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Book
Detection of Residual Pesticides in Foods
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Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Pesticides are used worldwide, and despite the fact that organic farming is increasing, they are still widely applied in different countries with pesticide regulations and monitoring programs. This Special Issue will cover the topic of the presence of pesticide residues in food, paying special attention to the use of modern analytical techniques based on chromatographic techniques coupled to mass spectrometry. Generic extraction methods are needed to allow the detection of pesticides with different physic-chemical properties, as well as different families of contaminants can be extracted simultaneously. Nevertheless, pluriresidue methods are still necessary for “orphan” compounds that cannot be included in multiresidue methods. Thus, in addition to targeted pesticides, the scope of this analysis can be increased and nowadays, metabolites are also detected, evaluating the degradation of pesticide residues in different food matrices.

Keywords

Public health & preventive medicine --- dispersive solid-liquid extraction --- sulfonylurea herbicides --- QuEChERS --- strawberry --- cleanup --- OCPs --- PCBs --- smoked pork meat products --- pancetta --- pork neck --- pork tenderloin --- sausage --- traditional and industrial smoking --- high polar pesticides --- UHPLC-Orbitrap-MS --- QuPPe --- pluri-residue analysis --- pesticide residues --- low-residue production --- zero-residue production --- half-lives --- pre-harvest interval --- lettuce --- onion --- leek --- carrot --- parsley --- phytohormones --- acidic herbicides --- fruits and vegetables --- multifamily method --- UHPLC-MS/MS --- residues in food --- pesticides --- LC-MS/MS --- GC-MS/MS --- honey --- persistent organic pollutants (POPs) --- glyphosate --- AMPA --- organic honey --- IC-HRMS --- food safety --- tea --- pyrethroid pesticide metabolite --- ultra-high performance liquid chromatography tandem mass spectrometry --- modified QuEChERS --- herbicide residues --- non-residual production --- low-residual production --- pesticide degradation in vegetables --- dispersive solid-liquid extraction --- sulfonylurea herbicides --- QuEChERS --- strawberry --- cleanup --- OCPs --- PCBs --- smoked pork meat products --- pancetta --- pork neck --- pork tenderloin --- sausage --- traditional and industrial smoking --- high polar pesticides --- UHPLC-Orbitrap-MS --- QuPPe --- pluri-residue analysis --- pesticide residues --- low-residue production --- zero-residue production --- half-lives --- pre-harvest interval --- lettuce --- onion --- leek --- carrot --- parsley --- phytohormones --- acidic herbicides --- fruits and vegetables --- multifamily method --- UHPLC-MS/MS --- residues in food --- pesticides --- LC-MS/MS --- GC-MS/MS --- honey --- persistent organic pollutants (POPs) --- glyphosate --- AMPA --- organic honey --- IC-HRMS --- food safety --- tea --- pyrethroid pesticide metabolite --- ultra-high performance liquid chromatography tandem mass spectrometry --- modified QuEChERS --- herbicide residues --- non-residual production --- low-residual production --- pesticide degradation in vegetables


Book
Monitoring of Honey Bee Colony Losses
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Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

In recent decades, independent national and international research programs have revealed possible reasons behind the death of managed honey bee colonies worldwide. Such losses are not due to a single factor, but instead are due to highly complex interactions between various internal and external influences, including pests, pathogens, honey bee stock diversity, and environmental changes. Reduced honey bee vitality and nutrition, exposure to agrochemicals, and the quality of colony management contribute to reduced colony survival in beekeeping operations. Our Special Issue (SI) on ‘’Monitoring of Honey Bee Colony Losses” aims to address the specific challenges that honey bee researchers and beekeepers face. This SI includes four reviews, with one being a meta-analysis that identifies gaps in the current and future directions for research into honey bee colonies’ mortalities. Other review articles include studies regarding the impact of numerous factors on honey bee mortality, including external abiotic factors (e.g., winter conditions and colony management) as well as biotic factors such as attacks by Vespa velutina and Varroa destructor.

