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Au Gold. Supplement volume B3. B3 : compounds with Si, P, As, Sb, Bi, the alkali metals and onium cations
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ISBN: 0387937196 3540937196 Year: 1995 Publisher: Berlin [etc.] : Springer-Verlag,

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Au Gold. Supplement volume B1. B1 : compounds with noble gases, H, O, N, F, and Cl
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ISBN: 0387936556 3540936556 Year: 1992 Publisher: Berlin [etc.] : Springer-Verlag,

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Au Gold. Supplement volume B2. B2 : compounds with Br, I, the Chalcogens (S,Se,Te,Po), B, and C
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ISBN: 0387936947 3540936947 Year: 1994 Publisher: Berlin [etc.] : Springer-Verlag,

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Article
The Physical Properties of the Metal Cluster Compound AU55(PPH3)12Cl6

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S.N. 62, Au organogold compounds.
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ISBN: 3540934154 0387934154 Year: 1980 Publisher: Berlin : Springer-Verlag,

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Book
In-vitro synthesis of gold nanoclusters in neurons
Authors: --- ---
Year: 2016 Publisher: Aberdeen Proving Ground, MD : US Army Research Laboratory,

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Inorganic Drugs in Deficiency and Disease
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ISBN: 0824715691 Year: 1982 Publisher: New York, NY ; Basel : Marcel Dekker,


Book
Gold catalysis
Author:
ISBN: 1848168535 1306942160 9781306942164 9781848168534 9781783265558 1783265558 9781848168527 1848168527 Year: 2014 Publisher: ICP

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Research on designing new catalytic systems has been one of the most important fields in modern organic chemistry, and one reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. This book presents the major advances in homogeneous catalysis, emphasizing the methodologies that create


Book
Synthesis and Original Reactivity of Copper and Gold Complexes : σ-Bond Coordination, Oxidative Addition, Migratory Insertion
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ISBN: 9783319186900 3319186892 9783319186894 3319186906 Year: 2015 Publisher: Cham : Springer International Publishing : Imprint: Springer,

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This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally characterized, yielding valuable insights into σ-bond activation processes for copper. Evidence for a highly unusual migratory syn insertion of unsaturated organic molecules into the gold-silicon bond of silylgold (I) complexes is provided and the corresponding mechanism identified. The intermolecular oxidative addition of σ-SiSi, σ-CC and σ-CX (X=halogen) bonds with molecular gold (I) complexes is studied in detail, effectively demonstrating that this reaction, usually considered to be impossible for gold, is actually highly favored, provided an adequate ligand is employed. The use of small-bite angle bis (phosphine) gold (I) complexes allows for the first time the oxidative addition of σ-CC and σ-CX bonds for gold (I). These results shed light on an unexpected reactivity pattern of gold complexes and may point the way to 2-electron redox transformations mediated by this metal, opening up new perspectives in gold catalysis.


Book
Gold(I,III) Complexes Designed for Selective Targeting and Inhibition of Zinc Finger Proteins
Author:
ISBN: 3030008533 3030008525 Year: 2018 Publisher: Cham : Springer International Publishing : Imprint: Springer,

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This book examines Au (I, III) complexes that selectively attack and inhibit zinc finger proteins (ZnFs) for potential therapeutic use. The author explores gold(I)-phosphine, gold(III) complexes with N^N and C^N donors as inhibitors of the HIV-1 nucleocapsid protein (NCp7), in comparison to the human transcription factor Sp1. To determine the coordination sphere of the gold adducts formed by interaction with ZnFs, two innovative approaches are used, based on Travelling-Wave Ion Mobility coupled with Mass Spectrometry (TWIM-MS), and X-ray Absorption Spectroscopy. Both approaches are proven to yield valuable structural information regarding the coordination sphere of gold in the adducts. In addition, the organometallic compound [Au (bnpy)Cl2] is evaluated. The system is shown to be capable of inhibiting ZnFs by means of C–S coupling.

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