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Book
Layered double hydroxide polymer nanocomposites
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ISBN: 0081022611 9780081022610 Year: 2019 Publisher: Oxford : Woodhead Publishing,


Book
Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production
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ISBN: 3319412752 3319412760 Year: 2016 Publisher: Cham : Springer International Publishing : Imprint: Springer,

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This thesis presents a combination of material synthesis and characterization with process modeling. In it, the CO2 adsorption properties of hydrotalcites are enhanced through the production of novel supported hybrids (carbon nanotubes and graphene oxide) and the promotion with alkali metals. Hydrogen is regarded as a sustainable energy carrier, since the end users produce no carbon emissions. However, given that most of the hydrogen produced worldwide comes from fossil fuels, its potential as a carbon-free alternative depends on the ability to capture the carbon dioxide released during manufacture. Sorption-enhanced hydrogen production, in which CO2 is removed as it is formed, can make a major contribution to achieving this. The challenge is to find solid adsorbents with sufficient CO2 capacity that can work in the right temperature window over repeated adsorption-desorption cycles. The book presents a highly detailed characterization of the materials, together with an accurate measurement of their adsorption properties under dry conditions and in the presence of steam. It demonstrates that even small quantities of graphene oxide provide superior thermal stability to hydrotalcites due to their compatible layered structure, making them well suited as volume-efficient adsorbents for CO2. Lastly, it identifies suitable catalysts for the overall sorption-enhanced water gas shift process.


Book
Application and Behavior of Nanomaterials in Water Treatment
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ISBN: 3039211722 3039211714 Year: 2019 Publisher: MDPI - Multidisciplinary Digital Publishing Institute

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The book compiles scientific articles describing advances in nanomaterial synthesis and their application in water remediation. The publications treat diverse problems such as dye degradation, heavy metal ion, as well as radioactive element capture and sequestration. There are 10 original research articles and one review article. The latter proposes graphene/CNT and Prussian blue nanocomposites for radioactive 137-cesium extraction from aqueous media. All reports thoroughly characterize the nanomaterials post-synthesis and describe their catalytic, photocatalytic, or ion exchange activities in contaminated water. The dyes studied in the collection are azo dyes, i.e. methylene blue and orange, rhodamine B, phenolic dyes viz. bromophenol blue, and other dyes with sulfonyl groups. Extraction of radioactive elements, including cationic 137Cs+ and anionic 125I?, is also investigated. The omnipresence of ZnO nanoparticles in everyday products and their effects in wastewater are also evaluated. Layered double hydroxide are capable of capturing Ag ions, which then has a catalytic effect on dye degradation. The nanomaterials considered are varied, viz., graphene, CNT, Prussian blue, nanoporous carbon, layered double hydroxides, magnetite, ferrites, organic powders, polymer membranes, bacteria, and inorganic nanomaterials such as MnO and Ag. The book targets an interdisciplinary readership.


Book
Layered Double Hydroxides (LDHs)
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Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Layered Double Hydroxides (LDHs) certainly do not represent a newcomer to the scientific community, yet they continue to attract a strong and general interest among a vast and multifaceted range of researchers. This persistent modernity is definitely due to some peculiar characteristics of these materials, which allow researchers and engineers to play with different aspects of two worlds: organic and inorganic, crystalline and molecular, solid and liquid, cationic and anionic. A virtually infinite number of possible chemical combinations takes advantage of their layered structure to express an unrivaled collection of remarkable properties. The capture and/or release of organic and inorganic species, versatile low-cost catalytic activity, and blending with other compounds to build up a variety of hybrid composites, are just some of the many effects investigated to date. As a result, the applications encompass almost all aspects of our life, ranging from renewable energy production to water purification, including biomedical applications, gas sensing, drug delivery, and food packaging and safety. This Special Issue highlights some of the recent research lines, and shows that remarkable progress has been and is still being made in all these aspects, to allow the consideration of LDHs as one of the most interesting and versatile inorganic materials.


Book
Layered Double Hydroxide-Based Catalytic Materials for Sustainable Processes
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Year: 2022 Publisher: Basel MDPI Books

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Layered double hydroxides (LDHs), also known as two-dimensional anionic clays, as well as the derived materials, including hybrids, nanocomposites, mixed oxides, and supported metals, have been highlighted as outstanding heterogeneous catalysts with unlimited applications in various processes involving both acid–base (addition, alkylation, acylation, decarboxylation, etc.) and redox (oxidation, reduction, dehydrogenation, etc.) mechanisms. This is mainly due to their flexibility in chemical composition, allowing the fine tuning of the nature of the active sites and the control of the balance between them. Additionally, LDHs display a large anion exchange capacity and the possibility to modify their interlayer space, constraining the size and type of reactants entering in the interlamellar space. Furthermore, their easy and economic synthesis, with high levels of purity and efficiency, at both the laboratory and industrial scales, make LDHs and their derived materials excellent solid catalysts. This Special Issue collects original research papers, reviews, and commentaries focused on the catalytic applications of these remarkable materials.


