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"In recent years, molecular modelling has become an indispensable tool for studying the structure and dynamics of molten salts. In this chapter we first provide a short description of the state-of-the-art models and methods used for modelling molten salts at the atomic scale. In particular, we discuss the importance of polarization effects for obtaining accurate results. We then give some examples of the structure of several molten salts, as yielded by the simulations. We finish by describing how the transport properties, which encompass the diffusion coefficients, electrical conductivities, viscosities and thermal conductivities, are computed. By comparing the values given by the simulations to reference experimental data, we show that this technique can now be considered as highly predictive"--
Fused salts --- Molten salts --- Salts --- Analysis.
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Chemistry, Inorganic. --- Ionization. --- Molten salts. --- Solution (Chemistry). --- Superacids.
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Physico-Chemical Analysis of Molten Electrolytes includes selected topics on the measurement and evaluation of physico-chemical properties of molten electrolytes. It describes the features, properties, and experimental measurement of different physico-chemical properties of molten salt systems used as electrolytes for different metal production, metallic layer deposition, as a medium for reactions in molten salts. The physico-chemical properties such as phase equilibria, density (molar volume), enthalpy (calorimetry), surface tension, vapor pressure, electrical conductivity, vis
Fused salts. --- Electrolyte solutions. --- Polyelectrolyte solutions --- Solutions, Electrolyte --- Electrolytes --- Solution (Chemistry) --- Molten salts --- Salts
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Ionic solutions. --- Fused salts --- Electrochemistry. --- Chemistry, Physical and theoretical --- Molten salts --- Salts --- Solutions, Ionic --- Ions --- Solution (Chemistry) --- Industrial applications.
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Ionic solutions. --- Ionic solutions --- Salts. --- Fused salts --- Industrial applications. --- Purification. --- Molten salts --- Salts --- Chemistry --- Salt deposits --- Salinity --- Solutions, Ionic --- Ions --- Solution (Chemistry)
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Metal Catalysed Reactions in Ionic Liquids by Paul J. Dyson and Tilmann J. Geldbach Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalysed reactions in ionic liquids and covers the literature from its origins until early 2005. The book begins with a general introduction to the field of biphasic/multiphasic catalysis and describes the synthesis, functionalisation and fundamental properties of ionic liquids relevant to catalysis. In the following chapters catalysed reactions are discussed according to their type, including: hydrogenation hydroformylation oxidation C-C coupling reactions metathesis dimerisation polymerisation Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are discussed. In addition, specific processes such as supported ionic liquid phase catalysis, continuous processes using CO2 extraction and nanoparticle catalysis are covered. This book is an invaluable resource for all those working in catalysis, green chemistry, and advanced synthetic methods, especially advanced level undergraduate and graduate students and those researching or contemplating research in biphasic or multiphasic catalysis using ionic liquids. .
Catalysis. --- Fused salts. --- Ionic structure. --- Ionic solutions. --- Metal catalysts. --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Catalysts --- Solutions, Ionic --- Ions --- Solution (Chemistry) --- Structure, Ionic --- Structure of ions --- Chemical structure --- Molten salts --- Salts --- Structure --- Chemistry, inorganic. --- Chemistry, Organic. --- Inorganic Chemistry. --- Organic Chemistry. --- Organic chemistry --- Chemistry --- Inorganic chemistry --- Inorganic compounds --- Inorganic chemistry. --- Organic chemistry.
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This book contains the lecture notes for the NATO Advanced Research Workshop on th Green Industrial Applications of Ionic Liquids held April 12th_16 , 2000 in Heraklion, Crete, Greece. This was the fIrst international meeting devoted to research in the area of ionic liquids (salts with melting points below 100 0c), and was intended to explore the promise of ionic liquids as well as to set a research agenda for the fIeld. It was the fIrst international meeting dedicated to the study and application of ionic liquids as solvents, and forty-one scientists and engineers from academia, industry, and government research laboratories (as well as six industry observers and four student assistants) met to discuss the current and future status of the application of ionic liquids to new green industrial technologies. It was immediately clear that the number of organic chemists and engineers working in the fIeld needed to be increased. It was also clear that the declining interest in high temperature molten salts and subsequent increase in low melting ionic liquid solvents had not yet taken hold in Eastern Europe. Participants from NATO Partner Countries contributed signifIcant expertise in high temperature molten salts and were able to take back a new awareness and interest in ionic liquid solvents.
Fused salts --- Environmental chemistry --- Sels fondus --- Chimie de l'environnement --- Industrial applications --- Congresses. --- Congresses --- Applications industrielles --- Congrès --- Molten salts --- Salts --- Sustainable chemistry --- Conferences - Meetings --- Organic chemistry. --- Physical chemistry. --- Organic Chemistry. --- Physical Chemistry. --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Organic chemistry
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Bond energy. --- Charge-transfer complex. --- Chromophores. --- Color indicators. --- Complex formation. --- Dimeric. --- Dissociation energy. --- Donor strength. --- Electron affinity. --- Electronegativity. --- Entropy. --- Exchange reactions. --- Fluorination. --- Free energy. --- Halides. --- Halogenation. --- Halogens. --- Heats of formation. --- IR. --- Ion affinities. --- Ionization potential. --- Metal-halogen bond. --- Metal-halogen vibration. --- Metal-metal bond. --- Molten salts. --- NMR. --- Oxidation numbers. --- Oxidation state. --- Solvent system. --- Stereochemistry. --- Thermodynamics.
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Here, the authors provide a unified concept for understanding multi-electron processes in electrochemical systems such as molten salts, ionic liquids, or ionic solutions. A major advantage of this concept is its independence of assumptions like one-step many-electron transfers or ‘discrete’ discharge of complex species. Therefore this monograph is a unique resource for basic electrochemical research but also for many important applications such as electrodeposition, electrorefining, or electrowinning of polyvalent metals from molten salts and other ionic media.
Electrochemistry. --- Electrolytes. --- Fused salts. --- Ionic solutions. --- Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Solutions, Ionic --- Molten salts --- Chemistry. --- Energy storage. --- Materials --- Thin films. --- Energy Storage. --- Surfaces and Interfaces, Thin Films. --- Surfaces. --- Chemistry, Physical and theoretical --- Ions --- Solution (Chemistry) --- Salts --- Surfaces (Physics). --- Physics --- Surface chemistry --- Surfaces (Technology) --- Physical sciences --- Materials—Surfaces. --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Coatings --- Thick films --- Storage of energy --- Force and energy --- Power (Mechanics) --- Flywheels --- Pulsed power systems
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