Keywords

Technology: general issues --- Biotechnology --- Apis mellifera --- honey bee colony losses --- biotic factors --- abiotic factors --- varroa mite detection --- diagnosis --- infestation --- mortality --- control --- organic treatment --- Apis cerana --- agriculture --- forests --- home garden --- neonicotinoid --- Tetragonula laeviceps --- Vespa velutina --- alien driver --- honey bee --- damage --- pollinator --- populations under study --- biological effects --- stress --- experimental methods --- techniques --- honey bees --- Varroa destructor --- experimental apiaries --- varroacidal efficacy --- VMP --- honeybee mortality incidents --- pesticide --- survey --- LC-MS/MS --- GC-MS/MS --- hydroxymethylfurfural --- cell death --- immunohistochemistry --- Nosema ceranae --- corn --- honeybee colony --- monitoring hive --- neonicotinoids --- oilseed rape --- sunflower --- varroa control --- colony losses --- forage --- beekeeping --- citizen science --- overwintering --- monitoring --- honey bee diseases --- stressors --- pathology --- honey bee mortalities --- colonies management --- BPMN --- hives monitoring --- IoT --- modeling & simulation --- interoperability --- sensors --- honeybee behavior --- Industry 4.0 --- workflow --- Apis mellifera --- honey bee colony losses --- biotic factors --- abiotic factors --- varroa mite detection --- diagnosis --- infestation --- mortality --- control --- organic treatment --- Apis cerana --- agriculture --- forests --- home garden --- neonicotinoid --- Tetragonula laeviceps --- Vespa velutina --- alien driver --- honey bee --- damage --- pollinator --- populations under study --- biological effects --- stress --- experimental methods --- techniques --- honey bees --- Varroa destructor --- experimental apiaries --- varroacidal efficacy --- VMP --- honeybee mortality incidents --- pesticide --- survey --- LC-MS/MS --- GC-MS/MS --- hydroxymethylfurfural --- cell death --- immunohistochemistry --- Nosema ceranae --- corn --- honeybee colony --- monitoring hive --- neonicotinoids --- oilseed rape --- sunflower --- varroa control --- colony losses --- forage --- beekeeping --- citizen science --- overwintering --- monitoring --- honey bee diseases --- stressors --- pathology --- honey bee mortalities --- colonies management --- BPMN --- hives monitoring --- IoT --- modeling & simulation --- interoperability --- sensors --- honeybee behavior --- Industry 4.0 --- workflow


Book
Analysis of Chemical Contaminants in Food
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Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

How many times have we thought with concern about the possible contamination of food? Pollution, agricultural treatments, technological treatments, and packaging are the best-known human sources of toxic substances as food contaminants. The present book contains 11 original research papers representing various approaches of identifying and measuring toxic residues in food materials. The analytical determination of food contaminants is an indispensable tool in characterizing the adverse effects and unexpected toxicity related to food intake. No risk assessment would be possible without data from the analysis of food contaminants. This Special Issue is an interesting overview of recent methods and is highly representative of a broad worldwide outline, collecting authors from ten different countries and four continents. Very different toxics are described, from volatile organic compounds to heavy metals and from highly polar chemicals to classical organic contaminants. A wide range of analytical techniques are portrayed, including sample preparation and clean-up methodologies, classical chromatographic and hyphenated spectroscopies, and the latest high-resolution mass spectrometry applications. The presented works consider a varied selection of foods: the studied matrices are meat, fishery products, fruits, and miscellaneous beverages.

