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Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the p
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This two-volume set presents exciting new developments in preparative heterocyclic chemistry with a special emphasis on the stereoselective synthesis of - or with the aid of - heterocycles. A wide range of modern methods and strategies for the construction and synthetic elaboration of versatile heterocycles is surveyed in depth by leading researchers in this field. Due to the high quality and up-to-date coverage of each chapter, this two-volume set provides a valuable overview of the different aspects discussed and will at the same time be highly inspiring for the expert synthetic organic chemist as well as the non-specialist reader.
Stereochemistry. --- Heterocyclic compounds --- Synthesis. --- Chemistry. --- Organic chemistry. --- Organic Chemistry. --- Organic chemistry --- Chemistry --- Heterocyclic compounds - Synthesis. --- HETEROCYCLIC COMPOUNDS --- DIELS-ALDER REACTION --- CYCLOADDITION REACTION --- PREPARATION
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Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the p
Heterocyclic compounds. --- Heterocyclic compounds - Synthesis. --- Heterocyclic compounds--Synthesis, Organopalladium compounds. --- Organopalladium compounds. --- Synthesis. --- Heterocyclic compounds --- Organopalladium compounds --- Inorganic Chemistry --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Synthesis --- Palladium organic compounds --- Organotransition metal compounds --- Palladium compounds --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Organic cyclic compounds --- Palladium catalysts.
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This volume presents exciting new developments in preparative heterocyclic chemistry with a special emphasis on the stereoselective synthesis of - or with the aid of - heterocycles. A wide range of modern methods and strategies for the construction and synthetic elaboration of versatile heterocycles is surveyed in depth by leading researchers in this field. Due to the high quality and up-to-date coverage of each chapter, this volume provides a valuable overview of the different aspects discussed and will at the same time be highly inspiring for the expert synthetic organic chemist as well as the non-specialist reader.
Heterocyclic compounds. --- Stereochemistry. --- Heterocyclic compounds --- Synthesis. --- Chemistry. --- Organic chemistry. --- Organic Chemistry. --- Organic chemistry --- Chemistry --- Heterocyclic compounds - Synthesis. --- HETEROCYCLIC COMPOUNDS --- RING OPENING --- NUCLEOPHILIC ADDITION REACTION --- CHIRAL SYNTHONS --- STEREOSELECTIVE SYNTHESIS (NATURAL PRODUCTS CHEMISTRY) --- PREPARATION
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For more than a century, heterocycles have played a crucial role in the biological and industrial development of society, becoming one of the most researched areas within organic chemistry. The first chapter of Microwave-Induced Synthesis of Aromatic Heterocycles is based on microwave theory, the latest developments in instrumentation technology, and the various microwave technologies used for synthesis. The remainder of the chapters are divided into two sections. Section A deals with the five-membered heterocycles (pyrazoles, isoxazoles, triazoles, oxadiazoles, thiazoles, imidazoles, oxazoles, oxazolines etc.) and in Section B, various six-membered heterocycles (triazines, benzoxazoles, benzimidazoles, benzothiazoles) are presented. Both sections contain a detailed, recent literature review of microwave assisted synthesis and its applicability to various aromatic heterocyclics.
Aromatic compounds -- Synthesis. --- Heterocyclic compounds -- Synthesis. --- Chemistry --- Physical Sciences & Mathematics --- Organic Chemistry --- Chemistry - General --- Heterocyclic compounds --- Microwaves. --- Synthesis. --- Hertzian waves --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Chemistry. --- Environmental chemistry. --- Chemistry/Food Science, general. --- Environmental Chemistry. --- Organic cyclic compounds --- Electric waves --- Electromagnetic waves --- Geomagnetic micropulsations --- Radio waves --- Shortwave radio --- Chemistry, Environmental --- Ecology --- Physical sciences
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This book is a volume in the series Topics in Heterocyclic Chemistry.Itc- ers the key methods used for designing synthetic approaches to heterocycles from carbohydrates and the value and scope of these methods. Carbohydrates are widely distributed in nature and constitute the largest part of renewable biomasses. Moreover, many carbohydrates and their derivatives are comm- cially available at relatively cheap prices. Consequently their utilization is highly encouraged and economically they are of great signi?cance. Moreover, carbohydrates are highly functionalized compounds that can be readily deri- tized and/or cyclized to provide heterocyclic compounds. This book provides a modern account and an up-to-date description of the advancement in the synthesis of diverse heterocycles from carbohydrates. Carbohydrates can be considered as a source of chiral centers in addition to the variable modi?cation thereof. Herein the elaboration of the carbohydrate molecules for providing different heterocycles is the main objective and team efforts from leaders of the topics has been gathered in this volume. This book is designed to be suitable for students and researchers. It is highly recommended as a reference book and for teaching the fascinating topics related to carbohydrates, heterocycles and organic synthesis. In addition to its importance in academia, it is also an excellent source for information about the variety of methods used in the synthesis of heterocycles important to industry.
Heterocyclic compounds --- Carbohydrates --- Glucides --- Synthesis --- Carbohydrates. --- Heterocyclic compounds -- Synthesis. --- Biochemistry --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Synthesis. --- Carbs (Carbohydrates) --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Chemistry. --- Organic chemistry. --- Medicinal chemistry. --- Organic Chemistry. --- Medicinal Chemistry. --- Chemistry, Medical and pharmaceutical --- Chemistry, Pharmaceutical --- Drug chemistry --- Drugs --- Medical chemistry --- Medicinal chemistry --- Pharmacochemistry --- Organic chemistry --- Physical sciences --- Biomolecules --- Organic compounds --- Glycomics --- Organic cyclic compounds --- Chemistry, Organic. --- Biochemistry. --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Biology --- Medical sciences --- Composition
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Find out how theoretical calculations are used to determine, elucidate and propose mechanisms for Pd-catalyzed C-C cross-coupling reactions in Max Garcia Melchor's outstanding thesis. Garcia Melchor investigates one of the most significant and useful types of reactions in modern organic synthesis; the Pd-cross coupling reaction. Due to its versatility, broad scope and selectivity under mild conditions, this type of reaction can now be applied in fields as diverse as the agrochemical and pharmaceutical industry. Garcia Melchor studies the reaction intermediates and transition states involved in the Negishi, the copper-free Sonogashira and the asymmetric version of Suzuki-Miyaura coupling. He also characterizes and provides a detailed picture of the associated reaction mechanisms. The author has won numerous prizes for this work which has led to over eight publications in internationally renowned journals.
Catalysts. --- Heterocyclic compounds -- Synthesis. --- Palladium catalysts. --- Chemistry --- Physical Sciences & Mathematics --- Inorganic Chemistry --- Physical & Theoretical Chemistry --- Organopalladium compounds. --- Organic reaction mechanisms. --- Mechanisms, Organic reaction --- Catalytic agents --- Palladium organic compounds --- Chemistry. --- Organic chemistry. --- Chemistry, Physical and theoretical. --- Catalysis. --- Theoretical and Computational Chemistry. --- Organic Chemistry. --- Reaction mechanisms (Chemistry) --- Catalysis --- Chemical inhibitors --- Organotransition metal compounds --- Palladium compounds --- Chemistry, Organic. --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Organic chemistry --- Physical sciences --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Organic compounds --- Synthesis.
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