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A comprehensive account of the physical / mechanical behaviour of polyurethanes (PU´s) elastomers, films and blends of variable crystallinity. Aspects covered include the elasticity and inelasticity of amorphous to crystalline PUs, in relation to their sensitivity to chemical and physical structure. A study is made of how aspects of the constitutive responses of PUs vary with composition: the polyaddition procedure, the hard segment, soft segment and chain extender (diols and diamines) are varied systematically in a large number of systems of model and novel crosslinked andthermoplastic PUs. Results will be related to: microstructural changes, on the basis of evidence from x-ray scattering (SAXS and WAXS), and also dynamic mechanical analyses (DMA), differential scanning calorimetry (DSC) and IR dichroism. Inelastic effects will be investigated also by including quantitative correlations between the magnitude of the Mullins effect and the fractional energy dissipation by hysteresis under cyclic straining, giving common relations approached by all the materials studied. A major structural feature explored is the relationship between the nature of the hard segment (crystallising or not) and that of the soft segments. Crystallinity has been sometimes observed in the commercial PUs hard phase but this is usually limited to only a few percent for most hard segment structures when solidified from the melt. One particular diisocyanate, 4,4’-dibenzyl diisocyanate (DBDI) that, in the presence of suitable chain extenders ( diols or diamines), gives rise to significant degrees of crystallinity [i-iii] and this is included in the present work. Understanding the reaction pathways involved, in resolving the subtle morphological evolution at the nanometre level, and capturing mathematically the complex, large-deformation nonlinear viscoelastic mechanical behaviour are assumed to bring new important insights in the world basic research in polyurethanes and towards applied industrial research in this area.
Polyurethane elastomers. --- Polyurethanes -- Industrial applications. --- Polyurethane elastomers --- Elastomers --- Chemistry --- Chemical & Materials Engineering --- Physical Sciences & Mathematics --- Engineering & Applied Sciences --- Chemical Engineering --- Organic Chemistry --- Elastomers. --- Elastomeric materials --- Reinforced elastomers --- Urethane elastomers --- Chemistry. --- Polymers. --- Crystallography. --- Materials science. --- Polymer Sciences. --- Characterization and Evaluation of Materials. --- Polymers --- Plastics --- Rubber --- Surfaces (Physics). --- Crystallography and Scattering Methods. --- Physics --- Surface chemistry --- Surfaces (Technology) --- Leptology --- Physical sciences --- Mineralogy --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Polymers . --- Material science
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There is increasingly intensive research for energy storage technologies development due to the enhanced energy needs of the contemporary societies. Increased global energy consumption results in the reduction in the availability of traditional energy resources, such as coal, oil and natural gas. Therefore, there is an urgent need for new systems development based on the conversion and storage of sustainable and clean energy. Phase change materials (PCMs) are one of the key components for the development of advanced sustainable solutions in renewable energy and engineering systems. In order to update the field of renewable energy and engineering systems with the use of PCMs, a Special Issue entitled “Phase Change Materials: Design and Applications” is introduced. This book gathers and reviews the collection of ten contributions (nine articles and one review), with authors from Europe, Asia and Americam accepted for publication in the aforementioned Special Issue of Applied Sciences.
