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This book, entitled “Mesoporous Metal Oxide Films”, contains an editorial and a collection of ten research articles covering fundamental studies and applications of different metal oxide films. Mesoporous materials have been widely investigated and applied in many technological applications owing to their outstanding structural and physical properties. In this book, important developments in this fast-moving field are presented from various research groups around the world. Different preparation methods and applications of these novel and interesting materials have been reported, and it was demonstrated that mesoporosity has a direct impact on the properties and potential applications of such materials. The potential use of mesoporous metal oxide films and coatings with different morphology and structures is demonstrated in many technological applications, particularly chemical and electrochemical sensors, supercapacitors, solar cells, photoelectrodes, bioceramics, photonic switches, and anticorrosion agents.
History of engineering & technology --- SnO2 --- Metglas --- hemin --- H2O2 --- cyclic voltammetry --- magnetoelastic resonance --- sensor --- titanium dioxide --- mesoporous --- thin film --- multi-layered --- photoanode --- semiconductor --- photoelectrochemical water oxidation --- Mn2O3 --- mesoporous materials --- electrochemical characterizations --- electrode --- supercapacitors --- gadolinium oxide --- hydrazine --- p-nitrophenol --- electrochemical sensing --- amperometric --- selective sensor --- nanocrystal --- ZnO --- density of states --- optical and electrical properties --- TiO2 films --- Ag nanoparticles --- optical properties --- spectroelectrochemistry --- surface plasmon --- Fe-doped TiO2 --- hydrothermal --- GCE --- chemical sensor --- amperometry --- dye-sensitized solar cells --- working electrode --- TiO2 --- NiO nanoparticles --- electron transport --- corrosion --- guar gum --- coatings --- electrochemical impedance spectroscopy (EIS) --- SECM --- AFM --- calcium phosphate silicate --- PEG --- bioceramics --- sol-gel preparation --- hard tissue engineering --- metal oxide --- sol-gel --- supercapacitor --- photoelectrode --- dye sensitized solar cell --- NiO
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Water is indispensable to the functioning of most known life forms, and good water quality is essential to human health, social and economic development, and ecosystem functioning. Nonetheless, population growth has been leading to the degradation and depletion of fresh water resources. Under these circumstances, ensuring sufficient and safe water supplies for everyone is one of the Sustainable Development Goals (SDGs) set by the United Nations General Assembly in 2015 for the year 2030. For this goal to be achieved, the development and implementation of appropriate and efficient wastewater treatments that allow us to reduce water pollution is a major challenge.In view of the relevant contribution that polymers and polymeric materials may have in the conservation of the aquatic environment, namely by their application in wastewater treatment, original research and review papers on “Current trends and perspectives in the application of polymeric materials for wastewater treatment” were here brought together. For sure, this set of papers will be helpful and inspiring for readers interested in this topic.
Technology: general issues --- waste silk --- dopamine --- iron particles --- wastewater treatment --- activated carbon microsphere --- sodium lignosulfonate --- Cr(VI) --- adsorption --- modified polymeric resin --- t-butyl phosphate impregnation --- polymer based adsorbents --- dye adsorption --- response surface methodology --- nano-MgO --- structural modification --- permeability --- antifouling --- color rejection --- POME --- fluoroquinolones --- ultrasound radiation --- mesoporous carbon --- desirability function --- thermodynamics --- wastewater --- cost analysis --- ciprofloxacin --- Polystyrene nanocomposite --- modifications --- characterizations --- antibiotics --- emerging contaminants --- pharmaceuticals --- polymeric adsorbents --- magnetization --- silver nanoparticles --- microfiltration --- membranes --- biofouling --- sputtering --- magnetite --- co-precipitation method --- Rhodamine B --- sodium dodecyl sulfate --- selective adsorption --- dysprosium --- neodymium --- fabric adsorbent --- radiation --- graft polymerization --- molecular imprinting --- polymer --- sertraline --- cross-reactivity --- SSRI --- template --- sorbent --- n/a
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Water is indispensable to the functioning of most known life forms, and good water quality is essential to human health, social and economic development, and ecosystem functioning. Nonetheless, population growth has been leading to the degradation and depletion of fresh water resources. Under these circumstances, ensuring sufficient and safe water supplies for everyone is one of the Sustainable Development Goals (SDGs) set by the United Nations General Assembly in 2015 for the year 2030. For this goal to be achieved, the development and implementation of appropriate and efficient wastewater treatments that allow us to reduce water pollution is a major challenge.In view of the relevant contribution that polymers and polymeric materials may have in the conservation of the aquatic environment, namely by their application in wastewater treatment, original research and review papers on “Current trends and perspectives in the application of polymeric materials for wastewater treatment” were here brought together. For sure, this set of papers will be helpful and inspiring for readers interested in this topic.
