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Energy crises and global warming pose serious challenges to researchers in their attempt to develop a sustainable society for the future. Solar energy conversion is a remarkable, clean, and sustainable way to nullify the effects of fossil fuels. The findings of photocatalytic hydrogen production (PCHP) by Fujishima and Honda propose that “water will be the coal for the future”. Hydrogen is a carbon-free clean fuel with a high specific energy of combustion. Titanium oxide (TiO2), graphitic-carbon nitride (g-C3N4) and cadmium sulfide (CdS) are three pillars of water splitting photocatalysts owing to their superior electronic and optical properties. Tremendous research efforts have been made in recent years to fabricate visible or solar-light, active photocatalysts. The significant features of various oxide, sulfide, and carbon based photocatalysts for cost-effective hydrogen production are presented in this Special Issue. The insights of sacrificial agents on the hydrogen production efficiency of catalysts are also presented in this issue.

Technology: general issues --- photocatalysis --- H2 generation --- water splitting --- solar energy --- hydrogen production --- methanol photo-splitting --- heterojunction --- CuS@CuGaS2 --- electron-hole recombination --- perovskite oxynitride --- band gap --- density-functional theory --- Niobium(V) oxide --- graphitic carbon nitride --- hydrothermal synthesis --- H2 evolution --- heterostructures --- Z-Scheme --- TiO2 --- g-C3N4 --- CdS --- energy --- spherical particle --- disordered surface --- photocatalysts --- MoS2 --- MoSe2 --- photoelectrochemical deposition --- rapid-thermal annealing --- hydrogen evolution --- CO2 reduction --- n/a

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Energy crises and global warming pose serious challenges to researchers in their attempt to develop a sustainable society for the future. Solar energy conversion is a remarkable, clean, and sustainable way to nullify the effects of fossil fuels. The findings of photocatalytic hydrogen production (PCHP) by Fujishima and Honda propose that “water will be the coal for the future”. Hydrogen is a carbon-free clean fuel with a high specific energy of combustion. Titanium oxide (TiO2), graphitic-carbon nitride (g-C3N4) and cadmium sulfide (CdS) are three pillars of water splitting photocatalysts owing to their superior electronic and optical properties. Tremendous research efforts have been made in recent years to fabricate visible or solar-light, active photocatalysts. The significant features of various oxide, sulfide, and carbon based photocatalysts for cost-effective hydrogen production are presented in this Special Issue. The insights of sacrificial agents on the hydrogen production efficiency of catalysts are also presented in this issue.

Technology: general issues --- photocatalysis --- H2 generation --- water splitting --- solar energy --- hydrogen production --- methanol photo-splitting --- heterojunction --- CuS@CuGaS2 --- electron-hole recombination --- perovskite oxynitride --- band gap --- density-functional theory --- Niobium(V) oxide --- graphitic carbon nitride --- hydrothermal synthesis --- H2 evolution --- heterostructures --- Z-Scheme --- TiO2 --- g-C3N4 --- CdS --- energy --- spherical particle --- disordered surface --- photocatalysts --- MoS2 --- MoSe2 --- photoelectrochemical deposition --- rapid-thermal annealing --- hydrogen evolution --- CO2 reduction --- photocatalysis --- H2 generation --- water splitting --- solar energy --- hydrogen production --- methanol photo-splitting --- heterojunction --- CuS@CuGaS2 --- electron-hole recombination --- perovskite oxynitride --- band gap --- density-functional theory --- Niobium(V) oxide --- graphitic carbon nitride --- hydrothermal synthesis --- H2 evolution --- heterostructures --- Z-Scheme --- TiO2 --- g-C3N4 --- CdS --- energy --- spherical particle --- disordered surface --- photocatalysts --- MoS2 --- MoSe2 --- photoelectrochemical deposition --- rapid-thermal annealing --- hydrogen evolution --- CO2 reduction

