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The main objective of polymer materials scientists is to develop and design high performance polymer-based materials via the introduction of block copolymers, ionomers or inorganic-organic hybrids, in order to introduce functionalities such as mechanical reinforcement, gas barrier properties, fire retardancy, shape memory behavior or self-healing ability. In the last ten years, ionic liquids have demonstrated huge potential as new components within polymer-based materials, leading to a wide range of applications. Due to their many physical-chemical properties, as well as their various possible combinations, ionic liquids represent a new path to produce multifunctional materials.
History of engineering & technology --- ionic liquids --- thermosets --- Lithium salts --- electrolytes --- polyoxymethylene --- ionic liquid --- crystallization behavior --- nucleation --- polymerizable ionic liquid microemulsions --- poly(ionic liquid)s --- adsorption --- poly(ionic liquid) --- cross-linker --- electrochemical detection --- 4-nonylphenol --- poly (butylene adipate-co-terephthalate) --- layered double hydroxide --- in-situ polymerization --- nanocomposite --- permeability --- biodegradable polymer --- IR spectroscopy --- silica --- high pressure --- microwave --- synthetic methods --- nanomaterials --- polymers --- humidity sensing --- free-ion concentration --- fast response and recovery --- respiratory rate monitoring --- PMMA --- plasticizer --- mechanical behavior --- crazing --- thermal behavior
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The main objective of polymer materials scientists is to develop and design high performance polymer-based materials via the introduction of block copolymers, ionomers or inorganic-organic hybrids, in order to introduce functionalities such as mechanical reinforcement, gas barrier properties, fire retardancy, shape memory behavior or self-healing ability. In the last ten years, ionic liquids have demonstrated huge potential as new components within polymer-based materials, leading to a wide range of applications. Due to their many physical-chemical properties, as well as their various possible combinations, ionic liquids represent a new path to produce multifunctional materials.
ionic liquids --- thermosets --- Lithium salts --- electrolytes --- polyoxymethylene --- ionic liquid --- crystallization behavior --- nucleation --- polymerizable ionic liquid microemulsions --- poly(ionic liquid)s --- adsorption --- poly(ionic liquid) --- cross-linker --- electrochemical detection --- 4-nonylphenol --- poly (butylene adipate-co-terephthalate) --- layered double hydroxide --- in-situ polymerization --- nanocomposite --- permeability --- biodegradable polymer --- IR spectroscopy --- silica --- high pressure --- microwave --- synthetic methods --- nanomaterials --- polymers --- humidity sensing --- free-ion concentration --- fast response and recovery --- respiratory rate monitoring --- PMMA --- plasticizer --- mechanical behavior --- crazing --- thermal behavior
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The main objective of polymer materials scientists is to develop and design high performance polymer-based materials via the introduction of block copolymers, ionomers or inorganic-organic hybrids, in order to introduce functionalities such as mechanical reinforcement, gas barrier properties, fire retardancy, shape memory behavior or self-healing ability. In the last ten years, ionic liquids have demonstrated huge potential as new components within polymer-based materials, leading to a wide range of applications. Due to their many physical-chemical properties, as well as their various possible combinations, ionic liquids represent a new path to produce multifunctional materials.
History of engineering & technology --- ionic liquids --- thermosets --- Lithium salts --- electrolytes --- polyoxymethylene --- ionic liquid --- crystallization behavior --- nucleation --- polymerizable ionic liquid microemulsions --- poly(ionic liquid)s --- adsorption --- poly(ionic liquid) --- cross-linker --- electrochemical detection --- 4-nonylphenol --- poly (butylene adipate-co-terephthalate) --- layered double hydroxide --- in-situ polymerization --- nanocomposite --- permeability --- biodegradable polymer --- IR spectroscopy --- silica --- high pressure --- microwave --- synthetic methods --- nanomaterials --- polymers --- humidity sensing --- free-ion concentration --- fast response and recovery --- respiratory rate monitoring --- PMMA --- plasticizer --- mechanical behavior --- crazing --- thermal behavior
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In this book we have collected a series of state-of-the art papers written by specialists in the field of ionic liquid crystals (ILCs) to address key questions concerning the synthesis, properties, and applications of ILCs. New compounds exhibiting ionic liquid crystalline phases are presented, both of calamitic as well as discotic type. Their dynamic and structural properties have been investigated with a series of experimental techniques including differential scanning calorimetry, polarized optical spectroscopy, X-ray scattering, and nuclear magnetic resonance, impedance spectroscopy to mention but a few. Moreover, computer simulations using both fully atomistic and highly coarse-grained force fields have been presented, offering an invaluable microscopic view of the structure and dynamics of these fascinating materials.
