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A comprehensive and detailed description of the most widely used sample introduction techniques in atomic spectroscopy is presented in this volume. Comprising twelve separate chapters, the book describes the theory in detail, and gives an account of techniques and selected applications of sample introduction systems. The first chapter is a general overview on sample introduction. The remaining eleven chapters are each devoted to a specific sample introduction and deal with the basic principles, describe the system, advantages, disadvantages and selected applications. Systems described are: pne
Atomic spectroscopy --- Sample introduction (Chemistry) --- Technique.
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Gas chromatography --- Sample introduction (Chemistry) --- Methodology
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The book starts with a detailed description of ICP-MS, including quadruple-based, sector-based and time-of-flight instruments. Instrumentation from existing manufacturers is described and compared to show their similarities and differences. Also, a review of the ICP-MS literature is carried out to outline both the strengths and limitations of the technique, whatever its brand, as well as what it can currently accomplish in terms of applications. Then, the book demonstrates how these limitations can be reduced and/or eliminated by combining various techniques with ICP-MS. Great detail is provided on each technique so that the reader can get a good understanding of it before carrying on to the instrumental requirements for its hyphenation to ICP-MS, and the resulting impact on the operation of the hyphenated instrument. Since this book is concerned with the ICP side only, which is fairly similar in all the instruments from the different manufacturers, the information should be useful to all ICP-MS users. The features and limitations of each technique are thoroughly discussed and illustrated with a review of the ICP-MS literature. Approaches which could be used but have not yet been tried with ICP-MS are also suggested. This is particularly true of flow injection techniques which are extremely flexible and have been used extensively in atomic spectroscopy and spectrophotometry. Many of the features of the technique have not yet been combined to ICP-MS, and one purpose of the book will be to point out potentially beneficial combinations.
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Sample preparation is an essential step in many analyses. This book approaches the topic of sample preparation in chromatography in a methodical way, viewing it as a logical connection between sample collection and analytical chromatography. Providing a guide for choosing the appropriate sample preparation for a given analysis, this book describes various ways to process the sample, explaining the principle, discussing the advantages and disadvantages, describing the applicability to different types of samples, and showing the fitness to specific chromatographic determinations. The fir
Chromatographic analysis. --- Chromatography --- Sample introduction (Chemistry). --- methods. --- Sample introduction (Chemistry) --- Application of chemical samples --- Introduction of chemical samples --- Presentation of chemical samples --- Sample application (Chemistry) --- Sample presentation (Chemistry) --- Analytical chemistry --- Analysis, Chromatographic --- Phase partition --- Technique
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Fysicochemical separation methods --- Gas chromatography --- -Sample introduction (Chemistry) --- Application of chemical samples --- Introduction of chemical samples --- Presentation of chemical samples --- Sample application (Chemistry) --- Sample presentation (Chemistry) --- Chemistry, Analytic --- Gas-liquid chromatography --- GLC (Chromatographic analysis) --- Vapor-phase chromatography --- Chromatographic analysis --- Methodology --- Technique --- Sample introduction (Chemistry) --- Methodology. --- Sample introduction (Chemistry). --- Analytical chemistry
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Physicochemistry --- fysicochemie --- Analysis of pharmaceuticals --- Fysicochemical separation methods --- Gas chromatography --- Sample introduction (Chemistry) --- Application of chemical samples --- Introduction of chemical samples --- Presentation of chemical samples --- Sample application (Chemistry) --- Sample presentation (Chemistry) --- Chemistry, Analytic --- Gas-liquid chromatography --- GLC (Chromatographic analysis) --- Vapor-phase chromatography --- Chromatographic analysis --- Technique --- Gas chromatography. --- Sample introduction (Chemistry). --- Analytical chemistry
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The direct determination of elements in solid samples by atomspectrometric methods without prior digestion is in many cases more efficient and reliable, faster, easier, more cost-effective and less time-consuming than other methods. In this first book on the topic the authors describe concisely all instrumental and methodological features, including calibration, influences from the matrix or sample inhomogeneities, optimisation, data analysis and measurement uncertainty. Special chapters deal with ET-AAS, slurry injection, ETV-ICP-AE/MS coupling. The authors' aim to deliver all their experience in a way that enables the spectroscopist to develop their own solid sampling based methods makes this book an unvaluable source for AAS- and AES-practitioners.
Furnace atomic absorption spectroscopy. --- Sample introduction (Chemistry) --- Solids --- Basic Sciences. Chemistry --- Analysis. --- Analytical Chemistry --- Sample introduction (Chemistry). --- Analytical Chemistry. --- Analytical chemistry. --- Analysis, Chemical --- Analytic chemistry --- Chemical analysis --- Chemistry, Analytic --- Chemistry --- Atomic absorption spectrometry --- Atomic emission spectrometry --- Inductively coupled plasma mass spectrometry --- Sampling --- Slurries --- Solid analysis
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