Keywords

Medicine --- furfuryl alcohol --- β-myrcene --- carcinogens --- occurrence --- blueberries --- lingonberries --- rose hips --- aluminium --- cadmium --- chromium --- nickel --- lead --- provisional tolerable intake --- perfluorooctane sulfonate --- perfluorooctane acid --- PFOS --- PFOA --- mediterranean fish --- toxicological risk --- high-resolution mass spectrometry --- Orbitrap --- structure elucidation --- pesticide residue analysis --- matcha --- conazole fungicides --- pressurized solvent extraction --- phthalate --- non-alcoholic beverages --- liquid-liquid extraction --- response surface methodology --- GC-MS/MS --- coffee --- acrylamide --- furan --- 5-hydroxymethylfurfural --- risk assessment --- magnetic stirring assisted demulsification dispersive liquid-liquid microextraction --- polycyclic aromatic hydrocarbons --- grilled pork --- high performance liquid chromatography --- infant formulae --- infant foods --- minerals --- toxic metals --- hydroxymethylfurfural --- storage conditions --- safety --- breast milk --- antibiotic residues --- pesticide residues --- LC-MS/MS --- mass spectrometry methods --- fishery product --- hydrogen peroxide --- illicit treatment --- furfuryl alcohol --- β-myrcene --- carcinogens --- occurrence --- blueberries --- lingonberries --- rose hips --- aluminium --- cadmium --- chromium --- nickel --- lead --- provisional tolerable intake --- perfluorooctane sulfonate --- perfluorooctane acid --- PFOS --- PFOA --- mediterranean fish --- toxicological risk --- high-resolution mass spectrometry --- Orbitrap --- structure elucidation --- pesticide residue analysis --- matcha --- conazole fungicides --- pressurized solvent extraction --- phthalate --- non-alcoholic beverages --- liquid-liquid extraction --- response surface methodology --- GC-MS/MS --- coffee --- acrylamide --- furan --- 5-hydroxymethylfurfural --- risk assessment --- magnetic stirring assisted demulsification dispersive liquid-liquid microextraction --- polycyclic aromatic hydrocarbons --- grilled pork --- high performance liquid chromatography --- infant formulae --- infant foods --- minerals --- toxic metals --- hydroxymethylfurfural --- storage conditions --- safety --- breast milk --- antibiotic residues --- pesticide residues --- LC-MS/MS --- mass spectrometry methods --- fishery product --- hydrogen peroxide --- illicit treatment


Book
Solid Phase Extraction: State of the Art and Future Perspectives
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ISBN: 3039211595 3039211587 Year: 2019 Publisher: MDPI - Multidisciplinary Digital Publishing Institute

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This book is a collection of 13 innovative papers describing the state of the art and the future perspectives in solid-phase extraction covering several analytical fields prior to the use of gas or liquid chromatographic analysis. New sorptive materials are presented including carbon nanohorn suprastructures on paper support, melamine sponge functionalized with urea–formaldehyde co-oligomers, chiral metal–organic frameworks, UiO-66-based metal–organic frameworks, and fabric phase sorptive media for various applications. Solid-phase extraction can be applied in several formats aside from the conventional cartridges or mini-column approach, e.g., online solid-phase extraction, dispersive solid-phase microextraction, and in-syringe micro-solid-phase extraction can be very helpful for analyte pre-concentration and sample clean-up. Polycyclic musks in aqueous samples, 8-Nitroguanine in DNA by chemical derivatization antibacterial diterpenes from the roots of salvia prattii, perfluoroalkyl substances (PFASs) in aater samples by bamboo charcoal-based SPE, parabens in environmental water samples, benzotriazoles as environmental pollutants, organochlorine pesticide residues in various fruit juices and water samples and synthetic peptide purification are among the applications cited in this collection. All these outstanding contributions highlight the necessity of this analytical step, present the advantages and disadvantages of each method and focus on the green analytical chemistry guidelines that have to be fulfilled in current analytical practices.