photoconductivity --- n/a --- thermotropic --- X-ray diffraction --- mesophases --- crystal polymorphs --- columnar --- viologens --- alignment layer --- crown ether --- imidazolium --- electron transport --- metathesis reaction --- polarizing optical microscopy --- liquid crystals --- Ag nano-particles doping --- discotic --- molecular orientational order --- thermogravimetric analysis --- ion transport --- molecular dynamics --- nuclear magnetic resonance --- smectic phase A --- ion channels --- ionic liquid --- ionic liquid crystal --- phase behavior --- impedance spectroscopy --- residual DC --- differential scanning calorimetry --- 4-n-alkylbenzenesulfonic acids --- ionic liquid crystals --- ionic liquids --- thiazolium --- liquid crystal --- salt effect
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Due to their distinctive properties, ionic liquids have attracted the great and unflagging interest of researchers for over 30 years. This interest has been focused mainly on their use as a green alternative to volatile organic solvents. However, they often act not only as solvents but also as catalysts, catalyst immobilizers and initiators. Over 100 types of chemical reactions are known in which ionic liquids (ILs) were applied successfully. This Special Issue is aimed at showing the most recent advances and trends in the design, synthesis and characterization of catalysts based on ILs, as well as presenting their activity and application potential.
Technology: general issues --- oxidation --- N-hydroxyphthalimide --- immobilization --- ionic liquids --- SCILL --- plasticizers --- acidic catalysis --- terephthalate esters --- ortho-phthalate esters --- esterification --- solvents --- hydrosilylation --- alkynes --- heterogeneous catalysis --- rhodium catalysts --- cellulose --- deep eutectic solvents --- 5-HMF --- biphasic system --- homogeneous catalysis --- supercritical CO2 --- borylative coupling --- catalyst recycling --- green chemistry --- ruthenium catalyst --- vinyl boronates --- organoboron compounds --- biomass --- microwaves --- Michael reaction --- chalcone --- dimethylmalonate --- biphasic catalysis --- platinum complexes --- acidic ionic liquid --- Eucalyptus wood --- furfural --- levulinic acid --- supported ionic liquid catalyst (SILCA) --- palladium --- Heck reaction --- catalyst screening --- optimization --- hydrothermal liquefaction of cellulose --- cellulose recovery and bleaching --- paper industry sludge --- municipal primary sludge --- value-added chemicals --- ionic liquid --- heterogeneous catalyst --- SILPC --- porous ionic liquids --- supported ionic liquid phase --- n/a
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Due to their distinctive properties, ionic liquids have attracted the great and unflagging interest of researchers for over 30 years. This interest has been focused mainly on their use as a green alternative to volatile organic solvents. However, they often act not only as solvents but also as catalysts, catalyst immobilizers and initiators. Over 100 types of chemical reactions are known in which ionic liquids (ILs) were applied successfully. This Special Issue is aimed at showing the most recent advances and trends in the design, synthesis and characterization of catalysts based on ILs, as well as presenting their activity and application potential.
oxidation --- N-hydroxyphthalimide --- immobilization --- ionic liquids --- SCILL --- plasticizers --- acidic catalysis --- terephthalate esters --- ortho-phthalate esters --- esterification --- solvents --- hydrosilylation --- alkynes --- heterogeneous catalysis --- rhodium catalysts --- cellulose --- deep eutectic solvents --- 5-HMF --- biphasic system --- homogeneous catalysis --- supercritical CO2 --- borylative coupling --- catalyst recycling --- green chemistry --- ruthenium catalyst --- vinyl boronates --- organoboron compounds --- biomass --- microwaves --- Michael reaction --- chalcone --- dimethylmalonate --- biphasic catalysis --- platinum complexes --- acidic ionic liquid --- Eucalyptus wood --- furfural --- levulinic acid --- supported ionic liquid catalyst (SILCA) --- palladium --- Heck reaction --- catalyst screening --- optimization --- hydrothermal liquefaction of cellulose --- cellulose recovery and bleaching --- paper industry sludge --- municipal primary sludge --- value-added chemicals --- ionic liquid --- heterogeneous catalyst --- SILPC --- porous ionic liquids --- supported ionic liquid phase --- n/a
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Due to their distinctive properties, ionic liquids have attracted the great and unflagging interest of researchers for over 30 years. This interest has been focused mainly on their use as a green alternative to volatile organic solvents. However, they often act not only as solvents but also as catalysts, catalyst immobilizers and initiators. Over 100 types of chemical reactions are known in which ionic liquids (ILs) were applied successfully. This Special Issue is aimed at showing the most recent advances and trends in the design, synthesis and characterization of catalysts based on ILs, as well as presenting their activity and application potential.
