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Antiferromagnetism. --- Crystal field theory. --- Diamagnetic corrections. --- Magnetochemistry. --- Spin free-spin paired equilibria. --- Valence bond theory.
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Quantum chemistry --- fysicochemie --- 530.145 --- #WSCH:MONO --- Chemistry, Quantum --- Chemistry, Physical and theoretical --- Quantum theory --- Excited state chemistry --- Quantum chemistry. --- Atoms --- Crystal field --- Diatomic molecules --- Valence bond theory --- Atoms. --- Crystal field. --- Diatomic molecules. --- Valence bond theory. --- 530.145 Quantum theory
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Organic chemistry --- Physical organic chemistry --- ORGANIC CHEMISTRY --- MOLECULAR STRUCTURE --- STEREOCHEMISTRY --- CONFORMATION --- MOLECULAR ORBITAL METHODS --- VALENCE BOND THEORY --- ORGANIC COMPOUNDS --- SUBSTITUTION REACTION --- ELIMINATION REACTION --- PHOTOCHEMISTRY --- REACTIONS
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Development in science depends on several factors. Among these, the role of individual scientists is perhaps not the most important one. Science is typically a body of collective knowledge and any increase in the amount of this knowledge is certainly due to strong interaction among scientists. Even in the past, it happened quite rarely that a single person, without any aid of others, d- covered something fundamental or opened a new chapter in science. Great figures of science history have, in most cases, had rather a summarizing and s- thesizing role. This is especially valid over the last few decades. On one hand, the amount of information necessary to achieve new discoveries, has increased tremendously. On the other hand, improvement of technical facilities has increased the speed of information exchange. These factors resulted in a degree of specialization in science that had never seen before. Most of us are experts and specialists rather than scientists in the classical sense. My personal feeling is that, even nowadays, there is a strong need for professionals with a broad knowledge and c- prehensive mind, although they may not be competitive in the number of their publications or the sizes of their grants. Every time I have met such a person (I can count these cases on my fingers) I have become deeply influenced by his or her strong intellect.
Chemistry. --- Organic chemistry. --- Chemistry, Physical and theoretical. --- Organic Chemistry. --- Theoretical and Computational Chemistry. --- Quantum theory. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Organic chemistry --- Electron configuration. --- Configuration, Electron --- Electron correlation --- Atomic orbitals --- Electrons --- Electron density --- Localized electronic state --- Perturbation theory --- Valence bond theory
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This book presents the fundamentals of bonding in polyoxometalates and related oxides based on classical bonding concepts and the bond valence model. The in-depth treatment includes a revision of the procedure for the determination of the parameters of bond length-bond valence functions, the application of the bond valence model to polyoxometalates and related oxides, and the explanation of the distribution of the bond valences, and hence of the bond lengths, over the metal-oxygen bond and of the ionic charge on the oxygen atoms. Numerous tables and figures underline and illuminate the results. The principal author is a leader in the field of polyoxometalate chemistry. This work provides for the first time a comprehensive analysis of the structure and bonding in polyoxometalates, based on classical chemical concepts and the bond valence approach, and as such is a valuable resource for chemists, physicists and material scientists working in the field.
Chemical bonds --- Chemische bindingen --- Density [Electron ] --- Distribution [Electron ] --- Distribution d'électrons --- Electron density --- Electron distribution --- Electronen--Densiteit --- Liaisons chimiques --- Polyoxometalaten --- Polyoxometalates --- Polyoxométalates --- Chemistry. --- Inorganic chemistry. --- Physical chemistry. --- Chemistry, Physical and theoretical. --- Condensed matter. --- Inorganic Chemistry. --- Theoretical and Computational Chemistry. --- Physical Chemistry. --- Condensed Matter Physics. --- Condensed materials --- Condensed media --- Condensed phase --- Materials, Condensed --- Media, Condensed --- Phase, Condensed --- Liquids --- Matter --- Solids --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Inorganic chemistry --- Inorganic compounds --- Heteropoly acids --- Valence bond theory
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