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The first edition of this book, published in 1966, received wide acclaim. This new edition has been almost entirely rewritten and expanded to incorporate the extensive research done in this field over the last two decades. The book provides a unified treatment, from a mechanistic viewpoint, of those reactions of unsaturated organic compoiunds which, being initiated by co-ordination with an electrophilic reagent, proceed through intermediates having cationic character, and are completed by the formation of products of addition. After a brief account of the properties of carbocations, electroph

Compounds, Unsaturated. --- Addition reactions. --- Composés insaturés --- Réactions d'addition --- Compounds, Unsaturated --- Addition reactions --- Composés insaturés --- Réactions d'addition --- Chemical reactions --- Unsaturated compounds

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Chemical Kinetics and Mechanism considers the role of rate of reaction. It begins by introducing chemical kinetics and the analysis of reaction mechanism, from basic well-established concepts to leading edge research. Organic reaction mechanisms are then discussed, encompassing curly arrows, nucleophilic substitution and E1 and E2 elimination reactions. The book concludes with a Case Study on Zeolites, which examines their structure and internal dimensions in relation to their behaviour as molecular sieves and catalysts. The accompanying CD-ROM contains the "Kinetics Toolkit", a graph-plotting application designed for manipulation and analysis of kinetic data, which is built into many of the examples, questions and exercises in the text. There are also interactive activities illustrating reaction mechanisms.

kinetica --- fysicochemie --- Thermodynamics --- reactiekinetiek --- Physicochemistry --- Chemical thermodynamics --- thermodynamica --- 541.12 --- 541.12 Chemical mechanics --- Chemical mechanics --- Chemical kinetics. --- Chemical reaction, Conditions and laws of. --- Organic reaction mechanisms. --- Substitution reactions. --- Elimination reactions. --- Addition reactions. --- Cinétique chimique --- Réactions chimiques --- Réactions organiques (Chimie) --- Reactions de substitution --- Réactions d'élimination --- Réactions d'addition --- Mécanismes