Technology: general issues --- oxidation --- N-hydroxyphthalimide --- immobilization --- ionic liquids --- SCILL --- plasticizers --- acidic catalysis --- terephthalate esters --- ortho-phthalate esters --- esterification --- solvents --- hydrosilylation --- alkynes --- heterogeneous catalysis --- rhodium catalysts --- cellulose --- deep eutectic solvents --- 5-HMF --- biphasic system --- homogeneous catalysis --- supercritical CO2 --- borylative coupling --- catalyst recycling --- green chemistry --- ruthenium catalyst --- vinyl boronates --- organoboron compounds --- biomass --- microwaves --- Michael reaction --- chalcone --- dimethylmalonate --- biphasic catalysis --- platinum complexes --- acidic ionic liquid --- Eucalyptus wood --- furfural --- levulinic acid --- supported ionic liquid catalyst (SILCA) --- palladium --- Heck reaction --- catalyst screening --- optimization --- hydrothermal liquefaction of cellulose --- cellulose recovery and bleaching --- paper industry sludge --- municipal primary sludge --- value-added chemicals --- ionic liquid --- heterogeneous catalyst --- SILPC --- porous ionic liquids --- supported ionic liquid phase
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liquid electrolytes --- ionic melts --- ionic fluids --- fused salts --- liquid salts --- ionic glasses --- Ionic solutions --- Ionic Liquids --- Solutions ioniques --- Liquides ioniques. --- Ionic solutions. --- Solutions, Ionic --- Ions --- Solution (Chemistry) --- Ionic Liquid --- Liquid, Ionic --- Liquids, Ionic
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This Special Issue contains some recently experimental and theoretical advances in hydrogen evolution reaction, oxygen evolution reaction, and oxygen reduction reaction, and the applications in water splitting, proton exchange membrane fuel cells, and lithium-ion batteries.
Technology: general issues --- History of engineering & technology --- Materials science --- SnSe --- 2D materials --- hydrogen evolution --- water splitting --- DFT calculations --- defect engineering --- proton exchange membrane fuel cell --- high energy efficiency --- durability --- degradation --- Pt/C catalyst --- anode --- flexible electronics --- nanosheets --- SnO2 --- oxygen reduction reaction --- fluorination --- density functional theory --- non-noble metal catalyst --- N-doped carbon catalyst --- hydrogen evolution reaction --- porous carbon --- PtNi alloy --- platinum --- nanoparticles --- electrochemistry --- reduced graphite oxide --- microwave --- ionic liquid --- tunable aryl alkyl ionic liquid --- metal-organic frameworks (MOF) --- electrocatalysis --- oxygen evolution reaction (OER) --- nickel --- ketjenblack --- Sm0.5Sr0.5Co1−xNixO3−δ --- perovskite --- cathode electrocatalyst --- OER/ORR --- two-dimensional metal-organic framework --- ligand --- single-atom catalysts --- oxygen evolution reaction --- n/a
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This Special Issue contains some recently experimental and theoretical advances in hydrogen evolution reaction, oxygen evolution reaction, and oxygen reduction reaction, and the applications in water splitting, proton exchange membrane fuel cells, and lithium-ion batteries.
SnSe --- 2D materials --- hydrogen evolution --- water splitting --- DFT calculations --- defect engineering --- proton exchange membrane fuel cell --- high energy efficiency --- durability --- degradation --- Pt/C catalyst --- anode --- flexible electronics --- nanosheets --- SnO2 --- oxygen reduction reaction --- fluorination --- density functional theory --- non-noble metal catalyst --- N-doped carbon catalyst --- hydrogen evolution reaction --- porous carbon --- PtNi alloy --- platinum --- nanoparticles --- electrochemistry --- reduced graphite oxide --- microwave --- ionic liquid --- tunable aryl alkyl ionic liquid --- metal-organic frameworks (MOF) --- electrocatalysis --- oxygen evolution reaction (OER) --- nickel --- ketjenblack --- Sm0.5Sr0.5Co1−xNixO3−δ --- perovskite --- cathode electrocatalyst --- OER/ORR --- two-dimensional metal-organic framework --- ligand --- single-atom catalysts --- oxygen evolution reaction --- n/a
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