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2023 (9)

2020 (1)

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Book
Modes of Cooperative Effects in Dinuclear Complexes
Authors: ---
ISBN: 9783031322501 Year: 2023 Publisher: Cham : Springer International Publishing : Imprint: Springer,

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Abstract

This book presents recent advances in dinuclear complexes in which the metal-metal cooperative effect operates for obtaining substrate activation and high performance catalysts. Catalysis continues to be a fast expanding area to design efficient tools in synthesis and in industrial chemistry. It allows performing syntheses with short reaction times, atom economy, reduced consumption of energy and loss of reagents, and low level of wastes. Dinuclear complexes are known to be more efficient than the mononuclear analogues for the reaction rates and the selectivities. This book analyses the latest research, focusing on the key concepts, in building and using these dinuclear complexes. The book is aimed at researchers, graduate students and chemists at all levels in academia and industry.


Book
2nd International Conference on Industrial Applications of Adhesives 2022 : Selected Contributions of IAA 2022
Authors: --- ---
ISBN: 3031111508 3031111494 Year: 2023 Publisher: Cham : Springer International Publishing : Imprint: Springer,

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This book provides selected papers presented at the 2nd International Conference on Industrial Applications of Adhesives 2022, held in Carvoeiro, Portugal, 3-4 March 2022. The volume focuses on applications of adhesive bonding in the industry such as automotive, aeronautic, railway, marine, energy, and electronics. A wide range of topics like adhesion assessment between polymers and metals, pressure sensitive adhesives, adhesive bonding process optimization, civil applications, adhesive joints in composite materials and elastic adhesives are covered. The book presents the latest results and innovations in this field, useful for adhesive producers and adhesive users.


Book
Weakest Bound Electron Theory and Applications
Author:
ISBN: 9789811966576 Year: 2023 Publisher: Singapore : Springer Nature Singapore : Imprint: Springer,

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This monograph describes the new quantum theory called the weakest bound electron theory (WBE theory) proposed by Prof. Neng-Wu Zheng and its applications. It starts with the fundamentals of quantum mechanics and then illustrates the key points of WBE theory and the mathematical expressions of WBE theory. Finally, it presents a wide range of applications of WBE theory to the chemical and physical properties of atoms and molecules, including energy levels, transition properties, the difference law of ionization energies etc. It appeals to a broad readership, particularly researchers and academics in chemistry, physics, and materials science.


Book
The Nature of Ultralong C-C Bonds
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ISBN: 9789819906703 Year: 2023 Publisher: Singapore : Springer,

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This book focuses on the creation and demonstration of a carbon–carbon (C–C) single bond beyond 1.8 Å and on elucidation of its unique nature. C–C single bond is one of the most fundamental concepts in organic chemistry. The elucidation of its nature is important for further understanding chemical phenomena. The nature in the extreme state of C–C single bond is still unexplored because of the instability of compounds. In terms of its bond length, the limit had been predicted around 1.8 Å based on the experimental and theoretical studies. This book describes a first example of a C–C single bond beyond 1.8 Å by employing the original intramolecular core-shell strategy to make a weak and elongated bond stable enough. The presence of such an elongated bond was demonstrated by experimental and theoretical studies. The bond length changes could affect physical properties such as optical absorption and redox potential. Furthermore, its unique "flexibility" was discovered. This book benefits the chemists with deeper understanding of the covalent bonding. .


Book
Alicyclic Chemistry
Authors: ---
ISBN: 3031360680 3031360672 Year: 2023 Publisher: Cham : Springer Nature Switzerland : Imprint: Springer,

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This textbook is intended for undergraduate and postgraduate students in organic chemistry. It describes the synthesis and properties of cycloalkanes compounds such as cyclopropane, cyclobutane, cyclopentane, cyclohexane, cycloheptane and cycloheptatriene. It further covers the chemistry of ring compounds. The book also covers the reaction mechanisms of non-benzenoid aromatic compounds including annulenes, metallocenes and azulenes. It further contains discussions on tropone, tropolones, fluxional molecules, catenanes and rotaxanes. End-of-chapter exercises such as multiple-choice questions and short answer-questions help students in self-learning. This textbook is useful for undergraduate and postgraduate students in organic chemistry.


