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Das Gebiet der Kolloid- und Grenzflächenchemie und -physik ist ausgesprochen vielschichtig und nahezu für alle Gebiete der Natur- und Lebenswissenschaften sowie der Technik von immenser und stetig zunehmender Bedeutung. Dieses Lehrbuch richtet sich an alle Studenten der Chemie und der Biologie im Master- bzw. Bachelor-Studiengang. Es ist das erste für Anfänger geeignete Lehrbuch zu dieser Thematik und fasst die chemischen, physikalischen und technologischen Grundlagen dieses aktuellen Gebietes auf dem Niveau eines Bachelor-Vertiefungsstudiums zusammen. Es schließt damit eine Lücke, denn bisher mussten sich viele Studierende die in diesem Buch aufgeführten Grundlagen mühsam aus vielen sehr speziellen Lehrbüchern unterschiedlicher Thematik zusammensuchen. Die Autoren Prof. Dr. Günter Jakob Lauth, FH Aachen Dr. Jürgen Kowalczyk, FH Aachen.
Physical chemistry. --- Surfaces (Physics). --- Polymers. --- Analytical chemistry. --- Physical Chemistry. --- Surface and Interface and Thin Film. --- Analytical Chemistry.
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This book presents a summary of the topic of supercooling during crystallization in condensed films. While recent findings are mainly published in English, the foundational classical results were originally published in Russian, with limited accessibility to general readers. The present work is based on a 2019 Ukrainian monograph, "Temperature Stability of the Supercooled Liquid Phase in Condensed Films," which has been extensively revised and expanded. The book includes a detailed analysis of the thermodynamics of supercooled fluids, with updated and expanded sections. Additionally, new results on the supercooling of indium-lead (In-Pb) alloys in contact with amorphous molybdenum and fusible metals in contact with nanocrystalline layers are presented. These layers occupy a middle ground between amorphous (carbon, molybdenum, as-deposited germanium films) and polycrystalline (copper, silver, aluminum) substrates. The book gives particular attention to the peculiarities of contractedgeometry conditions, which are natural for multilayered structures and can occur through fusible component segregation at grain boundaries. The analysis of new data has prompted a rethinking of the role of the more refractory layer's microstructure on the crystallization processes of metastable melts. The book includes a thorough discussion of these findings, highlighting the crucial role of the microstructure in the crystallization process. This book is a valuable resource for researchers and students interested in crystallization in thin-film metallic systems. This comprehensive study provides a detailed and authoritative analysis of the thermodynamics of supercooled fluids, and the impact of microstructure on the crystallization processes of metastable melts, making it an essential addition to any academic library.
Supercooled liquids. --- Metals. --- Surfaces (Physics). --- Materials --- Soft condensed matter. --- Metals and Alloys. --- Surface and Interface and Thin Film. --- Characterization and Analytical Technique. --- Fluids. --- Analysis. --- Surfaces (Physics)
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This open access book provides a detailed exploration of the phase behaviour of, and interfacial properties in, complex colloidal mixtures (e.g., clay, milk, blood). Insights into colloids have been at the heart of many innovations in different industries. The big question underlying these innovations is how can colloidal systems be formulated and designed towards the desired properties? To do this, the forces between the colloidal particles need to be controlled. Adding depletants (non-adsorbing polymers or small colloids) is key to controlling the attractive interactions. Colloids and the Depletion Interaction provides the qualitative insights and quantitative tools to understand and predict such forces in colloidal dispersions. It offers a concise introduction to the history and fundamentals of the depletion interaction in, and phase behaviour of, colloidal dispersions. Why does adding polymers lead to attractive forces between colloidal particles? What determines the phase stability of multi-component colloidal systems? These include colloid—polymer mixtures, binary colloidal mixtures, and anisotropic particles such as clay platelets, cubes and rod-like viruses. Conceptual explanations are accompanied by experimental and computer simulation results throughout. Illustrations of depletion effects in colloid science, biology and technology demonstrate its wider significance. The concluding outlook provides the scope of challenges and possibilities in this exciting field of science. This second updated and enlarged edition contains 12 Chapters. It is an ideal book for advanced undergraduates and graduate students in physical chemistry, chemical engineering and soft matter physics. Besides providing a fundamental understanding of depletion interactions in colloidal mixtures, it gives background information on colloidal stability and phase behaviour in general. For experienced scientists and engineers working on mixtures of colloids and non-adsorbing (bio)polymers or colloidal particles, this book serves as a reference for understanding depletion interactions in systems of their specific interest.
