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The book provides a penetrating and comprehensive description of energy selected reactions from a theoretical as well as experimental point of view. It presents three major aspects of unimolecular reactions involving the preparation of the reactants in selected energy states, the rate of dissipation of the activated molecule, and the partitioning of the excess energy among the final products.
Unimolecular reactions. --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Chemistry. --- Physical sciences --- POTENTIAL ENERGY SURFACE --- REACTION, UNIMOLECULAR --- MOLECULAR VIBRATION --- POTENTIAL ENERGY AND FUNCTION --- CLUSTERS --- MOLECULES --- REACTION KINETICS --- ROTATIONAL-VIBRATIONAL STATE --- VIBRATIONAL ENERGY --- CLUSTER COLLISIONS --- REACTIONS
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Chemical thermodynamics --- fysicochemie --- 541.124 --- Unimolecular reactions --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Limits of reactions --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- MOLECULES --- QUANTUM MECHANICS --- ACTIVATION ENERGY --- ENERGY LEVEL --- ISOTOPE EFFECT --- ENERGY TRANSFER --- REACTIONS
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Unimolecular reactions --- Quantum chemistry --- 541.124 --- 530.145 --- #WSCH:AAS1 --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Chemistry, Quantum --- Chemistry, Physical and theoretical --- Quantum theory --- Excited state chemistry --- Limits of reactions --- 530.145 Quantum theory --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Collisions --- Relaxation
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Chemical kinetics. --- Unimolecular reactions. --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry)
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Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade.This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aimi
Chemical kinetics. --- Unimolecular reactions. --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry)
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Chemical thermodynamics --- fysicochemie --- Unimolecular reactions --- 541.124 --- Statistical mechanics --- #WSCH:MACC --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Mechanics --- Mechanics, Analytic --- Quantum statistics --- Statistical physics --- Thermodynamics --- Limits of reactions --- Statistical mechanics. --- Unimolecular reactions. --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Energy transfer. --- Activation energy --- Fragmentation reaction --- Thermal decomposition
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Chemical reaction, Conditions and laws of --- Molecular theory --- Réactions chimiques --- Théorie moléculaire --- Mécanismes --- 541.124.7 --- 543.51 --- Unimolecular reactions --- #WSCH:AAS1 --- Chemistry, Physical and theoretical --- Matter --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Coupled reactions. Chain reactions. Thermal activation, dissociation, ionization --- Positive ray analysis. Mass spectrometry --- Constitution --- 543.51 Positive ray analysis. Mass spectrometry --- 541.124.7 Coupled reactions. Chain reactions. Thermal activation, dissociation, ionization --- Réactions chimiques --- Théorie moléculaire --- Mécanismes --- Mass spectrometry. --- Quantum transition --- Reaction (chemistry)
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Chemical reaction, Conditions and laws of --- Chemical kinetics --- Gases, Ionized --- Réactions chimiques --- Cinétique chimique --- Mécanismes --- 541.124 --- Ionized gases --- Unimolecular reactions --- #WSCH:AAS1 --- Monomolecular reactions --- Reactions, Monomolecular --- Reactions, Unimolecular --- Chemical reactions --- Gases --- Chemical reaction, Kinetics of --- Chemical reaction, Rate of --- Chemical reaction, Velocity of --- Chemical reaction rate --- Chemical reaction velocity --- Kinetics, Chemical --- Rate of chemical reaction --- Reaction rate (Chemistry) --- Velocity of chemical reaction --- Chemical affinity --- Reactivity (Chemistry) --- Limits of reactions --- 541.124 Chemical dynamics in general. Reaction mechanism in general --- 541.124 Limits of reactions --- Chemical dynamics in general. Reaction mechanism in general --- Ionized gases. --- Réactions chimiques --- Cinétique chimique --- Mécanismes --- CHEMICAL KINETICS --- CHROMATOGRAPHY --- IONIZED GASES --- PROTEINS --- PURIFICATION --- UNIMOLECULAR REACTIONS --- PREPARATION
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