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Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC

in plasma-catalysis --- gas composition --- radiofrequency plasma --- calcium carbonate decomposition --- phenanthrene --- methane reforming --- dry reforming of methane --- NH3 decomposition --- dielectric barrier discharge --- gas temperature --- relative humidity --- CO selectivity --- isotope labelling --- nanocatalyst --- packed-bed dielectric barrier discharge --- Ga–In alloys --- mineralization --- rotating gliding arc plasma --- dielectric barrier discharge (DBD) --- catalyst --- plasmas-catalysis --- H2S oxidation --- post plasma-catalysis --- naphthalene --- VOC abatement --- nonstoichiometry --- zeolites --- H2 generation --- tar destruction --- adsorption-plasma catalysis --- NOx conversion --- catalyst preparation --- CeO2 --- nonequilibrium plasma --- non-thermal plasmas --- mode transition --- bimetal --- DBD plasma --- surface filament --- self-cooling --- indium --- plasma catalysis --- gallium --- perovskite catalysts --- ammonia synthesis --- packing materials --- air pollution --- toluene --- particle-in- cell/Monte Carlo collision method --- CO2 decomposition --- Manganese

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This reprint focuses on new trends in photo-electrocatalysis, specifically addressed to the remediation of wastewater and energy production. The remediation of wastewater, up to a level that is acceptable for discharge into receiving waterbodies, involves an ever-growing demand of energy, so effective and low-energy treatment processes are highly desirable. Among the other treatments, photo- and photo-electrochemical treatment processes may be considered as advanced oxidation processes (AOP), which are based on the generation of OH radicals, strong oxidizing agents able to indiscriminately degrade even the most persistent organic compounds. Photocatalysis and photo-electrocatalysis can be considered as effective methods for organic degradation, especially when the semiconductor is active in the range of visible light. Several results are presented on new morphologies and structures, which allow more photoactive, visibly responsive, and stable materials, as well as studies on combined processes in which photo- or photo-electrochemistry contribute to an increase in the sustainability of the whole process, lowering costs and achieving the most valuable final products. In view of the circular economy concept, microbial fuel cell systems are also considered as possible way to recover energy from organic pollutants contained in wastewater.

Research & information: general --- Biology, life sciences --- composite --- polymethylmethacrylate --- photocatalytic oxidation --- titanium dioxide --- tetracycline --- ethanol --- photocatalysis --- silver(II) oxide --- mechanical mixture --- in situ deposition --- hydrogen evolution --- Anodic oxidation --- diamond electrodes --- UV irradiation --- ultrasounds --- amoxicillin --- ampicillin --- Composite catalysts --- synergy effect --- solar energy --- wastewater remediation --- photoelectrocatalysis --- TiO2 nanostructures --- Au nanoparticles --- water splitting --- bisphenol A oxidation --- ZnFe2O4 --- degree of inversion --- cation distribution --- photoelectrochemical activity --- porous nickel --- selective corrosion --- hydrogen evolution reaction --- metal sulfides --- H2 production --- photocatalyst --- facet effect --- light trapping --- crystal size --- non-precious metal catalysts --- Cu–B alloy --- microbial fuel cell --- cathode --- environmental engineering --- oxygen electrode --- renewable energy sources --- graphitic carbon nitride --- H2 generation --- Ni–Co catalyst --- electricity production --- advanced oxidation processes --- azo dye --- sustainable resources --- niobium --- water reuse --- water treatment --- AOPs --- zinc oxide --- nanoclusters --- UVA --- visible light --- photocatalytic reduction --- CO2 --- TiO2 photocatalysts --- surface modification --- solar fuel --- magnetron sputtering --- titanium dioxide (TiO2) film --- photocatalytic activity --- metal and non-metal doping --- optical properties --- n/a --- Cu-B alloy --- Ni-Co catalyst

