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Ammonia. --- Iron catalysts.

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Ammonia. --- Iron catalysts. --- Ammoniac. --- Catalyseurs au fer.

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Coal liquefaction --- Coal gasification --- Iron catalysts --- Fischer-Tropsch process. --- Coal liquefaction --- Coal gasification --- Catalyseurs au fer

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Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive, and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium, and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.

Iron catalysts. --- Aromatic compounds --- Synthesis. --- Catalysts --- Chemistry, Organic. --- Materials. --- Organometallic Chemistry. --- Metallic Materials. --- Engineering --- Engineering materials --- Industrial materials --- Engineering design --- Manufacturing processes --- Organic chemistry --- Chemistry --- Materials --- Organometallic chemistry . --- Metals. --- Metallic elements --- Chemical elements --- Ores --- Metallurgy --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic

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This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million. .

Chemistry. --- Organometallic chemistry. --- Chemical engineering. --- Catalysis. --- Organometallic Chemistry. --- Industrial Chemistry/Chemical Engineering. --- Alkenes. --- Iron catalysts. --- Alkynes. --- Alkines --- Ethene series --- Ethylene series --- Olefines --- Olefins --- Hydrocarbons --- Catalysts --- Chemistry, Organic. --- Chemistry, Industrial --- Engineering, Chemical --- Industrial chemistry --- Engineering --- Chemistry, Technical --- Metallurgy --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Organic chemistry --- Chemistry --- Organometallic chemistry . --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic