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This computational study investigates diverse bonding situations in nanostructures (carbon nanotubes, fullerenes, metal compounds) spanning a broad range of energies. Weak, dispersive interactions and covalent metal-ligand and metal-metal bonding are examined. The results of efficient density functional calculations are compared to those of correlated wavefunction calculations on model systems. This rigorous validation is crucial in evaluating the balance between computational cost and accuracy.

open-cage fullerenes --- single-walled carbon nanotubes --- subvalent aluminium and magnesium compounds --- computational chemistry --- nanostructures

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The book provides an introduction to the topic of magnesium materials for biomedical applications. Additional to the background on magnesium's physical, chemical and mechanical properties, areas of use, related diseases and pathways for biodegradation will be discussed. Also, an outlook of the future of magnesium material applications will be provided.

Magnesium compounds. --- Magnesium alloys. --- Physical metallurgy. --- Thixotropy. --- Magnésium --- Métallurgie physique. --- Thixotropie. --- Composés. --- Alliages. --- Magnésium --- Métallurgie physique. --- Composés.

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The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as

Organomagnesium compounds. --- Organic compounds --- Composés organiques --- Synthesis. --- Synthèse --- 547.057 --- 546.46 --- Organic chemistry--?.057 --- Magnesium Mg --- 546.46 Magnesium Mg --- 547.057 Organic chemistry--?.057 --- Composés organiques --- Synthèse --- Grignard reagents. --- Grignard reaction --- Chemical tests and reagents --- Organomagnesium compounds --- Magnesium organic compounds --- Magnesium compounds --- Organometallic compounds --- Grignard reagents --- ORGANIC COMPOUNDS --- MAGNESIUM COMPOUNDS --- ORGANOMETALLIC COMPOUNDS --- PREPARATION --- REACTIONS

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Nicholas Basta, Chemical Engineering, December 1992

