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Carbenes (Methylene compounds) --- Carbon, Divalent --- Divalent carbon --- Methene compounds --- Methylene compounds --- Carbon compounds --- Intermediates (Chemistry)

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Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

Catalysis. --- Chemistry, Inorganic. --- Iron compounds. --- Chemistry --- Physical Sciences & Mathematics --- Inorganic Chemistry --- Carbenes (Methylene compounds) --- Carbon, Divalent --- Divalent carbon --- Methene compounds --- Methylene compounds --- Ferric compounds --- Ferrous compounds --- Chemistry. --- Inorganic chemistry. --- Enzymology. --- Inorganic Chemistry. --- Carbon compounds --- Intermediates (Chemistry) --- Transition metal compounds --- Chemistry, inorganic. --- Enzymes. --- Biocatalysts --- Ferments --- Soluble ferments --- Catalysts --- Proteins --- Enzymology --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Inorganic chemistry --- Inorganic compounds --- Biochemistry --- Enzymes

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It was only in the early 1990s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated. Since the first report on the application of NHCs as ligands in transition metal catalysis in 1995, NHC have found numerous applications and have been established as a versatile and indispensable class of ligands. For many reactions like metathesis or cross-coupling reactions NHCs have often become the ligands of choice, allowing otherwise difficult transformations. In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes. The use of NHC as ligands in catalysis has reached a certain level of maturity and this book allows the reader to get a balanced view of this increasingly important ligand class.

Carbenes (Methylene compounds) --- Heterocyclic compounds. --- Transition metal catalysts. --- Carbènes --- Composés hétérocycliques --- Métaux de transition --- Catalyseurs --- Carbenes (Methylene compounds) -- Reactivity. --- Electronic books. -- local. --- Heterocyclic compounds --- Transition metal catalysts --- Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Reactivity. --- Carbon, Divalent --- Divalent carbon --- Methene compounds --- Methylene compounds --- Chemistry. --- Inorganic chemistry. --- Organometallic chemistry. --- Medicinal chemistry. --- Catalysis. --- Organometallic Chemistry. --- Inorganic Chemistry. --- Medicinal Chemistry. --- Carbon compounds --- Intermediates (Chemistry) --- Metal catalysts --- Chemistry, Organic. --- Chemistry, inorganic. --- Biochemistry. --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Biology --- Medical sciences --- Inorganic chemistry --- Inorganic compounds --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Organic chemistry --- Composition --- Organometallic chemistry . --- Chemistry, Medical and pharmaceutical --- Chemistry, Pharmaceutical --- Drug chemistry --- Drugs --- Medical chemistry --- Medicinal chemistry --- Pharmacochemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic --- Cycloids, Mixed (Chemistry) --- Heteroatomic compounds --- Heterocycles --- Mixed cycloids (Chemistry) --- Organic cyclic compounds