Book
Next Generation Quantum Theory of Atoms in Molecules : From Stereochemistry to Photochemistry and Molecular Devices
Authors: ---
ISBN: 9819903297 9819903289 Year: 2023 Publisher: Singapore : Springer Nature Singapore : Imprint: Springer,

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This book begins by providing a simplified version of the computational quantum chemistry sufficient to calculate the wavefunctions that are the basic input of NG-QTAIM. Enough basic (scalar) QTAIM theory is provided to understand the later chapters. In addition, our developments of scalar QTAIM are presented and activities at various levels of difficulty are provided for the readership to facilitate understanding. The topological origins of Quantum Theory of Atoms in Molecules (QTAIM) before explaining the highlights and consequences of the developments of Next-Generation QTAIM (NG-QTAIM) that is a 3-D vector-based realization of QTAIM. The book compiles all developments and extensions of Next-Generation QTAIM in one place for easy reference for those engaged in theoretical/computational chemistry. Essential insights into molecular switch functioning not available from the energy barrier or any scalar measures are presented along with a new measure to assess the efficiency of rotary molecular motors. The book also discusses how the treatment of external forces such as electric fields and laser irradiation is included in NG-QTAIM. This book benefits theoretical/computational chemists/physics/engineers, students (graduate and undergraduate) and chemical/pharmaceutical industry researchers who carry out chemical computations in universities and industries. Where appropriate, Target Learning Outcomes and Further Reading are provided along with a list of the scientific goals to be addressed in addition to a glossary table in the summary sections. Where applicable each chapter concludes by outlining benefits, limitations and suggestions for further investigations. All our NG-QTAIM publications are available as pre-prints in the form of .pdf files along with the corresponding supplementary materials at our BEACON website www.beaconresearch.org.


Book
Naturally occurring organohalogen compounds
Authors: --- --- --- --- --- et al.
ISBN: 3031266293 3031266285 Year: 2023 Publisher: Cham : Springer Nature Switzerland : Imprint: Springer,

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The present volume is the third in a trilogy that documents naturally occurring organohalogen compounds, bringing the total number — from fewer than 25 in 1968 — to approximately 8,000 compounds to date. Nearly all of these natural products contain chlorine or bromine, with a few containing iodine and, fewer still, fluorine. Produced by ubiquitous marine (algae, sponges, corals, bryozoa, nudibranchs, fungi, bacteria) and terrestrial organisms (plants, fungi, bacteria, insects, higher animals) and universal abiotic processes (volcanos, forest fires, geothermal events), organohalogens pervade the global ecosystem. Newly identified extraterrestrial sources are also documented. In addition to chemical structures, biological activity, biohalogenation, biodegradation, natural function, and future outlook are presented.


Book
Superhalogens : properties and applications
Author:
ISBN: 3031375718 303137570X Year: 2023 Publisher: Cham : Springer Nature Switzerland : Imprint: Springer,

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This brief introduces the reader to the topic of superhalogens, a special class of atomic clusters that can potentially mimic the behavior of halogen atoms. It provides an introduction to the history of superhalogens, their conceptualization, and experimental confirmation and discusses in detail their properties and various applications. Some of the applications analyzed in the text include their potential use in the design of superacids, electrolytes for Li-ion batteries, and organic superconductors as well as their use in ionic liquids. The latest developments in the field are also presented. This brief is of great interest to graduates and researchers working at the interface of chemistry, physics, and materials science.


Book
Chemoselective Nucleophilic α-Amination of Amides
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ISBN: 3658300205 3658300191 Year: 2020 Publisher: Wiesbaden : Springer Fachmedien Wiesbaden : Imprint: Springer Spektrum,

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α-Amino carbonyl compounds are omnipresent in all living organisms, making their selective synthesis highly sought after. However, the synthesis of α-amino amides, a subclass of α-amino carbonyls, in the presence of other carbonyls is usually challenging, due to the required harsh conditions. Miran Lemmerer expands a novel chemoselective approach for the synthesis of these intriguing molecules together with Univ.-Prof. Dr. Nuno Maulide’s team. Contents Traditional Umpolung Reactions in Organic Chemistry Insight into Electrophilic Amide Activation Results and Discussion of a New α-Amination Method via Umpolung of Amides α-Arylation of Carbonlys via a Smiles Rearrangement Target Groups Scientists and students in the field of organic chemistry, especially in methodology development The Author Miran Lemmerer is currently pursuing his PhD studies under supervision of Prof. Dr. Nuno Maulide at the Department of Organic Chemistry, University of Vienna, Austria. .