Chemistry, Technical --- Chemistry [Technical ] --- Encyclopedias --- Chemical technologies --- Chemistry, Technical. --- ENCYCLOPEDIAS --- Chemical technology --- Industrial chemistry --- Technical chemistry --- Chemistry --- Technology --- Chemical engineering --- Monograph --- Chemical Engineering --- Chemical & Materials Engineering --- Engineering & Applied Sciences --- Optical detectors. --- Patents. --- Petroleum. --- Gases. --- Materials. --- Microbiology. --- Nanoparticles. --- Optical rotation. --- Aquaculture --- Coal. --- Coating processes. --- Coatings. --- Colloids. --- Combustion --- Glass. --- Information science. --- Infrared spectroscopy. --- Insects. --- Ion exchange. --- Iron compounds. --- Ketones. --- Laboratories. --- Raman spectroscopy. --- Rare earth metal compounds. --- Immunoassay. --- Immunochemistry. --- Carbohydrates. --- Heat --- Mass transfer. --- Disinfection. --- Transmission. --- Computer software. --- Cosmetics. --- Databases. --- Composites --- Ceramics. --- Fuel. --- Genetic engineering. --- Heat exchangers. --- Nuclear fusion. --- Digestive System. --- Growth Substances. --- Géotextiles --- Lasers. --- Lead compounds. --- Lead. --- Light. --- Liquids. --- Manganese compounds. --- Mass spectrometry. --- Nuclear magnetic resonance. --- Marketing --- Actinide elements. --- Adsorption --- Aérosols --- Pollution atmosphérique --- Chemistry, Forensic. --- Flotation. --- Fluid mechanics. --- Fluidization. --- Fluorine compounds. --- Fluorine. --- Food additives. --- Food contamination. --- Food handling. --- Fuel cells. --- Digestive System --- Growth Substances --- Disinfection --- Benzene, ethenyl --- Benzene, ethenyl, polymers --- Butanedioic acid --- Dyes --- Microgravity --- Particle size --- Pesticides --- Silicon compounds --- Silk --- Silver --- Silver compounds --- Soaps --- Sodium --- Sodium compounds --- Soil --- Sol-gel processing --- Solar energy --- Solders --- Solvents --- Soybeans --- Spectroscopy --- Sprays --- Stains (coloring materials) --- Starches --- Steam --- Steel --- Steroids --- Stimulants (nervous systems) --- Strontium --- Strontium compounds --- Styrene-butadiene rubber --- Fungicides --- Furnaces --- Gallium --- Gallium compounds --- Gasoline --- Gelatins --- Gemstones --- Geothermal energy --- Germanium --- Germanium compounds --- Glycerol --- Glycols --- Gold --- Gold compounds --- Grignard reaction --- Gums --- Hafnium --- Hafnium compounds --- Hair preparations --- Hardness (mechanical) --- Heat resistant materials --- Heat stabilizers --- Metallic glasses --- Natural gas --- Safety --- Synthetic fuels --- Waters, natural --- 1,3-butadiene, 2-methyl --- Biocides --- Butanedioic acid, methylene --- -Catalysis --- Electric insulators --- Ethenone derivatives --- Hypoglycemic agents --- Imines --- Incinerators --- Inclusion compounds --- Indium --- Indium compounds --- Indole derivatives --- Industrial hygiene --- Inks --- Inorganic polymers --- Integrated circuits --- Iodine --- Iodine compounds --- Ion implantation --- Ionomers --- Iron --- Isocyanates --- Plastics, laminated --- Reaction kinetics --- Sound insulators --- Thermal insulators --- 2-butenedioic acid (z) --- Brown coal --- Esr (electron spin resonance) --- Latex --- Leather --- Lecithins --- Lignins --- Lime --- Limestone --- Liquefied petroleum gases --- Liquid crystals --- Lithium --- Lithium compounds --- Lubricants --- Lubrication --- Luminescent materials --- Machining --- Magnesium --- Magnesium compounds --- Magnetic substances --- Magnetohydrodynamics --- Malt --- Manganese --- Propanedioic acid --- 1,2,3-propanetricarboxylic acid, 2-hydroxy --- -2-propenoic acid, 3-phenyl --- Chloro hydrocarbons --- Chlorosulfuric acid --- Chocolate --- Choline --- Chromatography --- Chromium --- Chromium compounds --- Chromophores --- Cobalt --- Cobalt compounds --- Coffee (beverage) --- Color --- Coloring materials --- Hydroxy compounds --- Phenols --- Photography --- 2h-1-benzopyran-2-one --- Antifoaming agents --- Benzene, 1-methylethyl --- Contact lenses --- Contraceptive agents --- Controlled-release drug delivery systems --- Coordination compounds --- Copper --- Copper compounds --- Corrosion --- Cotton fibers --- Cryogenics --- Crystallization --- Cyanamide derivatives --- Cyanides (inorganic) --- Cyanine dyes --- Cyanohydrins --- Cyanuric acid --- Cyclohexane derivatives --- Cyclopentadiene --- Dairy products --- Dental materials --- Detergency --- Drying agents --- Laboratory experiment --- Nitriles --- 2-propanone --- 2-propenal --- Ablative materials --- Abrasives --- Absorption --- Acetic acid --- Acrylic polymers --- Adhesives --- Aeration --- Air conditioning --- Alcohols --- Aldehydes --- Alkali metal hydroxides --- Alkaloids --- Ethyne derivatives --- Hexanedioic acid --- Polyoxymethylenes --- Adrenal cortex hormones --- Aerogels --- Benzene, dimethyl --- Biopolymers --- Bioremediation --- Chirality --- Condensation (physical) --- Furans --- Microemulsions --- Molecular modeling --- Molecular recognition --- Photoresists --- Purity --- Recycling of polymeric materials --- Semiconductor compounds --- Separation --- Surface analysis --- Thermography --- Urea --- Water-soluble polymers --- Weighing --- Welding --- Wine --- Wood --- ANTIBIOTICS --- ANTI-OBESITY AGENTS --- ANTIFREEZE --- ANTIMONY --- ANTIMONY COMPOUNDS --- ANTIOXIDANTS --- ANTIOZONANTS --- PARASITICIDES --- ANTISTATIC AGENTS --- VIRUCIDES --- AQUACULTURE --- ARSENIC --- ARSENIC COMPOUNDS --- ASBESTOS --- ASPHALT --- AIR POLLUTION --- INSTRUMENTATION --- JET AIRCRAFT FUEL --- DYES --- BAKERY PRODUCTS --- BARIUM --- BARIUM COMPOUNDS --- POLYMERS --- PERMEABILITY --- FUEL CELLS --- PROPERTIES --- 9,10-anthracenedione --- Alcohols, compounds, metal salts --- Alkyd resins --- Alkylation --- Allylic compounds --- Aluminum --- Aluminum compounds --- Amides --- Amines --- Amino acids --- Amino alcohols --- Aminoplasts --- Ammonia --- Ammonium compounds --- Analgesics --- Analytical chemistry --- Anesthetics --- Antibacterial agents --- Antibiotics --- Bronchodilator agents --- Senescence --- POWER --- PRESSURE --- PRINTING --- PROCESS CONTROL AND DYNAMICS --- ENERGY CONSERVATION --- PRODUCT LIABILITY --- 1-PROPANOL --- 2-PROPANOL --- OXIRANE, METHYL --- PROSTAGLANDINS --- PROSTHETIC DEVICES --- PROTEINS --- PSYCHOTROPIC DRUGS --- PULP (CELLULOSE) --- PUMPS --- PYRAZOLE DERIVATIVES --- PYRIDINE DERIVATIVES --- PYROTECHNIC COMPOSITIONS --- PYRROLE DERIVATIVES --- QUALITY CONTROL --- QUATERNARY AMMONIUM COMPOUNDS --- QUINOLINE DERIVATIVES --- QUINONES --- CROSSLINKING AGENTS --- RADIATION --- ISOTOPE INDICATORS --- RADIOELEMENTS --- RADIOGRAPHY, CONTRAST AGENTS --- PHARMACEUTICALS, RADIO --- RADIOPROTECTANTS --- REACTORS --- COATINGS --- RECYCLING --- CHEMICAL AND PHYSICAL EFFECTS --- MATCHES --- MATERIALS --- STANDARDS --- MEAT PRODUCTS --- DIAGNOSIS --- DIAGNOSTIC IMAGING --- MEMBRANES --- MEMORY, BIOLOGICAL --- MERCURY --- MERCURY COMPOUNDS --- ANODES --- METALS --- METALLURGY --- COMPOSITES --- SURFACE (CHEMISTRY AND PHYSICS) --- 2-PROPENOIC ACID, 2-METHYL --- METHANOL --- MICA-GROUP MINERALS --- POLYSACCHARIDES, BACTERIAL --- METABOLISM (MICROBIAL) --- MICROENCAPSULATION --- MICROSCOPY --- MICROWAVE --- MILK --- DAIRY PRODUCTS --- MINERAL ELEMENTS --- NUTRIENTS --- MINERALS --- MIXING --- MOLECULAR SIEVES --- MOLYBDENUM --- MOLYBDENUM COMPOUNDS --- NAPHTHALENE DERIVATIVES --- NAPHTHENIC ACIDS --- NEUROHORMONES --- NEUROTRANSMITTER AGONISTS --- NEUROTRANSMITTER ANTAGONISTS --- PREPARATION --- 1,2-benzenedicarboxylic acid --- Carbonic dichloride --- Disperse systems --- Paper --- Perchloric acid --- Perfumes --- Peroxides --- Pharmaceutical preparations --- Phenolic resins --- Phosphates --- Phosphine derivatives --- Phosphoric acid --- Phosphorus --- Phosphorus compounds --- Photochemistry --- Photoconductivity --- Photoelectric devices --- Phthalocyanine compounds --- Pigments --- THIOGLYCOLIC ACID --- THIOLS --- THIOPHENE DERIVATIVES --- THIOSULFATES --- THORIUM --- THORIUM COMPOUNDS --- THYROID GLAND --- THYROID HORMONES --- TIN --- TIN ALLOYS --- TIN COMPOUNDS --- TIRES --- TITANIUM --- TITANIUM ALLOYS --- TITANIUM COMPOUNDS --- TOLUENE --- TOXICOLOGY --- TRACE ELEMENTS --- TRANSPORTATION --- TUNGSTEN --- TUNGSTEN ALLOYS --- TUNGSTEN COMPOUNDS --- ULTRAFILTRATION --- UNITS OF MEASUREMENT --- URANIUM --- URANIUM COMPOUNDS --- THALLIUM COMPOUNDS --- POLYURETHANES --- VACCINES --- VACUUM --- VANADIUM --- VANADIUM ALLOYS --- VANADIUM COMPOUNDS --- VANILLIN --- VETERINARY MEDICINE --- VINEGAR --- VINYL COMPOUNDS --- VINYL POLYMERS --- ANALYSIS --- 1,1'-biphenyl, deriv --- Alcoholic beverages --- Alkadienes --- Aromatic hydrocarbons --- Bearings --- Beer --- Benzene --- Beryllium --- Biotechnology --- Bismuth --- Bleaching agents --- Blood --- Boron --- Bromine --- Cadmium --- Calcium --- Carbides --- Carbon --- Construction materials --- Friction materials --- Alditols --- Films (physical chemistry) --- S-substitution --- Sulfamic acid --- Sulfolane --- Sulfonation --- Sulfonic acids --- Sulfoxides --- Sulfur --- Sulfur compounds --- Sulfuric acid --- Supercritical fluids --- Surfactants --- Sutures --- Sweetening agents --- Talc --- Tall oil --- Tanks (containers) --- Tantalum --- Tantalum compounds --- Tar --- Tea --- Tellurium --- Tellurium compounds --- Temperature sensors --- Terpenes --- Textiles --- Thallium --- Thallium compounds --- Thermodynamics --- Thermoelectricity --- Anemometers --- Blood chemical analysis --- Flavoring agents --- Flocculating agents --- Fluorescent brighteners --- Foams --- Formaldehyde --- Formic acid --- Fractionation --- Fracture (materials) --- Friedel-crafts reaction --- Fruit and vegetable juices --- Plastics, cellular --- Viscosimeters