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Unimolecular reactions.

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When this book was first published in 1984, the discovery of laser-induced mutliphoton chemical reactions had led to a resurgence of interest in the theory of unimolecular reactions. Attempts to explain these phenomena had been built on a very imperfectly understood theory of thermal unimolecular reactions. In this book, Professor Pritchard presents a treatment that dissects the unimolecular reaction process into a sequence of distinct phases, so that the assumptions of the theory can be clearly seen, and confusion over the theory avoided. As such it provides a self-consistent foundation upon which to begin to treat these phenomena. Postgraduate students and research workers in physical chemistry will find this an invaluable textbook on a topic that has suddenly become of primary importance.

Quantum chemistry. --- Unimolecular reactions.

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The book provides a penetrating and comprehensive description of energy selected reactions from a theoretical as well as experimental point of view. It presents three major aspects of unimolecular reactions involving the preparation of the reactants in selected energy states, the rate of dissipation of the activated molecule, and the partitioning of the excess energy among the final products.

Unimolecular reactions. --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Chemistry. --- Physical sciences --- POTENTIAL ENERGY SURFACE --- REACTION, UNIMOLECULAR --- MOLECULAR VIBRATION --- POTENTIAL ENERGY AND FUNCTION --- CLUSTERS --- MOLECULES --- REACTION KINETICS --- ROTATIONAL-VIBRATIONAL STATE --- VIBRATIONAL ENERGY --- CLUSTER COLLISIONS --- REACTIONS

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Chemical reaction, Conditions and laws of --- Chemical kinetics --- Gases, Ionized --- Réactions chimiques --- Cinétique chimique --- Mécanismes --- 541.124 --- Ionized gases --- Unimolecular reactions --- #WSCH:AAS1 --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Gases --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Limits of reactions --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Ionized gases. --- Réactions chimiques --- Cinétique chimique --- Mécanismes --- CHEMICAL KINETICS --- CHROMATOGRAPHY --- IONIZED GASES --- PROTEINS --- PURIFICATION --- UNIMOLECULAR REACTIONS --- PREPARATION

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Unimolecular reactions --- Quantum chemistry --- 541.124 --- 530.145 --- #WSCH:AAS1 --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Chemistry, Quantum --- Chemistry, Physical and theoretical --- Quantum theory --- Excited state chemistry --- Limits of reactions --- 530.145 Quantum theory --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Collisions --- Relaxation