Book
Layered Double Hydroxide-Based Catalytic Materials for Sustainable Processes
Authors: ---
Year: 2022 Publisher: Basel MDPI Books

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Layered double hydroxides (LDHs), also known as two-dimensional anionic clays, as well as the derived materials, including hybrids, nanocomposites, mixed oxides, and supported metals, have been highlighted as outstanding heterogeneous catalysts with unlimited applications in various processes involving both acid–base (addition, alkylation, acylation, decarboxylation, etc.) and redox (oxidation, reduction, dehydrogenation, etc.) mechanisms. This is mainly due to their flexibility in chemical composition, allowing the fine tuning of the nature of the active sites and the control of the balance between them. Additionally, LDHs display a large anion exchange capacity and the possibility to modify their interlayer space, constraining the size and type of reactants entering in the interlamellar space. Furthermore, their easy and economic synthesis, with high levels of purity and efficiency, at both the laboratory and industrial scales, make LDHs and their derived materials excellent solid catalysts. This Special Issue collects original research papers, reviews, and commentaries focused on the catalytic applications of these remarkable materials.


Book
Layered Double Hydroxides (LDHs)
Authors: ---
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Layered Double Hydroxides (LDHs) certainly do not represent a newcomer to the scientific community, yet they continue to attract a strong and general interest among a vast and multifaceted range of researchers. This persistent modernity is definitely due to some peculiar characteristics of these materials, which allow researchers and engineers to play with different aspects of two worlds: organic and inorganic, crystalline and molecular, solid and liquid, cationic and anionic. A virtually infinite number of possible chemical combinations takes advantage of their layered structure to express an unrivaled collection of remarkable properties. The capture and/or release of organic and inorganic species, versatile low-cost catalytic activity, and blending with other compounds to build up a variety of hybrid composites, are just some of the many effects investigated to date. As a result, the applications encompass almost all aspects of our life, ranging from renewable energy production to water purification, including biomedical applications, gas sensing, drug delivery, and food packaging and safety. This Special Issue highlights some of the recent research lines, and shows that remarkable progress has been and is still being made in all these aspects, to allow the consideration of LDHs as one of the most interesting and versatile inorganic materials.


Book
Layered Double Hydroxide-Based Catalytic Materials for Sustainable Processes
Authors: ---
Year: 2022 Publisher: Basel MDPI Books

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Abstract

Layered double hydroxides (LDHs), also known as two-dimensional anionic clays, as well as the derived materials, including hybrids, nanocomposites, mixed oxides, and supported metals, have been highlighted as outstanding heterogeneous catalysts with unlimited applications in various processes involving both acid–base (addition, alkylation, acylation, decarboxylation, etc.) and redox (oxidation, reduction, dehydrogenation, etc.) mechanisms. This is mainly due to their flexibility in chemical composition, allowing the fine tuning of the nature of the active sites and the control of the balance between them. Additionally, LDHs display a large anion exchange capacity and the possibility to modify their interlayer space, constraining the size and type of reactants entering in the interlamellar space. Furthermore, their easy and economic synthesis, with high levels of purity and efficiency, at both the laboratory and industrial scales, make LDHs and their derived materials excellent solid catalysts. This Special Issue collects original research papers, reviews, and commentaries focused on the catalytic applications of these remarkable materials.

