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Biological chemistry is a major frontier of inorganic chemistry. Three special volumes devoted to Metal Sites in Proteins and Models address the questions: how unusual ("entatic") are metal sites in metalloproteins and metalloenzymes compared to those in small coordination complexes? and if they are special, how do polypeptide chains and co-factors control this? The chapters deal with iron, with metal centres acting as Lewis acids, metals in phosphate enzymes, with vanadium, and with the wide variety of transition metal ions which act as redox centres. They illustrate in particular how the combined armoury of genetics and structure determination at the molecular level are providing unprecedented new tools for molecular engineering.

Acides de Lewis --- Fosfatasen --- Iron proteins --- Lewis [Acides de ] --- Lewis acids --- Lewiszuren --- Metallo-enzymen --- Metalloenzymes --- Metalloproteins --- Metalloproteïnen --- Métalloenzymes --- Métalloprotéïnes --- Phosphatases --- Phosphoesterases --- Phosphohydrolases --- Vanadium --- Zuren [Lewis] --- 577.118 --- #WSCH:AAS2 --- Inorganic and mineral substances --- Metalloproteins. --- Oxidation-reduction reaction. --- 577.118 Inorganic and mineral substances --- Boranes --- Hydrolases --- Zinc Compounds --- Metals, Heavy --- Boron Compounds --- Enzymes --- Transition Elements --- Inorganic Chemicals --- Organic Chemicals --- Chemicals and Drugs --- Elements --- Metals --- Enzymes and Coenzymes --- Animal Biochemistry --- Human Anatomy & Physiology --- Health & Biological Sciences --- Inorganic chemistry. --- Biochemistry. --- Molecular biology. --- Cell biology. --- Biophysics. --- Biological physics. --- Inorganic Chemistry. --- Biochemistry, general. --- Molecular Medicine. --- Cell Biology. --- Biological and Medical Physics, Biophysics. --- Biological physics --- Biology --- Medical sciences --- Physics --- Cell biology --- Cellular biology --- Cells --- Molecular biochemistry --- Molecular biophysics --- Biochemistry --- Biophysics --- Biomolecules --- Systems biology --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Chemistry --- Inorganic chemistry --- Inorganic compounds --- Composition