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This book has focused on novel developments and advancements in the field of heterogeneous catalysis with the aim of greenhouse gas reduction. The book determines whether carbon dioxide is a crisis or an opportunity, as well as its conversion into useful products such as synthesis gas. Moreover, the selective catalytic removal of nitrogen oxides is also presented.
Al2O3 --- CO2 reforming --- La2O3 --- CH4 --- ZrO2 --- perovskites --- strontium --- cerium --- hydrogen --- sintering --- carbon deposition --- BiF3 nanostructure --- POP composite --- photocatalyst --- Rz ink --- CO2 --- stability --- H-ZSM-5 --- greenhouse gas reduction --- CeO2 --- MgO --- dry reforming --- heterogeneous catalysis --- in situ XRD --- carbon dioxide (CO2) --- carbon monoxide (CO) --- CO2 feedstock --- methanation --- catalyst --- catalysis --- photocatalysis --- Power-to-Gas --- catalyst design --- heterogenous catalysts database --- ceramic foams --- ZnO nanorods --- TiO2 nanorods --- NOx mitigation (deNOx) --- environmental nanocatalysis --- selective catalytic reduction SCR --- W and V catalytic sites --- n/a
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This book has focused on novel developments and advancements in the field of heterogeneous catalysis with the aim of greenhouse gas reduction. The book determines whether carbon dioxide is a crisis or an opportunity, as well as its conversion into useful products such as synthesis gas. Moreover, the selective catalytic removal of nitrogen oxides is also presented.
Technology: general issues --- Chemical engineering --- Al2O3 --- CO2 reforming --- La2O3 --- CH4 --- ZrO2 --- perovskites --- strontium --- cerium --- hydrogen --- sintering --- carbon deposition --- BiF3 nanostructure --- POP composite --- photocatalyst --- Rz ink --- CO2 --- stability --- H-ZSM-5 --- greenhouse gas reduction --- CeO2 --- MgO --- dry reforming --- heterogeneous catalysis --- in situ XRD --- carbon dioxide (CO2) --- carbon monoxide (CO) --- CO2 feedstock --- methanation --- catalyst --- catalysis --- photocatalysis --- Power-to-Gas --- catalyst design --- heterogenous catalysts database --- ceramic foams --- ZnO nanorods --- TiO2 nanorods --- NOx mitigation (deNOx) --- environmental nanocatalysis --- selective catalytic reduction SCR --- W and V catalytic sites
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This book has focused on novel developments and advancements in the field of heterogeneous catalysis with the aim of greenhouse gas reduction. The book determines whether carbon dioxide is a crisis or an opportunity, as well as its conversion into useful products such as synthesis gas. Moreover, the selective catalytic removal of nitrogen oxides is also presented.
Technology: general issues --- Chemical engineering --- Al2O3 --- CO2 reforming --- La2O3 --- CH4 --- ZrO2 --- perovskites --- strontium --- cerium --- hydrogen --- sintering --- carbon deposition --- BiF3 nanostructure --- POP composite --- photocatalyst --- Rz ink --- CO2 --- stability --- H-ZSM-5 --- greenhouse gas reduction --- CeO2 --- MgO --- dry reforming --- heterogeneous catalysis --- in situ XRD --- carbon dioxide (CO2) --- carbon monoxide (CO) --- CO2 feedstock --- methanation --- catalyst --- catalysis --- photocatalysis --- Power-to-Gas --- catalyst design --- heterogenous catalysts database --- ceramic foams --- ZnO nanorods --- TiO2 nanorods --- NOx mitigation (deNOx) --- environmental nanocatalysis --- selective catalytic reduction SCR --- W and V catalytic sites --- n/a
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The important advances achieved over the past years in all technological directions (industry, energy, and health) contributing to human well-being are unfortunately, in many cases, accompanied by a threat to the environment, with photochemical smog, stratospheric ozone depletion, acid rain, global warming, and finally climate change being the most well-known major issues. These are the results of a variety of pollutants emitted through these human activities. The indications show that we are already at a tipping point that might lead to non-linear and sudden environmental change on a global scale. Aiming to tackle these adverse effects in an attempt to mitigate any damage that has already occurred and to ensure that we are heading toward a cleaner (green) and sustainable future, scientists around the world are developing tools and techniques to understand, monitor, protect, and improve the environment. Emissions control catalysis is continuously advancing, providing novel, multifunctional, and optimally promoted using a variety of methods, nano-structured catalytic materials, and strategies (e.g., energy chemicals recycling, cyclic economy) that enable us to effectively control emissions, either of mobile or stationary sources, improving the quality of air (outdoor and indoor) and water and the energy economy. Representative cases include the abatement and/or recycling of CO2, CO, NOx, N2O, NH3, CH4, higher hydrocarbons, volatile organic compounds (VOCs), particulate matter, and specific industrial emissions (e.g., SOx, H2S, dioxins aromatics, and biogas). The “Emissions Control Catalysis” Special Issue has succeeded in collecting 22 high-quality contributions, included in this MDPI open access book, covering recent research progress in a variety of fields relevant to the above topics and/or applications, mainly on: (i) NOx catalytic reduction from cars (i.e., TWC) and industry (SCR) emissions; (ii) CO, CH4, and other hydrocarbons removal, and (iii) CO2 capture/recirculation combining emissions control with added-value chemicals production.