Keywords

Research & information: general --- Chemistry --- layered double hydroxides (LDH) --- polyoxometalates (POM) --- catalytic materials --- Michael addition --- cobalt-based LDHs --- ultrasonic irradiation --- synergistic effect --- photocatalysis --- nitrophenol degradation --- Zn,Al-hydrotalcite --- ZnO dispersed on alumina --- reusability --- layered double hydroxide --- LDH --- catalytic oxidation --- ethanol --- toluene --- VOC --- photocatalysts --- Cu electrodes --- diazo dyes --- electrocatalysts --- layer double hydroxides --- photoelectrochemical degradation --- hydrotalcites --- mixed oxides --- aldol condensation --- basic catalysts --- exfoliation --- nanosheets --- oxidation --- layered double hydroxides --- base catalysts --- epoxide --- formaldehyde --- oxidation removal --- BiOCl --- manganese --- biodiesel --- transesterification --- hydrothermal --- nickel --- aluminum --- solid base --- structured catalyst --- ethanol steam reforming --- aluminum lathe waste strips --- Ni nanoparticle --- mechano-chemical/co-precipitation synthesis --- organic alkalis (tetramethylammonium hydroxide) --- memory effect --- Claisen-Schmidt condensation --- self-cyclohexanone condensation --- layered double hydroxides (LDH) --- polyoxometalates (POM) --- catalytic materials --- Michael addition --- cobalt-based LDHs --- ultrasonic irradiation --- synergistic effect --- photocatalysis --- nitrophenol degradation --- Zn,Al-hydrotalcite --- ZnO dispersed on alumina --- reusability --- layered double hydroxide --- LDH --- catalytic oxidation --- ethanol --- toluene --- VOC --- photocatalysts --- Cu electrodes --- diazo dyes --- electrocatalysts --- layer double hydroxides --- photoelectrochemical degradation --- hydrotalcites --- mixed oxides --- aldol condensation --- basic catalysts --- exfoliation --- nanosheets --- oxidation --- layered double hydroxides --- base catalysts --- epoxide --- formaldehyde --- oxidation removal --- BiOCl --- manganese --- biodiesel --- transesterification --- hydrothermal --- nickel --- aluminum --- solid base --- structured catalyst --- ethanol steam reforming --- aluminum lathe waste strips --- Ni nanoparticle --- mechano-chemical/co-precipitation synthesis --- organic alkalis (tetramethylammonium hydroxide) --- memory effect --- Claisen-Schmidt condensation --- self-cyclohexanone condensation


Book
Layered Double Hydroxides (LDHs)
Authors: ---
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

Loading...
Export citation

Choose an application

Bookmark

Abstract

Layered Double Hydroxides (LDHs) certainly do not represent a newcomer to the scientific community, yet they continue to attract a strong and general interest among a vast and multifaceted range of researchers. This persistent modernity is definitely due to some peculiar characteristics of these materials, which allow researchers and engineers to play with different aspects of two worlds: organic and inorganic, crystalline and molecular, solid and liquid, cationic and anionic. A virtually infinite number of possible chemical combinations takes advantage of their layered structure to express an unrivaled collection of remarkable properties. The capture and/or release of organic and inorganic species, versatile low-cost catalytic activity, and blending with other compounds to build up a variety of hybrid composites, are just some of the many effects investigated to date. As a result, the applications encompass almost all aspects of our life, ranging from renewable energy production to water purification, including biomedical applications, gas sensing, drug delivery, and food packaging and safety. This Special Issue highlights some of the recent research lines, and shows that remarkable progress has been and is still being made in all these aspects, to allow the consideration of LDHs as one of the most interesting and versatile inorganic materials.

Keywords

Research & information: general --- layered double hydroxides --- reconstruction --- curcumin --- drug release --- wastewater --- heavy metals removal --- sol-gel processing --- alkaline earth metals --- mixed metal oxides --- reconstruction effect --- surface properties --- nanocomposites --- nanofillers --- thermal stability --- flammability --- polymer matrix --- HC --- hydrothermal synthesis --- layered double hydroxide --- AFm phase --- calcium hemicarboaluminate --- cement phases --- cement hydration --- C3AH6 --- C4ACH11 --- katoite --- microwave-assisted organic synthesis --- biofuel production --- rehydrated hydrotalcite --- heterogeneous basic catalysis --- green chemistry --- mechanochemistry --- bead mill --- synthesis --- wet grinding --- layered double hydroxides (LDHs) --- other nanoclays --- organically modified LDH --- water purification --- adsorption --- adsorption interaction --- diffusion --- layered double hydroxides --- reconstruction --- curcumin --- drug release --- wastewater --- heavy metals removal --- sol-gel processing --- alkaline earth metals --- mixed metal oxides --- reconstruction effect --- surface properties --- nanocomposites --- nanofillers --- thermal stability --- flammability --- polymer matrix --- HC --- hydrothermal synthesis --- layered double hydroxide --- AFm phase --- calcium hemicarboaluminate --- cement phases --- cement hydration --- C3AH6 --- C4ACH11 --- katoite --- microwave-assisted organic synthesis --- biofuel production --- rehydrated hydrotalcite --- heterogeneous basic catalysis --- green chemistry --- mechanochemistry --- bead mill --- synthesis --- wet grinding --- layered double hydroxides (LDHs) --- other nanoclays --- organically modified LDH --- water purification --- adsorption --- adsorption interaction --- diffusion

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