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Ceramic materials --- Composite materials --- Glass --- Biomedical materials --- Sol-gel, Procédé. --- Matériaux céramiques. --- Composites --- Verre --- Biomatériaux. --- Résumés analytiques. --- Sol-gel, Procédé. --- Matériaux céramiques. --- Biomatériaux. --- Résumés analytiques.

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This thesis focuses on porous monolithic materials that are not in the forms of particles, fibers, or films. In particular, the synthetic strategy of porous monolithic materials via the sol-gel method accompanied by phase separation, which is characterized as the non-templating method for tailoring well-defined macropores, is described from the basics to actual synthesis. Porous materials are attracting more and more attention in various fields such as electronics, energy storage, catalysis, sensing, adsorbents, biomedical science, and separation science. To date, many efforts have been made to synthesize porous materials in various chemical compositions-organics, inorganics including metals, glasses and ceramics, and organic-inorganic hybrids. Also demonstrated in this thesis are the potential applications of synthesized porous monolithic materials to separation media as well as to electrodes for electric double-layer capacitors (EDLCs) and Li-ion batteries (LIBs). This work is ideal for graduate students in materials science and is also useful to engineers or scientists seeking basic knowledge of porous monolithic materials.

Chemical thermodynamics --- Electrochemistry --- Macromolecules --- Inorganic chemistry --- Chemistry --- Enzymology --- Relation between energy and economics --- Materials sciences --- Chemical technology --- katalyse --- thermodynamica --- materiaalkennis --- lithium-ion batterijen --- biochemie --- chemie --- biotechnologie --- anorganische chemie --- chemische technologie --- polymeren --- moleculaire biologie --- elektrochemie --- enzymen --- Porous materials. --- Nanostructured materials --- Matériaux poreux. --- Matériaux nanostructurés. --- Sol-gel, Procédé.

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Sol-Gel Science presents the physical and chemical principles of the sol-gel process at a level suitable for graduate students and practitioners in the field. This book defines sol-gel rather broadly as the preparation of ceramic materials by preparation of a sol, gelation of the sol, and removal of the solvent. The sol may be produced from inorganic or organic precursors (e.g., nitrates or alkoxides) and may consist of dense oxide particles of polymeric clusters. Brinker expands the definition of ceramics to include organically modified materials, often called ORMOSILs or CERAMERs. The emphasis of the author' treatment is on the science, rather than the technology, of sol-gel processing. Although a chapter on applications is included, more detailed discussion is available in proceedings of conferences and in the recent collection of articles, 'Sol-Gel Technology for thin films, Fibers, Preforms, Electronics, and Specialty Shapes (Noyes, Park Ridge, N.J., 1988), edited by professor Lisa Klein.

Surface chemistry --- fysicochemie --- Ceramic materials --- Colloids --- Matériaux céramiques --- Colloïdes --- 54-148 --- #WSCH:AAS1 --- Dispersoids --- Gels --- Hydrogels --- Sols --- Amorphous substances --- Chemistry, Physical and theoretical --- Diffusion --- Matter --- Micelles --- Particles --- Rheology --- Solution (Chemistry) --- Ceramic industries --- Ceramics --- Mines and mineral resources --- Colloidal state with liquid continuous phase. Suspensions. Emulsions. Sols. Gels. Foams --- Properties --- Materials --- Ceramic materials. --- Colloids. --- 54-148 Colloidal state with liquid continuous phase. Suspensions. Emulsions. Sols. Gels. Foams --- Hydrolysis --- Polymerization --- Gelation --- Surfaces --- Sintering --- Thin films --- Sol-gel, Procédé --- Hydrolyse --- Polymérisation --- Gélification --- Frittage (métallurgie) --- Couches minces --- Matériaux céramiques --- Colloïdes --- Colloïdes. --- Matériaux céramiques. --- Sol-gel, Procédé. --- Hydrolyse. --- Polymérisation. --- Gélification. --- Surfaces. --- Couches minces. --- Monograph --- Colloïdes. --- Matériaux céramiques. --- Sol-gel, Procédé. --- Polymérisation. --- Gélification. --- Frittage (métallurgie)