waste silk --- dopamine --- iron particles --- wastewater treatment --- activated carbon microsphere --- sodium lignosulfonate --- Cr(VI) --- adsorption --- modified polymeric resin --- t-butyl phosphate impregnation --- polymer based adsorbents --- dye adsorption --- response surface methodology --- nano-MgO --- structural modification --- permeability --- antifouling --- color rejection --- POME --- fluoroquinolones --- ultrasound radiation --- mesoporous carbon --- desirability function --- thermodynamics --- wastewater --- cost analysis --- ciprofloxacin --- Polystyrene nanocomposite --- modifications --- characterizations --- antibiotics --- emerging contaminants --- pharmaceuticals --- polymeric adsorbents --- magnetization --- silver nanoparticles --- microfiltration --- membranes --- biofouling --- sputtering --- magnetite --- co-precipitation method --- Rhodamine B --- sodium dodecyl sulfate --- selective adsorption --- dysprosium --- neodymium --- fabric adsorbent --- radiation --- graft polymerization --- molecular imprinting --- polymer --- sertraline --- cross-reactivity --- SSRI --- template --- sorbent --- n/a
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This book, entitled “Mesoporous Metal Oxide Films”, contains an editorial and a collection of ten research articles covering fundamental studies and applications of different metal oxide films. Mesoporous materials have been widely investigated and applied in many technological applications owing to their outstanding structural and physical properties. In this book, important developments in this fast-moving field are presented from various research groups around the world. Different preparation methods and applications of these novel and interesting materials have been reported, and it was demonstrated that mesoporosity has a direct impact on the properties and potential applications of such materials. The potential use of mesoporous metal oxide films and coatings with different morphology and structures is demonstrated in many technological applications, particularly chemical and electrochemical sensors, supercapacitors, solar cells, photoelectrodes, bioceramics, photonic switches, and anticorrosion agents.
SnO2 --- Metglas --- hemin --- H2O2 --- cyclic voltammetry --- magnetoelastic resonance --- sensor --- titanium dioxide --- mesoporous --- thin film --- multi-layered --- photoanode --- semiconductor --- photoelectrochemical water oxidation --- Mn2O3 --- mesoporous materials --- electrochemical characterizations --- electrode --- supercapacitors --- gadolinium oxide --- hydrazine --- p-nitrophenol --- electrochemical sensing --- amperometric --- selective sensor --- nanocrystal --- ZnO --- density of states --- optical and electrical properties --- TiO2 films --- Ag nanoparticles --- optical properties --- spectroelectrochemistry --- surface plasmon --- Fe-doped TiO2 --- hydrothermal --- GCE --- chemical sensor --- amperometry --- dye-sensitized solar cells --- working electrode --- TiO2 --- NiO nanoparticles --- electron transport --- corrosion --- guar gum --- coatings --- electrochemical impedance spectroscopy (EIS) --- SECM --- AFM --- calcium phosphate silicate --- PEG --- bioceramics --- sol-gel preparation --- hard tissue engineering --- metal oxide --- sol-gel --- supercapacitor --- photoelectrode --- dye sensitized solar cell --- NiO
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Water is indispensable to the functioning of most known life forms, and good water quality is essential to human health, social and economic development, and ecosystem functioning. Nonetheless, population growth has been leading to the degradation and depletion of fresh water resources. Under these circumstances, ensuring sufficient and safe water supplies for everyone is one of the Sustainable Development Goals (SDGs) set by the United Nations General Assembly in 2015 for the year 2030. For this goal to be achieved, the development and implementation of appropriate and efficient wastewater treatments that allow us to reduce water pollution is a major challenge.In view of the relevant contribution that polymers and polymeric materials may have in the conservation of the aquatic environment, namely by their application in wastewater treatment, original research and review papers on “Current trends and perspectives in the application of polymeric materials for wastewater treatment” were here brought together. For sure, this set of papers will be helpful and inspiring for readers interested in this topic.