LNT --- NSR --- NOx storage --- phosphorous --- deactivation --- poisoning --- electrochemical reduction --- CO2 --- CuO --- TiO2 --- ethanol --- cerium-doped titania --- sulfur-tolerant materials --- organic compounds purification --- diesel oxidation catalyst --- vehicle exhaust --- chemical looping reforming --- hydrogen --- oxygen carrier --- CeO2 --- nanorod --- selective catalytic reduction --- nitric oxide --- ammonia --- Cu/ZSM-5 --- cerium --- zirconium --- CO2 electroreduction --- CO2 valorization --- Cu catalyst --- particle size --- PEM --- acetaldehyde production --- methanol production --- Ce-based catalyst --- stepwise precipitation --- diesel exhaust --- nitrogen oxides abatement --- electrochemical promotion --- NEMCA --- palladium --- ionic promoter --- nanoparticles --- yttria-stabilized zirconia --- direct NO decomposition --- PGM oxide promotion --- PdO vs. PtO --- in-situ FT-IR --- NO adsorption properties --- redox properties --- sintered ore catalyst --- sulfate --- In-situ DRIFTS --- SCR --- copper-ceria catalysts --- hydrothermal method --- CO oxidation --- copper clusters --- nanoceria --- SOECs --- RWGS reaction kinetics --- Au–Mo–Fe-Ni/GDC electrodes --- high temperature H2O/CO2 co-electrolysis --- platinum --- Rhodium --- iridium --- NO --- N2O --- propene --- CO --- methane --- alkali --- alkaline earth --- platinum group metals --- deNOx chemistry --- lean burn conditions --- TWC --- catalyst promotion --- EPOC --- NH3-SCR --- nanostructure --- kinetics --- thermodynamics --- manganese oxides --- Co3O4 --- complete CH4 oxidation --- hydrothermal synthesis --- precipitation --- Pd/BEA --- Cold start --- Pd species --- NOx abatement --- ammonia oxidation --- response surface methodology --- desirability function --- Box-Behnken design --- carbon dioxide --- hydrogenation --- heterogeneous catalysis --- plasma catalysis --- value-added chemicals --- methanol synthesis --- methanation --- Catalyst --- (NH4)2SO4 --- deNOx --- H2O and SO2 poisoning --- low-temperature selective catalytic reduction --- de-NOx catalysis --- SO2/H2O tolerance --- transition metal-based catalysts --- perovskite --- catalytic coating --- cathodic sputtering method --- n/a --- Au-Mo-Fe-Ni/GDC electrodes
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The important advances achieved over the past years in all technological directions (industry, energy, and health) contributing to human well-being are unfortunately, in many cases, accompanied by a threat to the environment, with photochemical smog, stratospheric ozone depletion, acid rain, global warming, and finally climate change being the most well-known major issues. These are the results of a variety of pollutants emitted through these human activities. The indications show that we are already at a tipping point that might lead to non-linear and sudden environmental change on a global scale. Aiming to tackle these adverse effects in an attempt to mitigate any damage that has already occurred and to ensure that we are heading toward a cleaner (green) and sustainable future, scientists around the world are developing tools and techniques to understand, monitor, protect, and improve the environment. Emissions control catalysis is continuously advancing, providing novel, multifunctional, and optimally promoted using a variety of methods, nano-structured catalytic materials, and strategies (e.g., energy chemicals recycling, cyclic economy) that enable us to effectively control emissions, either of mobile or stationary sources, improving the quality of air (outdoor and indoor) and water and the energy economy. Representative cases include the abatement and/or recycling of CO2, CO, NOx, N2O, NH3, CH4, higher hydrocarbons, volatile organic compounds (VOCs), particulate matter, and specific industrial emissions (e.g., SOx, H2S, dioxins aromatics, and biogas). The “Emissions Control Catalysis” Special Issue has succeeded in collecting 22 high-quality contributions, included in this MDPI open access book, covering recent research progress in a variety of fields relevant to the above topics and/or applications, mainly on: (i) NOx catalytic reduction from cars (i.e., TWC) and industry (SCR) emissions; (ii) CO, CH4, and other hydrocarbons removal, and (iii) CO2 capture/recirculation combining emissions control with added-value chemicals production.