Book
Five Years of Separations : Feature Paper 2018
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Five years of Separations are celebrated by a collection of ten feature articles: one review and nine research articles on topics of current interest. Applications of Gas Chromatography for the Analysis of Tricyclic Antidepressants in Biological Matrices are presented focusing on novel extraction techniques and novel materials used for sample preparation due to the great demand for method development for the determination of TCAs in biofluids, especially for therapeutic drug monitoring. Original research articles include the following: 1. Insights into the Mechanism of Separation of Bisphosphonates by Zwitterionic Hydrophilic Interaction Liquid Chromatography: Application to the Quantitation of Risedronate in Pharmaceuticals. 2. A method based on micro-matrix solid-phase dispersion (μ-MSPD) followed by gas-chromatography tandem mass spectrometry (GC–MS/MS), developed to analyze UV filters in personal care products. 3. The performance of a vibratory shear-enhanced process (VSEP) combined with an appropriate membrane unit for the treatment of simulated or industrial tannery wastewaters. 4. A method for the analysis of thyroid hormones by liquid chromatography-mass spectrometry that was used for the dissolution testing of single- and dual-component thyroid hormone supplements via a two-stage biorelevant dissolution procedure. 5. A method involving the collection and determination of organic and inorganic gunshot residues on hands using online in-tube solid-phase microextraction (IT-SPME) coupled to miniaturized capillary liquid chromatography with diode array detection (CapLC-DAD) and scanning electron microscopy coupled to energy dispersion X-ray (SEM-EDX), respectively, for quantifying both residues. 6. The gas chromatographic retention behavior of 16 polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs on a new ionic liquid stationary phase, 1,12-di(tripropylphosphonium) dodecane bis(trifluoromethanesulfonyl)imide (SLB®-ILPAH) intended for the separation of PAH mixtures, which was compared with the elution pattern on more traditional stationary phases: a non-polar phenyl arylene (DB-5ms) and a semipolar 50% phenyl dimethyl siloxane (SLB PAHms) column. 7. The Multiple-Stage Precursor Ion Separation and High Resolution Mass Spectrometry toward Structural Characterization of 2,3-Diacyltrehalose Family from Mycobacterium tuberculosis 8. The use of micellar electrokinetic chromatography (MEKC) for studying the hydrophobic character of modified Monomethyl Auristatin E derivatives, as Novel Candidates for the Design of Antibody–Drug Conjugates, which are promising state-of-the-art biopharmaceutical drugs for selective drug-delivery applications and the treatment of diseases such as cancer. 9. The use of recycled diatomaceous earth as the extraction phase in solid phase microextraction (SPME) technique for the determination of polycyclic aromatic hydrocarbons (PAHs) in river water samples, with separation/detection performed by gas chromatography-mass spectrometry (GC-MS).


Book
Monitoring of Honey Bee Colony Losses
Author:
Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

In recent decades, independent national and international research programs have revealed possible reasons behind the death of managed honey bee colonies worldwide. Such losses are not due to a single factor, but instead are due to highly complex interactions between various internal and external influences, including pests, pathogens, honey bee stock diversity, and environmental changes. Reduced honey bee vitality and nutrition, exposure to agrochemicals, and the quality of colony management contribute to reduced colony survival in beekeeping operations. Our Special Issue (SI) on ‘’Monitoring of Honey Bee Colony Losses” aims to address the specific challenges that honey bee researchers and beekeepers face. This SI includes four reviews, with one being a meta-analysis that identifies gaps in the current and future directions for research into honey bee colonies’ mortalities. Other review articles include studies regarding the impact of numerous factors on honey bee mortality, including external abiotic factors (e.g., winter conditions and colony management) as well as biotic factors such as attacks by Vespa velutina and Varroa destructor.


Book
Detection of Residual Pesticides in Foods
Author:
Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Pesticides are used worldwide, and despite the fact that organic farming is increasing, they are still widely applied in different countries with pesticide regulations and monitoring programs. This Special Issue will cover the topic of the presence of pesticide residues in food, paying special attention to the use of modern analytical techniques based on chromatographic techniques coupled to mass spectrometry. Generic extraction methods are needed to allow the detection of pesticides with different physic-chemical properties, as well as different families of contaminants can be extracted simultaneously. Nevertheless, pluriresidue methods are still necessary for “orphan” compounds that cannot be included in multiresidue methods. Thus, in addition to targeted pesticides, the scope of this analysis can be increased and nowadays, metabolites are also detected, evaluating the degradation of pesticide residues in different food matrices.