Technology: general issues --- waste silk --- dopamine --- iron particles --- wastewater treatment --- activated carbon microsphere --- sodium lignosulfonate --- Cr(VI) --- adsorption --- modified polymeric resin --- t-butyl phosphate impregnation --- polymer based adsorbents --- dye adsorption --- response surface methodology --- nano-MgO --- structural modification --- permeability --- antifouling --- color rejection --- POME --- fluoroquinolones --- ultrasound radiation --- mesoporous carbon --- desirability function --- thermodynamics --- wastewater --- cost analysis --- ciprofloxacin --- Polystyrene nanocomposite --- modifications --- characterizations --- antibiotics --- emerging contaminants --- pharmaceuticals --- polymeric adsorbents --- magnetization --- silver nanoparticles --- microfiltration --- membranes --- biofouling --- sputtering --- magnetite --- co-precipitation method --- Rhodamine B --- sodium dodecyl sulfate --- selective adsorption --- dysprosium --- neodymium --- fabric adsorbent --- radiation --- graft polymerization --- molecular imprinting --- polymer --- sertraline --- cross-reactivity --- SSRI --- template --- sorbent --- waste silk --- dopamine --- iron particles --- wastewater treatment --- activated carbon microsphere --- sodium lignosulfonate --- Cr(VI) --- adsorption --- modified polymeric resin --- t-butyl phosphate impregnation --- polymer based adsorbents --- dye adsorption --- response surface methodology --- nano-MgO --- structural modification --- permeability --- antifouling --- color rejection --- POME --- fluoroquinolones --- ultrasound radiation --- mesoporous carbon --- desirability function --- thermodynamics --- wastewater --- cost analysis --- ciprofloxacin --- Polystyrene nanocomposite --- modifications --- characterizations --- antibiotics --- emerging contaminants --- pharmaceuticals --- polymeric adsorbents --- magnetization --- silver nanoparticles --- microfiltration --- membranes --- biofouling --- sputtering --- magnetite --- co-precipitation method --- Rhodamine B --- sodium dodecyl sulfate --- selective adsorption --- dysprosium --- neodymium --- fabric adsorbent --- radiation --- graft polymerization --- molecular imprinting --- polymer --- sertraline --- cross-reactivity --- SSRI --- template --- sorbent
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Catalysts are widely used in a great variety of technologies, providing remarkable efficiency in order to address sustainable energy production, climate change challenges, and to reduce industrial emissions. In the framework of the Environmental Catalysis section promoted by the Catalysts Editorial Office, this Special Issue, entitled “Environmental Friendly Catalysts for Energy and Pollution Control Applications”, comprises novel studies representing the state-of-the-art research for efficient energy generation and industrial emission control based on new environmentally friendly catalyst materials (EFCs). In particular, in this Special Issue (SI), different kinds of catalysts are presented for catalytic solutions, including the reduction of NOx emissions (new zeolite catalyst modified with Pt), the elimination of volatile organic compounds (Co3O4@SiO2 and acidic surface transformed natural zeolite) and the removal of SO2 emissions (through adsorption processes with sodium citrate). Moreover, novel biocatalysts for bioanodes and new functional nanostructured catalysts based on metal–organic framework (MOFs) for different applications are also included. Additionally, articles compiled in this SI are also focused on the improvement of catalytic processes. Thus, selected processes based on activated carbons (modified with titanium dioxide) and optimized Fenton processes for the removal of aqueous organic pollutants or for the inactivation of bacteria are also presented.
