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This book entitled “Chemical Symmetry Breaking” is a collective volume of state-of-the-art reports on unique nonlinear chemical and physical symmetry-breaking phenomena that were experimentally observed upon a thermally or photochemically induced phase transition in various organic condensed phases, such as metastable liquid crystals, crystals, amorphous solids, and colloidal polymer materials, only under nonequilibrium conditions. Each author summarizes the introductory section in simple terms but in detail for beginners in this field. We wish that many readers familiarize themselves with the general concepts and features of nonlinear and nonequilibrium (or out of equilibrium) complexity theory, which govern a variety of unique dynamic behaviors observed in chemistry, physics, life science and other fields, so that they may discover novel symmetry-breaking phenomena in their own research areas.

Research & information: general --- amplification of chirality --- dynamic crystallization --- Diels–Alder reaction --- absolute asymmetric synthesis --- conglomerate --- racemization --- attrition-enhanced deracemization --- Viedma ripening --- reversible reaction --- enantiomorphic crystal --- polymorphism --- off-shell quantum field --- space-like momentum --- dressed photon --- micro-macro duality --- Clebsch dual field --- Majorana fermion --- the cosmological term --- Weyl tensor --- dark energy --- dark matter --- photomechanical --- crystal --- right–left symmetry breaking --- chiral symmetry breaking --- dissipative structure --- energy conversion --- mechanical work --- self-oscillation --- collective dynamics --- autonomous motion --- self-replication --- autocatalysis --- molecular motor --- molecular robot --- amorphous-to-crystal phase transformation --- detection of real-time symmetry breaking --- mechanofluorochromism --- fluorescence spectroscopy --- liquid-like cluster --- evaporative crystallization --- quartz crystal microbalance --- two-step nucleation model --- chiral --- circularly polarized luminescence (CPL) --- magnetic circularly polarized luminescence (MCPL) --- spontaneous resolution --- chirality --- deracemization --- preferential enrichment --- thermodynamics --- phase diagrams --- kinetics --- symmetry breaking --- ferroelectricity --- antiferrolelectricity --- subphases --- resonant X-ray scattering --- vapochromism --- fluorescence --- macrocycles --- inclusion crystals --- host–guest chemistry --- spin symmetry breaking --- magnetic liquid crystals --- magneto-LC effect --- nitroxide radicals --- superparamagnetic domain --- spin glass state --- elastic organic crystals --- mechanical deformation --- π-conjugated molecules --- photoluminescence --- deformation-induced photoluminescence changes --- biomolecular handedness --- circular dichroism --- circularly polarized luminescence --- non-equilibrium --- colloid --- conjugated polymer --- amplification of chirality --- dynamic crystallization --- Diels–Alder reaction --- absolute asymmetric synthesis --- conglomerate --- racemization --- attrition-enhanced deracemization --- Viedma ripening --- reversible reaction --- enantiomorphic crystal --- polymorphism --- off-shell quantum field --- space-like momentum --- dressed photon --- micro-macro duality --- Clebsch dual field --- Majorana fermion --- the cosmological term --- Weyl tensor --- dark energy --- dark matter --- photomechanical --- crystal --- right–left symmetry breaking --- chiral symmetry breaking --- dissipative structure --- energy conversion --- mechanical work --- self-oscillation --- collective dynamics --- autonomous motion --- self-replication --- autocatalysis --- molecular motor --- molecular robot --- amorphous-to-crystal phase transformation --- detection of real-time symmetry breaking --- mechanofluorochromism --- fluorescence spectroscopy --- liquid-like cluster --- evaporative crystallization --- quartz crystal microbalance --- two-step nucleation model --- chiral --- circularly polarized luminescence (CPL) --- magnetic circularly polarized luminescence (MCPL) --- spontaneous resolution --- chirality --- deracemization --- preferential enrichment --- thermodynamics --- phase diagrams --- kinetics --- symmetry breaking --- ferroelectricity --- antiferrolelectricity --- subphases --- resonant X-ray scattering --- vapochromism --- fluorescence --- macrocycles --- inclusion crystals --- host–guest chemistry --- spin symmetry breaking --- magnetic liquid crystals --- magneto-LC effect --- nitroxide radicals --- superparamagnetic domain --- spin glass state --- elastic organic crystals --- mechanical deformation --- π-conjugated molecules --- photoluminescence --- deformation-induced photoluminescence changes --- biomolecular handedness --- circular dichroism --- circularly polarized luminescence --- non-equilibrium --- colloid --- conjugated polymer

Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

This book entitled “Chemical Symmetry Breaking” is a collective volume of state-of-the-art reports on unique nonlinear chemical and physical symmetry-breaking phenomena that were experimentally observed upon a thermally or photochemically induced phase transition in various organic condensed phases, such as metastable liquid crystals, crystals, amorphous solids, and colloidal polymer materials, only under nonequilibrium conditions. Each author summarizes the introductory section in simple terms but in detail for beginners in this field. We wish that many readers familiarize themselves with the general concepts and features of nonlinear and nonequilibrium (or out of equilibrium) complexity theory, which govern a variety of unique dynamic behaviors observed in chemistry, physics, life science and other fields, so that they may discover novel symmetry-breaking phenomena in their own research areas.

amplification of chirality --- dynamic crystallization --- Diels–Alder reaction --- absolute asymmetric synthesis --- conglomerate --- racemization --- attrition-enhanced deracemization --- Viedma ripening --- reversible reaction --- enantiomorphic crystal --- polymorphism --- off-shell quantum field --- space-like momentum --- dressed photon --- micro-macro duality --- Clebsch dual field --- Majorana fermion --- the cosmological term --- Weyl tensor --- dark energy --- dark matter --- photomechanical --- crystal --- right–left symmetry breaking --- chiral symmetry breaking --- dissipative structure --- energy conversion --- mechanical work --- self-oscillation --- collective dynamics --- autonomous motion --- self-replication --- autocatalysis --- molecular motor --- molecular robot --- amorphous-to-crystal phase transformation --- detection of real-time symmetry breaking --- mechanofluorochromism --- fluorescence spectroscopy --- liquid-like cluster --- evaporative crystallization --- quartz crystal microbalance --- two-step nucleation model --- chiral --- circularly polarized luminescence (CPL) --- magnetic circularly polarized luminescence (MCPL) --- spontaneous resolution --- chirality --- deracemization --- preferential enrichment --- thermodynamics --- phase diagrams --- kinetics --- symmetry breaking --- ferroelectricity --- antiferrolelectricity --- subphases --- resonant X-ray scattering --- vapochromism --- fluorescence --- macrocycles --- inclusion crystals --- host–guest chemistry --- spin symmetry breaking --- magnetic liquid crystals --- magneto-LC effect --- nitroxide radicals --- superparamagnetic domain --- spin glass state --- elastic organic crystals --- mechanical deformation --- π-conjugated molecules --- photoluminescence --- deformation-induced photoluminescence changes --- biomolecular handedness --- circular dichroism --- circularly polarized luminescence --- non-equilibrium --- colloid --- conjugated polymer

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This Reprint Book highlights and overviews the most important and novel aspects of chiral auxiliary and chirogenesis in different natural/physical sciences and in modern technologies. In particular, some newly emerging classes of molecules used for these purposes have been described. Furthermore, some important experimental and theoretical issues associated with the chirality field have been addressed. This book consists of one review article and six research papers and is of interest for general chemistry readership, including graduate and post-graduate students, and for researchers specializing in the fields of chirality and stereochemistry

Research & information: general --- pillar[5]arene --- planar chirality --- chiral resolution --- racemization kinetics --- supramolecular chemistry --- self-induced diastereomeric anisochronism (SIDA) --- enantiomeric analysis --- molecular association --- NMR --- diffusion --- molecular chirality --- self-disproportionation of enantiomers (SDE) --- indole --- asymmetric synthesis --- organocatalysis --- transition-metal catalysis --- C-N bond formation --- enantioselective --- heterocycles --- porphyrinoids --- multinuclear complexes --- chiral ligands --- circular dichroism --- paramagnetic NMR --- magnetochemistry --- porphyrin --- guanidine --- host-guest binding --- chirality --- DFT --- TD-DFT simulation --- induced optical activity --- stereodynamic chirality probe --- exciton coupling --- circularly polarized luminescence --- sergeants-and-soldiers --- majority-rule --- polysilane --- polyfluorenevinylene --- polyfluorene --- mirror symmetry breaking --- parity violation --- pillar[5]arene --- planar chirality --- chiral resolution --- racemization kinetics --- supramolecular chemistry --- self-induced diastereomeric anisochronism (SIDA) --- enantiomeric analysis --- molecular association --- NMR --- diffusion --- molecular chirality --- self-disproportionation of enantiomers (SDE) --- indole --- asymmetric synthesis --- organocatalysis --- transition-metal catalysis --- C-N bond formation --- enantioselective --- heterocycles --- porphyrinoids --- multinuclear complexes --- chiral ligands --- circular dichroism --- paramagnetic NMR --- magnetochemistry --- porphyrin --- guanidine --- host-guest binding --- chirality --- DFT --- TD-DFT simulation --- induced optical activity --- stereodynamic chirality probe --- exciton coupling --- circularly polarized luminescence --- sergeants-and-soldiers --- majority-rule --- polysilane --- polyfluorenevinylene --- polyfluorene --- mirror symmetry breaking --- parity violation