Book
Five Years of Separations : Feature Paper 2018
Authors: ---
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Bookmark

Abstract

Five years of Separations are celebrated by a collection of ten feature articles: one review and nine research articles on topics of current interest. Applications of Gas Chromatography for the Analysis of Tricyclic Antidepressants in Biological Matrices are presented focusing on novel extraction techniques and novel materials used for sample preparation due to the great demand for method development for the determination of TCAs in biofluids, especially for therapeutic drug monitoring. Original research articles include the following: 1. Insights into the Mechanism of Separation of Bisphosphonates by Zwitterionic Hydrophilic Interaction Liquid Chromatography: Application to the Quantitation of Risedronate in Pharmaceuticals. 2. A method based on micro-matrix solid-phase dispersion (μ-MSPD) followed by gas-chromatography tandem mass spectrometry (GC–MS/MS), developed to analyze UV filters in personal care products. 3. The performance of a vibratory shear-enhanced process (VSEP) combined with an appropriate membrane unit for the treatment of simulated or industrial tannery wastewaters. 4. A method for the analysis of thyroid hormones by liquid chromatography-mass spectrometry that was used for the dissolution testing of single- and dual-component thyroid hormone supplements via a two-stage biorelevant dissolution procedure. 5. A method involving the collection and determination of organic and inorganic gunshot residues on hands using online in-tube solid-phase microextraction (IT-SPME) coupled to miniaturized capillary liquid chromatography with diode array detection (CapLC-DAD) and scanning electron microscopy coupled to energy dispersion X-ray (SEM-EDX), respectively, for quantifying both residues. 6. The gas chromatographic retention behavior of 16 polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs on a new ionic liquid stationary phase, 1,12-di(tripropylphosphonium) dodecane bis(trifluoromethanesulfonyl)imide (SLB®-ILPAH) intended for the separation of PAH mixtures, which was compared with the elution pattern on more traditional stationary phases: a non-polar phenyl arylene (DB-5ms) and a semipolar 50% phenyl dimethyl siloxane (SLB PAHms) column. 7. The Multiple-Stage Precursor Ion Separation and High Resolution Mass Spectrometry toward Structural Characterization of 2,3-Diacyltrehalose Family from Mycobacterium tuberculosis 8. The use of micellar electrokinetic chromatography (MEKC) for studying the hydrophobic character of modified Monomethyl Auristatin E derivatives, as Novel Candidates for the Design of Antibody–Drug Conjugates, which are promising state-of-the-art biopharmaceutical drugs for selective drug-delivery applications and the treatment of diseases such as cancer. 9. The use of recycled diatomaceous earth as the extraction phase in solid phase microextraction (SPME) technique for the determination of polycyclic aromatic hydrocarbons (PAHs) in river water samples, with separation/detection performed by gas chromatography-mass spectrometry (GC-MS).


Book
Detection of Residual Pesticides in Foods
Author:
Year: 2022 Publisher: Basel MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

Pesticides are used worldwide, and despite the fact that organic farming is increasing, they are still widely applied in different countries with pesticide regulations and monitoring programs. This Special Issue will cover the topic of the presence of pesticide residues in food, paying special attention to the use of modern analytical techniques based on chromatographic techniques coupled to mass spectrometry. Generic extraction methods are needed to allow the detection of pesticides with different physic-chemical properties, as well as different families of contaminants can be extracted simultaneously. Nevertheless, pluriresidue methods are still necessary for “orphan” compounds that cannot be included in multiresidue methods. Thus, in addition to targeted pesticides, the scope of this analysis can be increased and nowadays, metabolites are also detected, evaluating the degradation of pesticide residues in different food matrices.


Book
Analysis of Chemical Contaminants in Food
Author:
Year: 2020 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

How many times have we thought with concern about the possible contamination of food? Pollution, agricultural treatments, technological treatments, and packaging are the best-known human sources of toxic substances as food contaminants. The present book contains 11 original research papers representing various approaches of identifying and measuring toxic residues in food materials. The analytical determination of food contaminants is an indispensable tool in characterizing the adverse effects and unexpected toxicity related to food intake. No risk assessment would be possible without data from the analysis of food contaminants. This Special Issue is an interesting overview of recent methods and is highly representative of a broad worldwide outline, collecting authors from ten different countries and four continents. Very different toxics are described, from volatile organic compounds to heavy metals and from highly polar chemicals to classical organic contaminants. A wide range of analytical techniques are portrayed, including sample preparation and clean-up methodologies, classical chromatographic and hyphenated spectroscopies, and the latest high-resolution mass spectrometry applications. The presented works consider a varied selection of foods: the studied matrices are meat, fishery products, fruits, and miscellaneous beverages.

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