Technology: general issues --- Environmental science, engineering & technology --- photocatalysis --- organic wastewater --- preparation method --- degradation --- characterizations --- hybridization --- exoelectrogen --- biocatalyst --- microenvironment --- porous electrode --- anaerobic --- recalcitrant compounds --- E. coli K12 --- methylene blue --- optimization --- Pareto chart --- perturbation graph --- Pt-based promoter --- CO oxidation --- environmental catalysis --- refinery compliance --- fluid catalytic cracking --- FCC --- sodium citrate --- sodium humate --- SO2 --- absorption --- BaQD --- carbamazepine --- ferric coordination complex --- photo-Fenton --- turbidity --- cyanide --- activated carbon --- titanium dioxide --- composites --- continuous flow --- adsorption --- catalytic ozonation --- Lewis and Brønsted acid sites --- natural zeolite --- reaction mechanism --- toluene --- three-phase modelling --- fixed-bed reactor --- wastewater treatment --- phenol --- granular activated carbon --- Ad/Ox --- volatile organic compounds --- core–shell structures --- spherical polymer templates --- Co3O4 --- Pd-based promoter --- NOx emission --- metal–organic frameworks --- heterogeneous catalysis --- carbon dioxide --- biomass --- hydrogenation --- oxidation --- Fisher-Tropsch --- photocatalysis --- organic wastewater --- preparation method --- degradation --- characterizations --- hybridization --- exoelectrogen --- biocatalyst --- microenvironment --- porous electrode --- anaerobic --- recalcitrant compounds --- E. coli K12 --- methylene blue --- optimization --- Pareto chart --- perturbation graph --- Pt-based promoter --- CO oxidation --- environmental catalysis --- refinery compliance --- fluid catalytic cracking --- FCC --- sodium citrate --- sodium humate --- SO2 --- absorption --- BaQD --- carbamazepine --- ferric coordination complex --- photo-Fenton --- turbidity --- cyanide --- activated carbon --- titanium dioxide --- composites --- continuous flow --- adsorption --- catalytic ozonation --- Lewis and Brønsted acid sites --- natural zeolite --- reaction mechanism --- toluene --- three-phase modelling --- fixed-bed reactor --- wastewater treatment --- phenol --- granular activated carbon --- Ad/Ox --- volatile organic compounds --- core–shell structures --- spherical polymer templates --- Co3O4 --- Pd-based promoter --- NOx emission --- metal–organic frameworks --- heterogeneous catalysis --- carbon dioxide --- biomass --- hydrogenation --- oxidation --- Fisher-Tropsch
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In recent years, there has been rapid growth in the availability of innovative, non-combustible products, including oral tobacco-derived nicotine (OTDN) products, heated tobacco products (HTPs), and electronic cigarettes (also referred to as e-vapor products; EVPs). Industry, academic, and government researchers are developing and validating analytical methods to extract, separate, identify, and quantitate a variety of analytes from these innovative tobacco products using a wide range of analytical techniques. These analytes include constituents such as nicotine, degradants and impurities, flavors, non-tobacco ingredients, HPHCs, and other currently unknown constituents. In this Special Issue, we received nine contributions that covered the latest analytical methods that have been developed and applied for the chemical characterization or exposure assessment to tobacco product constituents of innovative non-combustible products. This Special Issue is representative of the importance of analytical sciences research in characterizing innovative non-combustible products for guiding product design, determining relative product performance, ensuring consistency during the manufacturing process, informing toxicological risk assessment, and enabling regulatory reporting. The current advances in the development and applications of the analytical methods reported in this Special Issue can be used to inform the harm reduction potential of innovative non-combustible products for adult smokers.