Research & information: general --- Environmental economics --- Pollution control --- LNT --- NSR --- NOx storage --- phosphorous --- deactivation --- poisoning --- electrochemical reduction --- CO2 --- CuO --- TiO2 --- ethanol --- cerium-doped titania --- sulfur-tolerant materials --- organic compounds purification --- diesel oxidation catalyst --- vehicle exhaust --- chemical looping reforming --- hydrogen --- oxygen carrier --- CeO2 --- nanorod --- selective catalytic reduction --- nitric oxide --- ammonia --- Cu/ZSM-5 --- cerium --- zirconium --- CO2 electroreduction --- CO2 valorization --- Cu catalyst --- particle size --- PEM --- acetaldehyde production --- methanol production --- Ce-based catalyst --- stepwise precipitation --- diesel exhaust --- nitrogen oxides abatement --- electrochemical promotion --- NEMCA --- palladium --- ionic promoter --- nanoparticles --- yttria-stabilized zirconia --- direct NO decomposition --- PGM oxide promotion --- PdO vs. PtO --- in-situ FT-IR --- NO adsorption properties --- redox properties --- sintered ore catalyst --- sulfate --- In-situ DRIFTS --- SCR --- copper-ceria catalysts --- hydrothermal method --- CO oxidation --- copper clusters --- nanoceria --- SOECs --- RWGS reaction kinetics --- Au-Mo-Fe-Ni/GDC electrodes --- high temperature H2O/CO2 co-electrolysis --- platinum --- Rhodium --- iridium --- NO --- N2O --- propene --- CO --- methane --- alkali --- alkaline earth --- platinum group metals --- deNOx chemistry --- lean burn conditions --- TWC --- catalyst promotion --- EPOC --- NH3-SCR --- nanostructure --- kinetics --- thermodynamics --- manganese oxides --- Co3O4 --- complete CH4 oxidation --- hydrothermal synthesis --- precipitation --- Pd/BEA --- Cold start --- Pd species --- NOx abatement --- ammonia oxidation --- response surface methodology --- desirability function --- Box-Behnken design --- carbon dioxide --- hydrogenation --- heterogeneous catalysis --- plasma catalysis --- value-added chemicals --- methanol synthesis --- methanation --- Catalyst --- (NH4)2SO4 --- deNOx --- H2O and SO2 poisoning --- low-temperature selective catalytic reduction --- de-NOx catalysis --- SO2/H2O tolerance --- transition metal-based catalysts --- perovskite --- catalytic coating --- cathodic sputtering method
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Catalyst lifetime represents one of the most crucial economic aspects in industrial catalytic processes, due to costly shutdowns, catalyst replacements, and proper disposal of spent materials. Not surprisingly, there is considerable motivation to understand and treat catalyst deactivation, poisoning, and regeneration, which causes this research topic to continue to grow. The complexity of catalyst poisoning obviously increases along with the increasing use of biomass/waste-derived/residual feedstocks and with requirements for cleaner and novel sustainable processes. This book collects 15 research papers providing insights into several scientific and technical aspects of catalyst poisoning and deactivation, proposing more tolerant catalyst formulations, and exploring possible regeneration strategies.
cyclic operation --- n/a --- nickel catalysts --- regeneration --- Cu/SSZ-13 --- syngas --- NH3-SCR --- oxysulfate --- Ni-catalyst --- MW incinerator --- iso-octane --- hydrogenation --- dry reforming of methane --- oxysulfide --- Co-Zn/H-Beta --- Low-temperature catalyst --- Rh catalysts --- deactivation --- vanadia species --- SO2 poisoning --- vehicle emission control --- barium carbonate --- sodium ions --- sulfur deactivation --- tetragonal zirconia --- sulfur poisoning --- Liquefied natural gas --- water --- deactivation by coking --- phase stabilization --- catalyst --- NO removal --- physico-chemical characterization --- octanol --- SEM --- aluminum sulfate --- oxygen storage capacity --- unusual deactivation --- diesel --- nitrous oxide --- exhaust gas --- over-reduction --- poisoning --- catalyst deactivation --- ammonium sulfates --- CO2 reforming --- SO3 --- Rh --- in situ regeneration --- copper --- V2O5–WO3/TiO2 catalysts --- palladium sulfate --- Selective Catalytic Reduction (SCR) --- biogas --- thermal stability --- phthalic anhydride --- octanal --- natural gas --- sulfur-containing sodium salts --- washing --- coke deposition --- vanadia-titania catalyst --- CPO reactor --- homogeneous catalysis --- NOx reduction by C3H8 --- nitrogen oxides --- effect of flow rate --- DeNOx --- catalytic methane combustion --- deactivation mechanism --- TEM --- catalyst durability --- V2O5-WO3/TiO2 catalysts
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