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CYCLOPROPANE DERIVATIVES --- BIOLOGICAL STUDIES --- CYCLOPROPANE DERIVATIVES --- BIOLOGICAL STUDIES
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CYCLOPROPANE DERIVATIVES --- TRANSITION METALS --- RING ENLARGEMENT --- REACTIONS --- PROPERTIES --- CYCLOPROPANE DERIVATIVES --- TRANSITION METALS --- RING ENLARGEMENT --- REACTIONS --- PROPERTIES
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Cyclopropane --- Enflurane --- Inhalation anesthesia --- Isoflurane --- Threshold limit values (Industrial toxicology) --- Physiological effect --- Physiological effect --- Complications --- Physiological effect
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Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.
Cyclopropane -- Synthesis. --- Cyclopropane --- Chemistry --- Physical Sciences & Mathematics --- Physical & Theoretical Chemistry --- Organic Chemistry --- Synthesis --- Cyclopropane. --- Trimethylene --- Chemistry. --- Organometallic chemistry. --- Catalysis. --- Organometallic Chemistry. --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic --- Physical sciences --- Cycloalkanes --- Propane --- Chemistry, Organic. --- Organic chemistry --- Organometallic chemistry .
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This current and five previous volumes (Volumes 133, 135, 144, 155, 178) convincingly demonstrate the vast applications of small rings in modern Organic Synthesis. Such applications range from total syntheses of cyclopropyl-group-containing natural products and non-natural biologically active compounds or compounds with other important properties (e.g. liquid crystalline) via syntheses of cyclopropyl analogues of natural and non-natural physiologically active compounds, e.g. peptidomimetics, to the use of cyclopropyl groups as reactive subunits in so-called composite functional groups. This current volume covers a survey of the wide range of biological activities of cyclopropyl-containing compounds, up-to-date comprehensive reviews on the multiple applicabilities of two multifunctional small ring building blocks - methyl-2-chloro-2-cyclopropylidene acetate and bicyclopropylidene - in Organic Synthesis as well as a striking new approach to cyclopentenones from easily accessible 1-ethynylcyclopropanols, which is rather general and favorably complements other cyclopentenone syntheses.
Organic compounds --- Ring formation (Chemistry) --- Chimie organique --- Cyclisation (Chimie) --- Synthesis. --- Synthèse --- 547.512 --- Cyclopropane group --- 547.512 Cyclopropane group --- 547.057 --- 547.057 Organic chemistry--?.057 --- Organic chemistry--?.057 --- Descriptive organic chemistry --- Ring formation (Chemistry). --- Organic chemistry. --- Organic Chemistry. --- Organic chemistry --- Chemistry --- Cyclopropane derivatives
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Akee --- Hypoglycin A --- Aminomethylenecyclopropanepropionic acid --- Amino acids --- Cyclopropane --- Hypoglycemic agents --- Plant toxins --- Propionic acid --- Ackee --- Apple, Akee --- Blighia sapida --- Capania sapida --- Blighia --- Toxicology --- Congresses --- Toxicology&delete& --- Human biochemistry
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