Research & information: general --- Physics --- phase change materials --- thermal energy storage --- energy efficiency --- building applications --- construction materials --- phase-change material --- dispersion --- thermal-mechanical stability --- viscosity --- supercooling --- nucleating agent --- cold storage --- battery cooling --- LPMO --- Fourier Transform ac Voltammetry (FTacV) --- cyclic voltammetry --- Direct Electron Transfer (DET) --- lathrate hydrate --- tetrabutylammonium acrylate (TBAAc) --- crystal growth --- ultrasonic vibration --- polyurethane elastomers --- microencapsulated PCMs --- thermal properties --- mechanical properties --- phase change material --- sugar alcohol --- erythritol --- latent heat storage --- thermal stability --- degradation kinetics --- PCM --- mini-channels --- air --- melting --- solidification --- latent heat thermal energy storage --- phase change materials (PCM) --- macro-encapsulation --- rectangular slab --- experimental study --- sodium nitrate --- thermal conductivity --- microencapsulation --- latent heat --- multicriteria decision --- finite element --- automotive --- energy storage --- n/a
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There is increasingly intensive research for energy storage technologies development due to the enhanced energy needs of the contemporary societies. Increased global energy consumption results in the reduction in the availability of traditional energy resources, such as coal, oil and natural gas. Therefore, there is an urgent need for new systems development based on the conversion and storage of sustainable and clean energy. Phase change materials (PCMs) are one of the key components for the development of advanced sustainable solutions in renewable energy and engineering systems. In order to update the field of renewable energy and engineering systems with the use of PCMs, a Special Issue entitled “Phase Change Materials: Design and Applications” is introduced. This book gathers and reviews the collection of ten contributions (nine articles and one review), with authors from Europe, Asia and Americam accepted for publication in the aforementioned Special Issue of Applied Sciences.
phase change materials --- thermal energy storage --- energy efficiency --- building applications --- construction materials --- phase-change material --- dispersion --- thermal-mechanical stability --- viscosity --- supercooling --- nucleating agent --- cold storage --- battery cooling --- LPMO --- Fourier Transform ac Voltammetry (FTacV) --- cyclic voltammetry --- Direct Electron Transfer (DET) --- lathrate hydrate --- tetrabutylammonium acrylate (TBAAc) --- crystal growth --- ultrasonic vibration --- polyurethane elastomers --- microencapsulated PCMs --- thermal properties --- mechanical properties --- phase change material --- sugar alcohol --- erythritol --- latent heat storage --- thermal stability --- degradation kinetics --- PCM --- mini-channels --- air --- melting --- solidification --- latent heat thermal energy storage --- phase change materials (PCM) --- macro-encapsulation --- rectangular slab --- experimental study --- sodium nitrate --- thermal conductivity --- microencapsulation --- latent heat --- multicriteria decision --- finite element --- automotive --- energy storage --- n/a
Choose an application
There is increasingly intensive research for energy storage technologies development due to the enhanced energy needs of the contemporary societies. Increased global energy consumption results in the reduction in the availability of traditional energy resources, such as coal, oil and natural gas. Therefore, there is an urgent need for new systems development based on the conversion and storage of sustainable and clean energy. Phase change materials (PCMs) are one of the key components for the development of advanced sustainable solutions in renewable energy and engineering systems. In order to update the field of renewable energy and engineering systems with the use of PCMs, a Special Issue entitled “Phase Change Materials: Design and Applications” is introduced. This book gathers and reviews the collection of ten contributions (nine articles and one review), with authors from Europe, Asia and Americam accepted for publication in the aforementioned Special Issue of Applied Sciences.
Research & information: general --- Physics --- phase change materials --- thermal energy storage --- energy efficiency --- building applications --- construction materials --- phase-change material --- dispersion --- thermal-mechanical stability --- viscosity --- supercooling --- nucleating agent --- cold storage --- battery cooling --- LPMO --- Fourier Transform ac Voltammetry (FTacV) --- cyclic voltammetry --- Direct Electron Transfer (DET) --- lathrate hydrate --- tetrabutylammonium acrylate (TBAAc) --- crystal growth --- ultrasonic vibration --- polyurethane elastomers --- microencapsulated PCMs --- thermal properties --- mechanical properties --- phase change material --- sugar alcohol --- erythritol --- latent heat storage --- thermal stability --- degradation kinetics --- PCM --- mini-channels --- air --- melting --- solidification --- latent heat thermal energy storage --- phase change materials (PCM) --- macro-encapsulation --- rectangular slab --- experimental study --- sodium nitrate --- thermal conductivity --- microencapsulation --- latent heat --- multicriteria decision --- finite element --- automotive --- energy storage
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