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Coordination polymers.

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The assembly of organic ligands and metal centres yields coordination polymers, many of which find applications in conductivity, catalysis, magnetism, gas sorption, biological sensing and luminescence. The structure and topology of coordination polymers may be manipulated by changing the reaction conditions, leading to a large variety of structurally and topologically unique products. However, controlling and predicting the final outcome of the self-assembly procedure remains one of the major challenges in the field. The final products are often strongly influenced by factors such as the behaviour of a functional group in a molecule, the influence of the crystallization conditions and the various conformations of the components within the crystal. This Special Issue aims to cover a broad range of subjects in coordination polymer chemistry, which are important to the continued growth of the field, showcase current developments and realise its full potential in applications to address major societal challenges. Therefore, we invite you to contribute a research article to this Special Issue and provide a clear snapshot of your research in this field.

Coordination polymers. --- Chelate polymers --- Chelates --- Polymers

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This book is a collection of contributions on the synthesis, characterization, and applications of Metal-Organic Frameworks (MOF) and Coordination Polymers (CP). Coordination Polymers (CP) and Metal–Organic Frameworks (MOF) are at the core of contemporary research on inorganic materials. The virtually infinite combination of their building blocks—inorganic metallic nodes (single ions or clusters) and organic polytopic linkers (polycarboxylates, bridging N-/S-/O-containing heterocycles)—generates solid air- and water-stable compounds. Interesting features from an applicative point of view are porosity, large surface area, and lattice flexibility (the “breathing” effect). These properties make them ubiquitous in several fields of materials science: gas storage and separation, luminescent sensing, heterogeneous catalysis, and magnetism.

Research & information: general --- zirconium-based MOFs --- water adsorption --- ethanol adsorption --- porous materials --- adsorption heat pump --- coordination polymer --- MOF --- CP --- dimensionality control --- Cu(II)-4,4'-bipyridine --- dipyridil ligand --- copper --- metal-organic frameworks --- solid sorbents --- shaping --- gas separation --- gas storage --- water harvesting --- zirconium --- metal-organic framework --- post-synthetic modification --- iridium catalysis --- water oxidation --- water splitting --- thiazole --- thiadiazole --- coordination polymers --- luminescence --- cerium --- terephthalic acid --- spectroscopic characterization --- adsorption --- calorimetry --- carbon dioxide --- Ag(I) complexes --- metal-organic coordination polymers --- thermally activated delayed fluorescence --- phosphorescence --- pyrimidylphosphines --- poly(azolate) spacers --- 1,3-bis(1,2,4-triazol-4-yl)adamantane --- zinc --- cadmium --- crystal structure --- group 12 metals --- 1H-indazole-6-carboxylic acid --- photoluminescence properties --- organometallic --- coordination bonds --- supramolecular chemistry --- catalysis --- zirconium-based MOFs --- water adsorption --- ethanol adsorption --- porous materials --- adsorption heat pump --- coordination polymer --- MOF --- CP --- dimensionality control --- Cu(II)-4,4'-bipyridine --- dipyridil ligand --- copper --- metal-organic frameworks --- solid sorbents --- shaping --- gas separation --- gas storage --- water harvesting --- zirconium --- metal-organic framework --- post-synthetic modification --- iridium catalysis --- water oxidation --- water splitting --- thiazole --- thiadiazole --- coordination polymers --- luminescence --- cerium --- terephthalic acid --- spectroscopic characterization --- adsorption --- calorimetry --- carbon dioxide --- Ag(I) complexes --- metal-organic coordination polymers --- thermally activated delayed fluorescence --- phosphorescence --- pyrimidylphosphines --- poly(azolate) spacers --- 1,3-bis(1,2,4-triazol-4-yl)adamantane --- zinc --- cadmium --- crystal structure --- group 12 metals --- 1H-indazole-6-carboxylic acid --- photoluminescence properties --- organometallic --- coordination bonds --- supramolecular chemistry --- catalysis

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This book is a collection of contributions on the synthesis, characterization, and applications of Metal-Organic Frameworks (MOF) and Coordination Polymers (CP). Coordination Polymers (CP) and Metal–Organic Frameworks (MOF) are at the core of contemporary research on inorganic materials. The virtually infinite combination of their building blocks—inorganic metallic nodes (single ions or clusters) and organic polytopic linkers (polycarboxylates, bridging N-/S-/O-containing heterocycles)—generates solid air- and water-stable compounds. Interesting features from an applicative point of view are porosity, large surface area, and lattice flexibility (the “breathing” effect). These properties make them ubiquitous in several fields of materials science: gas storage and separation, luminescent sensing, heterogeneous catalysis, and magnetism.

zirconium-based MOFs --- water adsorption --- ethanol adsorption --- porous materials --- adsorption heat pump --- coordination polymer --- MOF --- CP --- dimensionality control --- Cu(II)-4,4′-bipyridine --- dipyridil ligand --- copper --- metal–organic frameworks --- solid sorbents --- shaping --- gas separation --- gas storage --- water harvesting --- zirconium --- metal–organic framework --- post-synthetic modification --- iridium catalysis --- water oxidation --- water splitting --- thiazole --- thiadiazole --- coordination polymers --- luminescence --- cerium --- terephthalic acid --- spectroscopic characterization --- adsorption --- calorimetry --- carbon dioxide --- Ag(I) complexes --- metal-organic coordination polymers --- thermally activated delayed fluorescence --- phosphorescence --- pyrimidylphosphines --- poly(azolate) spacers --- 1,3-bis(1,2,4-triazol-4-yl)adamantane --- zinc --- cadmium --- crystal structure --- group 12 metals --- 1H-indazole-6-carboxylic acid --- photoluminescence properties --- organometallic --- coordination bonds --- supramolecular chemistry --- catalysis --- n/a --- Cu(II)-4,4'-bipyridine --- metal-organic frameworks --- metal-organic framework

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Research on molecule-based magnetic materials was systematized in the 1980s and expanded rapidly. A Special Issue focusing on molecule-based magnetic substances was published in Magnetochemistry. However, the functionalities of the substances increase daily; therefore, the researchers’ quest is not yet in decline. Research on molecule-based magnetism developed across many fields, including chemistry, physics, material chemistry, and applied physics, and the use of the various functionalities of these molecule-based magnetic substances has greatly influenced research on spin-based devices. In honor of Professor Masahiro Yamashita, who contributed greatly to this field, I have put together a Special Issue that highlights ten groundbreaking articles. The issue is entitled, “A Themed Issue of Functional Molecule-Based Magnets: Dedicated to Professor Masahiro Yamashita on the Occasion of his 65th Birthday”. I wish to thank the authors for their dedicated work, and the referees and editorial staff for the time they invested commenting on the articles.

pressure effect --- slow magnetic relaxation --- n/a --- graphene oxide --- mixed metal Co/Ln clusters --- X-ray diffraction --- magnetism --- AC susceptibility --- two-dimensional (2D) ferrimagnets --- cobalt --- coordination clusters --- lanthanides --- DFT calculation --- long-range magnetic ordering --- iron complex --- single-molecule magnets --- lanthanide complex --- coordination polymers --- octacyanidoniobate(IV) --- ferromagnetism --- nickel(II) --- heterometallic layers --- single-molecule magnet --- spin crossover --- high pressure --- molecule-based magnets --- chloranilato --- [2 --- crystal structure --- lanthanide ions --- honeycomb layers --- 3d/4f metal clusters --- di-2 pyridyl ketone