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This book presents the proceedings of the ‘3rd International Conference on Advanced Surface Enhancement’, INCASE 2023. It compiles the papers presented by researchers in surface engineering field at INCASE 2023 conference. The book presents a comprehensive review of the state of the art in surface engineering-related techniques and strategies, with a focus towards sustainability. The main topics include ‘Advanced techniques for surface engineering towards enhanced performance’, ‘Surface and sub-surface characterisation’, ‘Simulation and modelling of surface integrity’, ‘Advanced coating materials design synthesis and industry applications’, and ‘Emerging trends in surface engineering’. The book identifies the gaps between research and manufacturing and promotes sustainable approaches towards development of surface engineering solutions for adoption by industry. The book is useful for researchers, scientists, students, and engineers working in the field of surface engineering.
Materials. --- Surfaces (Technology). --- Thin films. --- Surfaces (Physics). --- Materials Engineering. --- Surfaces, Interfaces and Thin Film. --- Surface and Interface and Thin Film. --- Surfaces (Technology) --- Surfaces (Physics)
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This second edition delves into surface topography, exploring its impact on the functionality of various components. Beginning with an introduction to surface topography in Chapter 1, the subsequent chapters delve into the areal field parameters, feature parameters, filtering methods, and form removal techniques, leading into more specialized topics such as fractal-related multiscale geometric characterization and deep learning-based quantification of surface texture. With a focus on characterizing measurement data to glean functional insights, the book presents a comprehensive framework adopted by the international community. Through a diverse array of case studies spanning automotive applications, road surface engineering, additive manufacturing, and precision machining, readers are offered a holistic understanding of how areal techniques are pivotal in modern manufacturing industries. This edition builds upon the foundation laid by its predecessor, integrating evolving standards and additional case studies to provide an updated and comprehensive resource for modern surface engineering.
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This book is a collection of reports (reviewed) selected from several sections of the IEEE Nanomaterials: Application and Properties-2023 conference. The book is devoted to the study of films, coatings, and materials obtained by various methods of preparation and deposition, for example, magnetron sputtering of targets, vacuum arc deposition , electron-plasma processing, sintering of composites, plasma jet deposition, and other methods for obtaining nanomaterials. The chapters and reports describe superhard coatings, spark, and plasma alloying of materials (metals, semiconductors, polymers, ceramics).
Surfaces (Physics). --- Coatings. --- Composite materials. --- Solid state physics. --- Nanoparticles. --- Metals. --- Surface and Interface and Thin Film. --- Composites. --- Electronic Devices. --- Metals and Alloys.
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This book highlights the use/application of Vanadium Oxide as a Supercapacitor (SC) material using the electrodeposition method. The preparation methods, material characterization, and performance testing of VOx-based SC are thoroughly discussed. Electrolyte solutions from VCl3 and other metal precursors are used to form V3O5 electrodes on nickel foam (NF). The cathode can deliver a specific capacitance value of 5689 F/g. The work is improved by depositing V3O5 film on Ni(OH)2 to form a bilayer coating on NF substrate. Ni(OH)2 with a nano-sheet structure is used for the purpose of increasing the specific surface area of V3O5 layer which can achieve specific capacitance of 7500 F/g, the energy density of 167 Wh/kg, and the power density of 199 W/kg. After 10,000 charge-discharge cycles, the capacitance retention rate is 93%. Finally, a full cell SC is assembled using the bilayer electrode and active carbon. The asymmetric and symmetric full cells performed the specific capacitances of 390 F/g and 846 F/g, the energy densities of 286 Wh/kg and 170 Wh/kg, and the power densities of 1149 W/kg and 602 W/g, respectively. After 10,000 charge-discharge cycles, the capacitance retention rates of asymmetric and symmetric full cells are 97% and 95%, respectively.