Research & information: general --- Chemistry --- Analytical chemistry --- on!® nicotine pouches --- nicotine --- dissolution --- release profile --- validation --- product assessment --- smokeless tobacco product --- nicotine degradants --- nicotine-related impurities --- alkaloids --- nicotine degradation products --- nicotine pouches --- reduced-risk products --- constituents --- method development --- method validation --- JUUL --- aerosol --- non-targeted analysis --- chemical characterization --- ENDS --- e-cigarette --- GC-MS --- LC-HRMS --- e-liquid --- 2,4-DNPH derivatization --- formaldehyde --- "hidden formaldehyde" --- formaldehyde-containing hemiacetal/acetal adducts --- HPHC --- GC-MS --- 3-hydroxybenzo[a]pyrene --- LC-MS/MS --- urine --- human biomonitoring --- derivatization --- potentially reduced-risk products --- propylene glycol --- electronic cigarette --- biomarker of exposure --- compliance marker --- oral tobacco derived nicotine (OTDN) pouches --- snus --- nicotine release --- nicotine dissolution --- nicotine extraction --- equivalence --- modern oral nicotine products --- HPHCs --- product characterizations --- on!® nicotine pouches --- nicotine --- dissolution --- release profile --- validation --- product assessment --- smokeless tobacco product --- nicotine degradants --- nicotine-related impurities --- alkaloids --- nicotine degradation products --- nicotine pouches --- reduced-risk products --- constituents --- method development --- method validation --- JUUL --- aerosol --- non-targeted analysis --- chemical characterization --- ENDS --- e-cigarette --- GC-MS --- LC-HRMS --- e-liquid --- 2,4-DNPH derivatization --- formaldehyde --- "hidden formaldehyde" --- formaldehyde-containing hemiacetal/acetal adducts --- HPHC --- GC-MS --- 3-hydroxybenzo[a]pyrene --- LC-MS/MS --- urine --- human biomonitoring --- derivatization --- potentially reduced-risk products --- propylene glycol --- electronic cigarette --- biomarker of exposure --- compliance marker --- oral tobacco derived nicotine (OTDN) pouches --- snus --- nicotine release --- nicotine dissolution --- nicotine extraction --- equivalence --- modern oral nicotine products --- HPHCs --- product characterizations
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This book, entitled “Mesoporous Metal Oxide Films”, contains an editorial and a collection of ten research articles covering fundamental studies and applications of different metal oxide films. Mesoporous materials have been widely investigated and applied in many technological applications owing to their outstanding structural and physical properties. In this book, important developments in this fast-moving field are presented from various research groups around the world. Different preparation methods and applications of these novel and interesting materials have been reported, and it was demonstrated that mesoporosity has a direct impact on the properties and potential applications of such materials. The potential use of mesoporous metal oxide films and coatings with different morphology and structures is demonstrated in many technological applications, particularly chemical and electrochemical sensors, supercapacitors, solar cells, photoelectrodes, bioceramics, photonic switches, and anticorrosion agents.
History of engineering & technology --- SnO2 --- Metglas --- hemin --- H2O2 --- cyclic voltammetry --- magnetoelastic resonance --- sensor --- titanium dioxide --- mesoporous --- thin film --- multi-layered --- photoanode --- semiconductor --- photoelectrochemical water oxidation --- Mn2O3 --- mesoporous materials --- electrochemical characterizations --- electrode --- supercapacitors --- gadolinium oxide --- hydrazine --- p-nitrophenol --- electrochemical sensing --- amperometric --- selective sensor --- nanocrystal --- ZnO --- density of states --- optical and electrical properties --- TiO2 films --- Ag nanoparticles --- optical properties --- spectroelectrochemistry --- surface plasmon --- Fe-doped TiO2 --- hydrothermal --- GCE --- chemical sensor --- amperometry --- dye-sensitized solar cells --- working electrode --- TiO2 --- NiO nanoparticles --- electron transport --- corrosion --- guar gum --- coatings --- electrochemical impedance spectroscopy (EIS) --- SECM --- AFM --- calcium phosphate silicate --- PEG --- bioceramics --- sol-gel preparation --- hard tissue engineering --- metal oxide --- sol-gel --- supercapacitor --- photoelectrode --- dye sensitized solar cell --- NiO --- SnO2 --- Metglas --- hemin --- H2O2 --- cyclic voltammetry --- magnetoelastic resonance --- sensor --- titanium dioxide --- mesoporous --- thin film --- multi-layered --- photoanode --- semiconductor --- photoelectrochemical water oxidation --- Mn2O3 --- mesoporous materials --- electrochemical characterizations --- electrode --- supercapacitors --- gadolinium oxide --- hydrazine --- p-nitrophenol --- electrochemical sensing --- amperometric --- selective sensor --- nanocrystal --- ZnO --- density of states --- optical and electrical properties --- TiO2 films --- Ag nanoparticles --- optical properties --- spectroelectrochemistry --- surface plasmon --- Fe-doped TiO2 --- hydrothermal --- GCE --- chemical sensor --- amperometry --- dye-sensitized solar cells --- working electrode --- TiO2 --- NiO nanoparticles --- electron transport --- corrosion --- guar gum --- coatings --- electrochemical impedance spectroscopy (EIS) --- SECM --- AFM --- calcium phosphate silicate --- PEG --- bioceramics --- sol-gel preparation --- hard tissue engineering --- metal oxide --- sol-gel --- supercapacitor --- photoelectrode --- dye sensitized solar cell --- NiO
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This book represents a collection of contributions in the field of the synthesis and characterization of chemical compounds, natural products, chemical reactivity, and computational chemistry. Among its contents, the reader will find high-quality, peer-reviewed research and review articles that were published in the open access journal Compounds by members of the Editorial Board and the authors invited by the Editorial Office and Editor-in-Chief.