Book
Progress in the Chemistry of Organic Natural Products 122 : Botanical Dietary Supplements and Herbal Medicines
Authors: --- --- --- --- --- et al.
ISBN: 3031267680 3031267672 Year: 2023 Publisher: Cham : Springer Nature Switzerland : Imprint: Springer,

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Abstract

This volume highlights some recent developments on plants used widely as botanical dietary supplements and herbal medicines, especially in terms of knowledge of the chemical types and diverse biological activities of their constituents, as well as laboratory approaches for their quality control and taxonomic identification. In the first chapter, the biologically active secondary metabolites are described of selected botanicals that have a wide current use in the United States, with recent information provided also on their in vitro and in vivo biological activities. The second chapter constitutes an updated survey of the different chromatographic, spectroscopic, and metabolomics techniques that can be utilized for the quality control of botanical products. The penultimate chapter covers different nomenclatural systems that are of use for the taxonomic identification of source plants used in botanical products. Finally, deoxyribonucleic acid molecular barcoding techniques for the identification for plants used as dietary supplements are covered.

Keywords

Dietary Supplements. --- Herbal Medicine. --- Plant Extracts. --- Phytochemicals. --- Chemical Phenomena. --- Chemical Phenomenon --- Chemical Process --- Physical Chemistry Phenomena --- Physical Chemistry Process --- Physicochemical Phenomenon --- Physicochemical Process --- Chemical Concepts --- Chemical Processes --- Physical Chemistry Concepts --- Physical Chemistry Processes --- Physicochemical Concepts --- Physicochemical Phenomena --- Physicochemical Processes --- Chemical Concept --- Chemistry Process, Physical --- Chemistry Processes, Physical --- Concept, Chemical --- Concept, Physical Chemistry --- Concept, Physicochemical --- Concepts, Chemical --- Concepts, Physical Chemistry --- Concepts, Physicochemical --- Phenomena, Chemical --- Phenomena, Physical Chemistry --- Phenomena, Physicochemical --- Phenomenon, Chemical --- Phenomenon, Physicochemical --- Physical Chemistry Concept --- Physicochemical Concept --- Process, Chemical --- Process, Physical Chemistry --- Process, Physicochemical --- Processes, Chemical --- Processes, Physical Chemistry --- Processes, Physicochemical --- Bioactive Coumpounds, Plant --- Biologically Active Coumpounds, Plant --- Dietary Phytochemicals --- Phytochemical --- Phytonutrient --- Phytonutrients --- Plant Bioactive Compounds --- Plant Biologically Active Compounds --- Plant-Derived Chemicals --- Plant-Derived Compounds --- Dietary Phytochemical --- Plant Bioactive Compound --- Plant Biologically Active Compound --- Plant-Derived Chemical --- Plant-Derived Compound --- Bioactive Compound, Plant --- Bioactive Compounds, Plant --- Chemical, Plant-Derived --- Chemicals, Plant-Derived --- Compound, Plant Bioactive --- Compound, Plant-Derived --- Compounds, Plant Bioactive --- Compounds, Plant-Derived --- Coumpounds, Plant Bioactive --- Phytochemical, Dietary --- Phytochemicals, Dietary --- Plant Bioactive Coumpounds --- Plant Derived Chemical --- Plant Derived Chemicals --- Plant Derived Compound --- Plant Derived Compounds --- Secondary Metabolism --- Herbal Medicines --- Plant Extract --- Extract, Plant --- Extracts, Plant --- Medicines, Herbal --- Materia Medica --- Phytotherapy --- Plants, Medicinal --- Herbal Medicine --- Hawaiian Herbal Medicine --- La au Lapa au --- La'au Lapa'au --- Laau Lapaau --- Herbalism --- Medicine, Herbal --- Herbal Medicine, Hawaiian --- Medicine, Hawaiian Herbal --- Naturopathy --- Dietary Supplementations --- Food Supplementations --- Herbal Supplements --- Nutraceuticals --- Nutriceuticals --- Food Supplements --- Neutraceuticals --- Dietary Supplement --- Food Supplement --- Herbal Supplement --- Neutraceutical --- Nutraceutical --- Nutriceutical --- Supplement, Food --- Supplement, Herbal --- Supplementations, Dietary --- Supplements, Dietary --- Supplements, Food --- Supplements, Herbal --- Functional Food --- Natural products. --- Biomaterials. --- Nucleic acids. --- Chemical structure. --- Natural Products. --- Nucleic Acid. --- Structure And Bonding. --- Plant Materials. --- Structure, Chemical --- Chemistry, Physical and theoretical --- Matter --- Polynucleotides --- Biomolecules --- Products, Natural --- Raw materials --- Constitution

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