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Thermoresponsive polymers, materials able to undergo sharp and often reversible phase separations in response to temperature stimuli, are introducing new paradigms in different fields, including medicine, advanced separations and oil and gas. In "Advances in Thermoresponsive Polymers", a clear picture of the frontiers reached in the understanding of the mechanistic behavior associated with temperature-induced phase separation, the influence of the polymer structure in regulating the macroscopic behavior of these materials and the latest applications for which thermoresponsive polymers show great potential is provided.

Technology: general issues --- Chemical engineering --- poly(N,N-diethylacrylamide) --- glycidyl methacrylate --- thermoresponsive copolymer --- α-chymotrypsin --- polymer-enzyme conjugate nanoparticle --- polymeric nanoparticles --- emulsion polymerization --- RAFT --- thermo-responsive polymers --- smart materials --- LCST --- phase diagram --- phase separation --- thermoresponsive star-shaped polymers --- poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines --- aqueous solutions --- light scattering --- turbidimetry --- microcalorimetry --- aggregation --- dual-stimuli-responsive materials --- thin films --- out-of-equilibrium --- thermoresponsive --- oligo(ethylene glycol) --- OEGylated --- poly(amino acid) --- ring-opening polymerization --- post-polymerization modification --- Ugi reaction --- synthesis --- star-shaped macromolecules --- calix[n]arene --- block and gradient copolymers of poly-2-alkyl-2-oxazolines --- conformation --- thermoresponsibility --- self-organization --- poly-N-vinylcaprolactam --- thermoresponsive polymers --- polymer-protein conjugates --- controlled release --- temperature-sensitive polymers --- hydrogels --- stereocomplexation --- polylactic acid --- temperature/reduction --- self-recombination --- thermosensitive polymers --- enzyme complexation --- reversible inactivation --- UCST polymers --- stimuli-responsive polymers --- electronic paramagnetic resonance --- spin probe --- nitroxides --- coil to globule --- poly(L-lysine) --- N-isopropylacrylamide --- aza-Michael addition reaction --- thermo-responsive --- pH-responsive --- biodegradable polymer

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Thermoresponsive polymers, materials able to undergo sharp and often reversible phase separations in response to temperature stimuli, are introducing new paradigms in different fields, including medicine, advanced separations and oil and gas. In "Advances in Thermoresponsive Polymers", a clear picture of the frontiers reached in the understanding of the mechanistic behavior associated with temperature-induced phase separation, the influence of the polymer structure in regulating the macroscopic behavior of these materials and the latest applications for which thermoresponsive polymers show great potential is provided.