Technology: general issues --- Chemical engineering --- atropisomerism --- 4,4′-bipyridine --- pyridine N-oxidation --- halogenation --- halogen bond --- cyanation --- Finkelstein reaction --- Suzuki coupling --- Orchis --- scent --- gas chromatography --- mass spectrometry --- solid-phase microextraction --- quantum chemistry --- computational chemistry --- molecular dynamics --- modeling --- open-source software --- proprietary software --- Himantoglossum --- solid phase microextraction --- iodination --- alkanes --- alkenes --- alkynes --- alkyl carbonyls --- elemental iodine --- iodides --- Zutano variety --- avocado oil --- Soxhlet extraction --- ultrasound-assisted extraction --- volatiles --- ripening --- over-ripe --- HS-SPME–GC–MS --- Basilicata --- Barlia robertiana --- Himantoglossum robertianum --- mantel test --- Orchidaceae --- pollination syndrome --- Italy --- volatile compounds --- solvolysis --- aryldiazonium ions --- perchlorate anions --- silicon carbide (SiC) --- 3C-SiC powder --- 4H-SiC crystal --- impurities --- photoluminescence --- pnictogen bonding --- nitrogen as pnictogen bond donor --- geometries --- crystal structure analysis --- ICSD and CSD database analyses --- MESP characterizations --- sum of the van der Waals radii concept --- Dactylorhiza --- volatile organic compounds --- thiosemicarbazone --- metal complexes --- DNA interactions --- biological activity --- thiazolidinedione --- microwave synthesis --- compound library --- rosiglitazone --- Knoevangel condensation --- biodiesel production --- crude glycerin --- carbon materials --- n/a --- 4,4'-bipyridine --- HS-SPME-GC-MS
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This book describes unconventional noncovalent interactions and analyzes their importance for crystal growth in organic and hybrid organic–inorganic systems. Several examples illustrate how the combination of theory and experiment allows rationalizing the strength and directionality of noncovalent interactions. This book elegantly describes the results of a survey of X-ray structures of main group element compounds (M = Sn, Pb As, Sb, Bi, and Te) exhibiting intermolecular M•••Se noncovalent interactions in one of its chapters. Moreover, it provides a consistent description of noncovalent interactions, covering most groups of the periodic table. The interactions are described and discussed using their trivial names. That is, a comprehensive and accurate description is provided for alkali, alkaline earth, regium, spodium, triel, tetrel, pnictogen, chalcogen, halogen, and aerogen bonding interactions. No other book is available covering such an extensive number of interactions and examples where these interactions are relevant. relevant.
Research & information: general --- Biology, life sciences --- non-covalent interactions --- regium bonds --- silver(I) --- coinage metals --- pyrazolates --- phosphines --- halogen bonding --- hydrogen bonding sigma-hole interactions --- theoretical studies --- characterizations --- noncovalent interactions --- Lewis acids --- Lewis bases --- spodium bonds --- σ/π-hole interactions --- EDTA --- 2,6-diaminopurine --- cadmium --- co-crystal --- H-bonding --- π–π stacking --- triazinane --- 1,3,5-Triazacyclohexane --- Hirshfeld surface analysis --- DFT study --- C–H···π interaction --- hybridization of a nitrogen atom in sulfonamides --- molecular cocrystal --- sandwiched-layer structure --- C–I···F halogen bonds --- π···π stacking interactions --- PBE0-D3(BJ) calculations --- secondary bonding --- supramolecular --- crystal engineering --- tetrel bonding --- pnictogen bonding --- chalcogen bonding --- selenium --- structural chemistry --- main group elements --- π–hole interaction --- substituent effects --- vibrational spectroscopy --- local vibrational mode theory --- direct measure for π–hole interaction strength --- noncovalent interaction --- hydrogen bonding --- nickel --- Schiff bases --- crystallography --- σ-hole --- π-hole --- crystal growth --- supramolecular chemistry --- σ-hole interactions --- self-assembly --- scanning tunneling microscopy
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