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Supercooled liquids --- Supercooled liquids --- Industrial applications
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Amorphous substances --- Glass --- Polymers --- Supercooled liquids --- Congresses
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Supercooled liquids are found in the atmosphere, in cold hardy organisms, in metallurgy, and in many industrial systems today. Stabilizing the metastable, supercooled state, or encouraging the associated process of nucleation have both been the subject of scientific interest for several hundred years. This book is an invaluable starting point for researchers interested in the supercooling of water and aqueous solutions in biology and industry. The book also deals with modeling and the formation subsequent dendritic growth of supercooled solutions, as well as glass transitions and interface stability.
Supercooled liquids. --- Supercooled fluids --- Liquids --- Solid state chemistry
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This book presents some of the most exciting recent work on supercooled liquids. Topics include domain models of supercooled liquids, inhomogeneity and polymorphism, and Mode-Coupling Theory and its applications. It provides in-depth coverage of supercooled water and of the connections between supercooled liquids and the conformational dynamics of proteins. The introduction includes a detailed discussion of terminology, major problems, and leading theoretical and experimental approaches.
Supercooled liquids --- Engineering & Applied Sciences --- Applied Physics --- Industrial applications --- Congresses --- Congresses.
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This book presents a summary of the topic of supercooling during crystallization in condensed films. While recent findings are mainly published in English, the foundational classical results were originally published in Russian, with limited accessibility to general readers. The present work is based on a 2019 Ukrainian monograph, "Temperature Stability of the Supercooled Liquid Phase in Condensed Films," which has been extensively revised and expanded. The book includes a detailed analysis of the thermodynamics of supercooled fluids, with updated and expanded sections. Additionally, new results on the supercooling of indium-lead (In-Pb) alloys in contact with amorphous molybdenum and fusible metals in contact with nanocrystalline layers are presented. These layers occupy a middle ground between amorphous (carbon, molybdenum, as-deposited germanium films) and polycrystalline (copper, silver, aluminum) substrates. The book gives particular attention to the peculiarities of contractedgeometry conditions, which are natural for multilayered structures and can occur through fusible component segregation at grain boundaries. The analysis of new data has prompted a rethinking of the role of the more refractory layer's microstructure on the crystallization processes of metastable melts. The book includes a thorough discussion of these findings, highlighting the crucial role of the microstructure in the crystallization process. This book is a valuable resource for researchers and students interested in crystallization in thin-film metallic systems. This comprehensive study provides a detailed and authoritative analysis of the thermodynamics of supercooled fluids, and the impact of microstructure on the crystallization processes of metastable melts, making it an essential addition to any academic library.
Supercooled liquids. --- Metals. --- Surfaces (Physics). --- Materials --- Soft condensed matter. --- Metals and Alloys. --- Surface and Interface and Thin Film. --- Characterization and Analytical Technique. --- Fluids. --- Analysis.
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Metastable Liquids provides a comprehensive treatment of the properties of liquids under conditions where the stable state is a vapor, a solid, or a liquid mixture of different composition. It examines the fundamental principles that govern the equilibrium properties, stability, relaxation mechanisms, and relaxation rates of metastable liquids. Building on the interplay of kinetics and thermodynamics that determines the thermophysical properties and structural relaxation of metastable liquids, it offers an in-depth treatment of thermodynamic stability theory, the statistical mechanics of metastability, nucleation, spinodal decomposition, supercooled liquids, and the glass transition. Both traditional topics--such as stability theory--and modern developments--including modern theories of nucleation and the properties of supercooled and glassy water--are treated in detail. An introductory chapter illustrates, with numerous examples, the importance and ubiquity of metastable liquids. Examples include the ascent of sap in plants, the strategies adopted by many living organisms to survive prolonged exposure to sub-freezing conditions, the behavior of proteins at low temperatures, metastability in mineral inclusions, ozone depletion, the preservation and storage of labile biochemicals, and the prevention of natural gas clathrate hydrate formation. All mathematical symbols are defined in the text and key equations are clearly explained. More complex mathematical explanations are available in the appendixes.
Liquids --- Supercooled liquids. --- Phase transformations (Statistical physics) --- Chemistry, Physical and theoretical. --- Thermal properties. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Phase changes (Statistical physics) --- Phase transitions (Statistical physics) --- Phase rule and equilibrium --- Statistical physics --- Supercooled fluids --- Adam-Gibbs theory. --- Ginzburg criterion. --- Kauzmann paradox. --- Laplace equation. --- Maxwell construction. --- antifreeze proteins. --- beta relaxation. --- capillarity approximation. --- critical nucleus. --- crystallization. --- detailed balance. --- dividing surface. --- embryos. --- energetics of formation. --- fragile liquids. --- free energy barrier. --- hard sphere fluid. --- ice. --- interfacial tension. --- mean-field theory. --- non-ergodicity parameter. --- order parameter. --- polyamorphism. --- spinodal curve. --- structural arrest. --- supercooled vapors. --- temperature.
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