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This reprint focuses on new trends in photo-electrocatalysis, specifically addressed to the remediation of wastewater and energy production. The remediation of wastewater, up to a level that is acceptable for discharge into receiving waterbodies, involves an ever-growing demand of energy, so effective and low-energy treatment processes are highly desirable. Among the other treatments, photo- and photo-electrochemical treatment processes may be considered as advanced oxidation processes (AOP), which are based on the generation of OH radicals, strong oxidizing agents able to indiscriminately degrade even the most persistent organic compounds. Photocatalysis and photo-electrocatalysis can be considered as effective methods for organic degradation, especially when the semiconductor is active in the range of visible light. Several results are presented on new morphologies and structures, which allow more photoactive, visibly responsive, and stable materials, as well as studies on combined processes in which photo- or photo-electrochemistry contribute to an increase in the sustainability of the whole process, lowering costs and achieving the most valuable final products. In view of the circular economy concept, microbial fuel cell systems are also considered as possible way to recover energy from organic pollutants contained in wastewater.

Research & information: general --- Biology, life sciences --- composite --- polymethylmethacrylate --- photocatalytic oxidation --- titanium dioxide --- tetracycline --- ethanol --- photocatalysis --- silver(II) oxide --- mechanical mixture --- in situ deposition --- hydrogen evolution --- Anodic oxidation --- diamond electrodes --- UV irradiation --- ultrasounds --- amoxicillin --- ampicillin --- Composite catalysts --- synergy effect --- solar energy --- wastewater remediation --- photoelectrocatalysis --- TiO2 nanostructures --- Au nanoparticles --- water splitting --- bisphenol A oxidation --- ZnFe2O4 --- degree of inversion --- cation distribution --- photoelectrochemical activity --- porous nickel --- selective corrosion --- hydrogen evolution reaction --- metal sulfides --- H2 production --- photocatalyst --- facet effect --- light trapping --- crystal size --- non-precious metal catalysts --- Cu-B alloy --- microbial fuel cell --- cathode --- environmental engineering --- oxygen electrode --- renewable energy sources --- graphitic carbon nitride --- H2 generation --- Ni-Co catalyst --- electricity production --- advanced oxidation processes --- azo dye --- sustainable resources --- niobium --- water reuse --- water treatment --- AOPs --- zinc oxide --- nanoclusters --- UVA --- visible light --- photocatalytic reduction --- CO2 --- TiO2 photocatalysts --- surface modification --- solar fuel --- magnetron sputtering --- titanium dioxide (TiO2) film --- photocatalytic activity --- metal and non-metal doping --- optical properties --- composite --- polymethylmethacrylate --- photocatalytic oxidation --- titanium dioxide --- tetracycline --- ethanol --- photocatalysis --- silver(II) oxide --- mechanical mixture --- in situ deposition --- hydrogen evolution --- Anodic oxidation --- diamond electrodes --- UV irradiation --- ultrasounds --- amoxicillin --- ampicillin --- Composite catalysts --- synergy effect --- solar energy --- wastewater remediation --- photoelectrocatalysis --- TiO2 nanostructures --- Au nanoparticles --- water splitting --- bisphenol A oxidation --- ZnFe2O4 --- degree of inversion --- cation distribution --- photoelectrochemical activity --- porous nickel --- selective corrosion --- hydrogen evolution reaction --- metal sulfides --- H2 production --- photocatalyst --- facet effect --- light trapping --- crystal size --- non-precious metal catalysts --- Cu-B alloy --- microbial fuel cell --- cathode --- environmental engineering --- oxygen electrode --- renewable energy sources --- graphitic carbon nitride --- H2 generation --- Ni-Co catalyst --- electricity production --- advanced oxidation processes --- azo dye --- sustainable resources --- niobium --- water reuse --- water treatment --- AOPs --- zinc oxide --- nanoclusters --- UVA --- visible light --- photocatalytic reduction --- CO2 --- TiO2 photocatalysts --- surface modification --- solar fuel --- magnetron sputtering --- titanium dioxide (TiO2) film --- photocatalytic activity --- metal and non-metal doping --- optical properties