Technology: general issues --- Chemical engineering --- poly(N,N-diethylacrylamide) --- glycidyl methacrylate --- thermoresponsive copolymer --- α-chymotrypsin --- polymer-enzyme conjugate nanoparticle --- polymeric nanoparticles --- emulsion polymerization --- RAFT --- thermo-responsive polymers --- smart materials --- LCST --- phase diagram --- phase separation --- thermoresponsive star-shaped polymers --- poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines --- aqueous solutions --- light scattering --- turbidimetry --- microcalorimetry --- aggregation --- dual-stimuli-responsive materials --- thin films --- out-of-equilibrium --- thermoresponsive --- oligo(ethylene glycol) --- OEGylated --- poly(amino acid) --- ring-opening polymerization --- post-polymerization modification --- Ugi reaction --- synthesis --- star-shaped macromolecules --- calix[n]arene --- block and gradient copolymers of poly-2-alkyl-2-oxazolines --- conformation --- thermoresponsibility --- self-organization --- poly-N-vinylcaprolactam --- thermoresponsive polymers --- polymer-protein conjugates --- controlled release --- temperature-sensitive polymers --- hydrogels --- stereocomplexation --- polylactic acid --- temperature/reduction --- self-recombination --- thermosensitive polymers --- enzyme complexation --- reversible inactivation --- UCST polymers --- stimuli-responsive polymers --- electronic paramagnetic resonance --- spin probe --- nitroxides --- coil to globule --- poly(L-lysine) --- N-isopropylacrylamide --- aza-Michael addition reaction --- thermo-responsive --- pH-responsive --- biodegradable polymer --- poly(N,N-diethylacrylamide) --- glycidyl methacrylate --- thermoresponsive copolymer --- α-chymotrypsin --- polymer-enzyme conjugate nanoparticle --- polymeric nanoparticles --- emulsion polymerization --- RAFT --- thermo-responsive polymers --- smart materials --- LCST --- phase diagram --- phase separation --- thermoresponsive star-shaped polymers --- poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines --- aqueous solutions --- light scattering --- turbidimetry --- microcalorimetry --- aggregation --- dual-stimuli-responsive materials --- thin films --- out-of-equilibrium --- thermoresponsive --- oligo(ethylene glycol) --- OEGylated --- poly(amino acid) --- ring-opening polymerization --- post-polymerization modification --- Ugi reaction --- synthesis --- star-shaped macromolecules --- calix[n]arene --- block and gradient copolymers of poly-2-alkyl-2-oxazolines --- conformation --- thermoresponsibility --- self-organization --- poly-N-vinylcaprolactam --- thermoresponsive polymers --- polymer-protein conjugates --- controlled release --- temperature-sensitive polymers --- hydrogels --- stereocomplexation --- polylactic acid --- temperature/reduction --- self-recombination --- thermosensitive polymers --- enzyme complexation --- reversible inactivation --- UCST polymers --- stimuli-responsive polymers --- electronic paramagnetic resonance --- spin probe --- nitroxides --- coil to globule --- poly(L-lysine) --- N-isopropylacrylamide --- aza-Michael addition reaction --- thermo-responsive --- pH-responsive --- biodegradable polymer

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A total of 16 original research articles. Contributions from 10 countries from 3 continents. Organic synthesis towards novel heterocyclic compounds. Fully characterized inorganic and organic molecules including X-ray crystallographic analysis. Cyclization reactions, reactivity of aromatic compounds and improved synthetic methodologies of important intermediate compounds.

heterocycle --- piperazine --- pyrimidine --- DABCO --- nucleophilic displacement --- chlorination --- [1,3]-H shift --- aza-Michael addition --- DFT calculations --- dimethyl acetylenedicarboxylate --- isoxazolo[3,4-b]quinolin-3(1H)-one --- pyrazolines --- curcuminoids --- nitrogen heterocycles --- cytotoxic --- DNA binding --- MDR reversal --- oxygen-nitrogen heterocycles --- 11a,12-dihydrobenzo[b]benzo[5,6][1,4]oxazino[2,3-e][1,4]oxazine --- disulfur dichloride --- o-aminophenol --- condensation --- 4-anilino-quin(az)olines --- hinge binder --- conformational flexibility --- kinase inhibitor design --- imine --- Schiff base --- X-ray crystallographic analysis --- Cu(II) complex --- gamma-amino acid --- ruthenium --- carbonyl complex --- azopyridine --- anion radical --- electronic structure --- magnetic properties --- chalcogenophene --- heterocycles --- ligands --- pyridine derivatives --- thiophene derivatives --- aminocyclopentitol --- bicyclic aziridine --- water chemistry --- nucleophilic substitution --- homopiperazine --- X-ray structure --- C–C bond length --- 15N-NMR --- catechol --- alkyne --- thiol-alkyne click reaction --- domino reactions --- bromination --- intramolecular SN displacement --- carbocyclic hydantoins --- N-1 substituted hydantoin --- spiro hydantoins --- imidazolidine-2,4-diones --- stereochemistry --- NMR --- HRMS --- GIAO --- ring closing --- Au-nanoparticles --- NaBH4 --- amino-substituted fused oxazolocoumarin --- fused oxazolocoumarins --- chemoselective reduction --- o-hydroxynitrocoumarins --- benzimidazole --- nucleophilic aromatic substitution --- thiosemicarbazone --- n/a --- C-C bond length