Surfaces (Physics). --- Materials --- Nanochemistry. --- Nanotechnology. --- Surface and Interface and Thin Film. --- Materials Characterization Technique. --- Nanoengineering. --- Analysis. --- Supercapacitors. --- Vanadium oxide. --- Cathodes. --- Surfaces (Physics)
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This textbook provides a comprehensive overview of biomimetics and biologically inspired materials, capturing the essence of innovation that draws inspiration from nature. Featuring diverse examples of biomimetics, the book explores surfaces exhibiting characteristics such as roughness-induced super-phobicity/philicity, self-cleaning mechanisms, antifouling properties, low drag, reversible adhesion, high hardness, and mechanical toughness. It also covers phenomena like water harvesting, purification, insect locomotion, and piercing. The book emphasizes durable materials and surfaces with a strong focus on the Lotus Effect, superoleophobic/philic surfaces, anti-biofouling, water purification, oil-water separation, shark skin-inspired low-drag surfaces, gecko-inspired reversible adhesion, nanofabrication, water-harvesting, and mosquito-inspired painless piercing. This is the first textbook on biomimetics and bioinspired surfaces. It is tailored for undergraduate or graduate students of materials science, chemistry, physics, and biology, and serves as an excellent resource for a one-semester course in biomimetics/bioinspiration while also functioning as a valuable textbook for applied nanotechnology courses. Accessible to both novices and experts alike, as well as practitioners, solution seekers, and the intellectually curious, this book is poised to contribute to the advancement of biomimetics, fostering a deeper understanding of nature's design brilliance and its transformative potential in materials science.
Biomaterials. --- Nanotechnology. --- Surfaces (Technology). --- Surfaces (Physics). --- Nanoparticles. --- Sustainability. --- Nanoengineering. --- Surface patterning. --- Surface and Interface and Thin Film. --- Surfaces (Technology) --- Surfaces (Physics)
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This book describes the fundamentals and applicability of the atmospheric-pressure non-thermal plasma surface modification of materials. Non-thermal plasma modification is an effective procedure for chemical activation. In this book, the principles of non-thermal plasma surface modification and its application to various machine parts are described. By reading this book, technologists from a variety of fields can learn about plasma generation and surface treatment technology, which will assist them in performing advanced procedures. This book also explains the basics of atmospheric-pressure plasma and the principle of plasma treatment in an easy-to-understand manner and also provides examples of the application of atmospheric-pressure plasma surface modification technologies to plastics, glass, polymers, and metals. After reading this book, readers can get the knowledge that researchers need to apply the methodology to meet their own research goals. The book is self-contained in the sense that it spans the divide between the fundamentals and more advanced content regarding applications. Many engineers and graduate students working in this field get many helps.
Plasma (Ionized gases). --- Surfaces (Technology). --- Thin films. --- Surfaces (Physics). --- Atmospheric pressure plasmas. --- Surfaces, Interfaces and Thin Film. --- Surface and Interface and Thin Film. --- Basic Plasma Phenomena and Gas Discharges. --- Plasma (Ionized gases) --- Surfaces (Technology) --- Surfaces (Physics)
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Interfacial phenomena play a crucial role in various industrial processes and daily operations. These phenomena are related to the formation of emulsions and foams, adsorption on solid and fluid interfaces, wettability alteration, and others that strongly impact the quality and cost of products and processes. Understanding the interfacial phenomena encompasses inexorably the description of surface thermodynamics and the assessment of thermodynamic properties. The book Fundamentals of Surface Thermodynamics introduces the basics of the thermodynamics of interface from a perspective of chemical engineering thermodynamics and surface chemistry. It provides insights into real-life phenomena, emphasizing the practical significance of abstract properties routinely dealt with by scientists and engineers. The book is tailored for both graduate and undergraduate courses in chemistry and engineering schools. The book content is particularly beneficial for industry professionals involved in oil & gas, fluid transportation, nanotechnology, and other operations with multiphase complex systems, where the process effectiveness is affected by interfacial phenomena. The Fundamentals of Surface Thermodynamics brings a comprehensive description of colloidal science, ranging from conventional surfactant applications to responsive systems and nanomaterials applied to life science. The author invites the reader on a journey into the fascinating world where small-dimension entities breathe. The book aims to inspire students and professionals to delve deep into the intricacies of interface thermodynamics, thereby contributing to supporting education activities and enabling industrial solutions.
Thermodynamics. --- Heat engineering. --- Heat transfer. --- Mass transfer. --- Surfaces (Physics). --- Physical chemistry. --- Engineering Thermodynamics, Heat and Mass Transfer. --- Surface and Interface and Thin Film. --- Physical Chemistry. --- Heat --- Surfaces (Physics) --- Chemistry, Physical and theoretical. --- Transmission.
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