT simulation --- induced optical activity --- stereodynamic chirality probe --- exciton coupling --- circularly polarized luminescence --- sergeants-and-soldiers --- majority-rule --- polysilane --- polyfluorenevinylene --- polyfluorene --- mirror symmetry breaking --- parity violation --- n/a --- host-guest binding
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This Reprint Book highlights and overviews the most important and novel aspects of chiral auxiliary and chirogenesis in different natural/physical sciences and in modern technologies. In particular, some newly emerging classes of molecules used for these purposes have been described. Furthermore, some important experimental and theoretical issues associated with the chirality field have been addressed. This book consists of one review article and six research papers and is of interest for general chemistry readership, including graduate and post-graduate students, and for researchers specializing in the fields of chirality and stereochemistry
Research & information: general --- pillar[5]arene --- planar chirality --- chiral resolution --- racemization kinetics --- supramolecular chemistry --- self-induced diastereomeric anisochronism (SIDA) --- enantiomeric analysis --- molecular association --- NMR --- diffusion --- molecular chirality --- self-disproportionation of enantiomers (SDE) --- indole --- asymmetric synthesis --- organocatalysis --- transition-metal catalysis --- C-N bond formation --- enantioselective --- heterocycles --- porphyrinoids --- multinuclear complexes --- chiral ligands --- circular dichroism --- paramagnetic NMR --- magnetochemistry --- porphyrin --- guanidine --- host-guest binding --- chirality --- DFT --- TD-DFT simulation --- induced optical activity --- stereodynamic chirality probe --- exciton coupling --- circularly polarized luminescence --- sergeants-and-soldiers --- majority-rule --- polysilane --- polyfluorenevinylene --- polyfluorene --- mirror symmetry breaking --- parity violation
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The search for bioactive marine natural products calls for the need of efficient chemical profiling strategies, together with the need to make advances in separation and characterization methodologies, in order to expedite their discovery. This Special Issue of Marine Drugs aims to highlight advances in extraction, isolation, purification and dereplication methodologies in the quest for bioactive marine natural products.
Research & information: general --- Chaceon quinquedens --- cold water species --- red deep-sea crab --- insulin-like androgenic gland hormone (IAG) --- androgenic gland --- bioguided-discovery --- dereplication --- cytotoxicity --- antifungal --- MS/HRMS --- marine-derived --- pimarane-type diterpenoids --- ilicicolin H --- trichothecene mycotoxins --- roridin --- verrucarin --- high-speed countercurrent chromatography --- preparative separation --- stepwise elution --- Eustigmatos cf. polyphem --- violaxanthin --- culture conditions --- purification --- antioxidant activity --- Mosher --- retroflexanone --- phloroglucinol --- HPLC-NMR --- secondary alcohol --- cephalimysins --- Aspergillus fumigatus --- marine microorganism --- Mugil cephalus --- spiro-heterocyclic γ-lactam --- circular dichroism spectroscopy --- hydroxypropyltrimethyl ammonium chloride chitosan --- halogenated acetate --- antifungal activity --- electronegativity --- microalgae --- Haematococcus pluvialis --- astaxanthin --- lutein --- fatty acids --- supercritical fluid extraction --- natural medicines --- chondroitin sulfate production --- cartilage Galeus melastomus by-products --- sulfation patterns --- process optimization --- molecular weight glycosaminoglycans determination --- bycatch waste management --- electronic circular dichroism --- absolute configuration --- molecular conformation --- electric transition dipole moment --- exciton coupling --- TDDFT calculations
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The search for bioactive marine natural products calls for the need of efficient chemical profiling strategies, together with the need to make advances in separation and characterization methodologies, in order to expedite their discovery. This Special Issue of Marine Drugs aims to highlight advances in extraction, isolation, purification and dereplication methodologies in the quest for bioactive marine natural products.
Chaceon quinquedens --- cold water species --- red deep-sea crab --- insulin-like androgenic gland hormone (IAG) --- androgenic gland --- bioguided-discovery --- dereplication --- cytotoxicity --- antifungal --- MS/HRMS --- marine-derived --- pimarane-type diterpenoids --- ilicicolin H --- trichothecene mycotoxins --- roridin --- verrucarin --- high-speed countercurrent chromatography --- preparative separation --- stepwise elution --- Eustigmatos cf. polyphem --- violaxanthin --- culture conditions --- purification --- antioxidant activity --- Mosher --- retroflexanone --- phloroglucinol --- HPLC-NMR --- secondary alcohol --- cephalimysins --- Aspergillus fumigatus --- marine microorganism --- Mugil cephalus --- spiro-heterocyclic γ-lactam --- circular dichroism spectroscopy --- hydroxypropyltrimethyl ammonium chloride chitosan --- halogenated acetate --- antifungal activity --- electronegativity --- microalgae --- Haematococcus pluvialis --- astaxanthin --- lutein --- fatty acids --- supercritical fluid extraction --- natural medicines --- chondroitin sulfate production --- cartilage Galeus melastomus by-products --- sulfation patterns --- process optimization --- molecular weight glycosaminoglycans determination --- bycatch waste management --- electronic circular dichroism --- absolute configuration --- molecular conformation --- electric transition dipole moment --- exciton coupling --- TDDFT calculations
Choose an application
The search for bioactive marine natural products calls for the need of efficient chemical profiling strategies, together with the need to make advances in separation and characterization methodologies, in order to expedite their discovery. This Special Issue of Marine Drugs aims to highlight advances in extraction, isolation, purification and dereplication methodologies in the quest for bioactive marine natural products.
Research & information: general --- Chaceon quinquedens --- cold water species --- red deep-sea crab --- insulin-like androgenic gland hormone (IAG) --- androgenic gland --- bioguided-discovery --- dereplication --- cytotoxicity --- antifungal --- MS/HRMS --- marine-derived --- pimarane-type diterpenoids --- ilicicolin H --- trichothecene mycotoxins --- roridin --- verrucarin --- high-speed countercurrent chromatography --- preparative separation --- stepwise elution --- Eustigmatos cf. polyphem --- violaxanthin --- culture conditions --- purification --- antioxidant activity --- Mosher --- retroflexanone --- phloroglucinol --- HPLC-NMR --- secondary alcohol --- cephalimysins --- Aspergillus fumigatus --- marine microorganism --- Mugil cephalus --- spiro-heterocyclic γ-lactam --- circular dichroism spectroscopy --- hydroxypropyltrimethyl ammonium chloride chitosan --- halogenated acetate --- antifungal activity --- electronegativity --- microalgae --- Haematococcus pluvialis --- astaxanthin --- lutein --- fatty acids --- supercritical fluid extraction --- natural medicines --- chondroitin sulfate production --- cartilage Galeus melastomus by-products --- sulfation patterns --- process optimization --- molecular weight glycosaminoglycans determination --- bycatch waste management --- electronic circular dichroism --- absolute configuration --- molecular conformation --- electric transition dipole moment --- exciton coupling --- TDDFT calculations
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