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Kinetics and reactor modeling for heterogeneous catalytic reactions are prominent tools for investigating and understanding catalyst functionalities at nanoscale and the related rates of complex reaction networks. This book illustrates some examples related to the transformation of simple to more complex feedstocks, including different types of reactor designs, i.e., steady-state, transient plug flow reactors, and TAP reactors for which there is sometimes a strong gap in the operating conditions from ultra-high-vacuum to high-pressure conditions. In conjunction, new methodologies have emerged, giving rise to more robust microkinetics models. As exemplified, they include the kinetics and the dynamics of the reactors and span a large range of length and time scales. The objective of this Special Issue is to provide contributions that can illustrate recent advances and novel methodologies for elucidating the kinetics of heterogeneous reactions and the necessary multiscale approach for optimizing the reactor design. This book is dedicated to postgraduate and scientific researchers, and experts in heterogeneous catalysis. It may also serve as a source of original information for the elaboration of lessons on catalysis for Master students.
microkinetics --- n/a --- internal effectiveness factor --- FTIR spectroscopy --- automation --- power-law --- AEIR method --- promoter --- TAP reactor --- rhodium --- Temkin model --- mechanism analysis --- H2S --- N2O --- catalytic decomposition --- cracking --- 1 --- 2 --- methanol-to-olefins (MTO) --- zeolite --- ZSM-23 --- kinetic model --- pilot-scale fixed-bed reactor --- methane --- effective diffusion coefficient --- SAPO-18 --- kinetics --- alkali metal --- ZSM-5 --- digitalization --- gas-phase oxidation --- kinetic modeling --- temporal analysis of products --- selective oxidation --- Methyl Ethyl Ketone --- amorphous calcium phosphate --- reactor modeling --- HNO3 --- 3-Butadiene --- transient kinetics --- catalytic combustion --- cobalt mixed oxide --- 3-Butanediol dehydration --- ammonia decomposition --- heats of adsorption --- Pd/?-Al2O3 --- SAPO-34 --- Langmuir–Hinshelwood --- hierarchical graphite felts
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The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.
sustainable ammonia synthesis --- Pt3Sn alloy --- alkenols --- n/a --- PtSn alloy --- propane dehydrogenation --- chelate --- photodegradation --- gold nanoparticles --- photochemical --- alkynols --- triple bond electron charge --- palladium catalyst --- Pt/Al2O3 --- 2-methyl-3-butyn-2-ol --- hydrogen storage --- X-ray crystallography --- ruthenium --- platinum dispersion --- gold catalysts --- reduction temperature --- DOC --- palladium --- renewable hydrogen --- 1-propanol --- 4-hydroxyproline --- glycerol --- 2-?-benzylproline --- proline --- hydrogen bonding --- oxidative coupling --- glucose oxidation --- stabilizing agent --- titania --- 4-fluoroproline --- turnover frequency --- porous carbons --- Pt–Sn/Al2O3 --- P25@Pd --- catalyst synthesis --- 2-propanol --- amino acid --- azetidine --- precious metals --- clay --- gas phase hydrogenation --- CNTs --- 3-butyn-2-ol --- Pd/Al2O3 --- heterogeneous enantioselective hydrogenation --- XPS --- microwave --- caesium --- perovskite --- CO oxidation --- Au–TiO2 --- dodecahydro-N-ethylcarbazole --- phenol photo-degradation --- pipecolinic acid --- 3-butyn-1-ol --- acetophenone --- drying --- palladium catalysts --- N-methylproline --- dehydrogenation --- PVA --- aging --- hydrodechlorination --- hydrogenolysis --- dispersion --- direct reduction --- core-shell --- Pt-Sn/Al2O3 --- Au-TiO2
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