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Poly(ethylene oxide) (PEO) is the more promising material for lithium-ion conducting solid polymer electrolyte. However, linear PEO solid polymer electrolytes (SPE)s have insufficient ionic conductivity and low lithium transference number. The incorporation of carbonate groups, as polar units, has been evaluated to improve the dissolution of the salt and reduce the tendency for ion aggregate formation. In this research work, we propose an original method for the synthesis of new CO2 sourced poly(PEG oxo carbonate), poly(cyclic carbonate-thioether) and their corresponding copolymer with different (oxo-carbonate/cyclic carbonate-thioether) ratios. The copolymerization has been performed by the polyaddition of bis(αCC)s; PEG 4000, as diol; and 2,2′-(Ethylenedioxy)diethanethiol, as dithiol, in DMF at room temperature in presence of DBU. As a result, copolymers with high molecular weight (20,980 g mol-1 to 90,400 g mol-1) and stable to temperatures up to 200 °C, were obtained. These polymers show low glass transition temperature (Tg = -48 °C) and semi crystalline phase; but the crystallinity domains are diminished by the increasing proportion of cyclic carbonate thioether in the copolymers. These decrease on crystallinity is evident on the detrimental effect on the mechanical properties were the Young Modulus decreases from 135.7 MPa to 41.9 MPa. The mixture of copolymers with 30 wt% of bis(trifluoromethylsulfonyl)amine lithium salt (LiTFSi) completely suppresses the crystallinity on the poly(PEG-oxo-carbonate-co-cyclic carbonate-thioether)s. FTIR spectra revealed the preference of coordination of the Li+ with the cyclic carbonate group rather than the linear carbonate group.

Solid polymer electrolytes --- Polycarbonate --- carbon dioxide --- polymerization --- poly(ethylene oxide) --- Cyclic carbonate --- Physique, chimie, mathématiques & sciences de la terre > Chimie --- Ingénierie, informatique & technologie > Science des matériaux & ingénierie

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Polymerized nanoparticles and nanofibers can be prepared using various processes, such as chemical synthesis, the electrochemical method, electrospinning, ultrasonic irradiation, hard and soft templates, seeding polymerization, interfacial polymerization, and plasma polymerization. Among these processes, plasma polymerization and aerosol-through-plasma (A-T-P) processes have versatile advantages, especially due to them being “dry", for the deposition of plasma polymer films and carbon-based materials with functional properties suitable for a wide range of applications, such as electronic and optical devices, protective coatings, and biomedical materials. Furthermore, it is well known that plasma polymers are highly cross-linked, pinhole free, branched, insoluble, and adhere well to most substrates. In order to synthesize the polymer films using the plasma processes, therefore, it is very important to increase the density and electron temperature of plasma during plasma polymerization.

Technology: general issues --- Chemical engineering --- polytetrafluoroethylene --- fluorine depletion --- hydrogen plasma --- VUV radiation --- surface modification --- hydrophilic --- polyamide --- gaseous plasma --- water contact angle --- XPS --- polyamide membranes --- magnetron sputtering --- TiO2 + AgO coatings --- low-pressure plasma --- plasma treatment --- polyaniline (PANI) --- conductive polymer --- plasma polymerization --- aniline --- atmospheric pressure plasma reactor (AP plasma reactor) --- in-situ iodine (I2) doping --- atmospheric pressure plasma --- filler --- polylactic acid --- polymer composite --- polyethylene --- corona discharge --- polyethylene glycol --- adhesion --- polymer --- biomedical applications --- additive manufacturing --- toluidine blue method --- enzymatic degradation --- microwave discharge --- discharges in liquids --- microwave discharge in liquid hydrocarbons --- methods of generation --- plasma properties --- gas products --- solid products --- plasma diagnostics --- plasma modeling --- room temperature growth --- porous polythiophene --- conducting polymer --- NO2 --- gas sensors --- ion beam sputtering --- continuum equation --- plasma --- sublimation --- PA6.6 --- cold plasma --- electrical discharges --- voltage multiplier --- polymers --- oleofobization --- paper --- cellulose --- HMDSO --- atmospheric-pressure plasma --- solution plasma --- polymer films --- nanoparticles --- surface wettability --- graphene oxide --- cyclic olefin copolymer --- GO reduction --- titanium (Ti) alloys --- low-temperature plasma polymerization --- plasma-fluorocarbon-polymer --- anti-adhesive surface --- inflammatory/immunological response --- intramuscularly implantation --- atmospheric pressure plasma jet --- dielectric barrier discharge --- piezoelectric direct discharge --- surface free energy --- test ink --- surface activation --- allyl-substituted cyclic carbonate --- free-radical polymerization --- plasma process --- plasma polymerisation --- plasma deposition --- poly(lactic acid) --- PLA --- ascorbic acid --- fumaric acid --- grafting --- wettability --- BOPP foil --- DCSBD --- VDBD --- ageing --- surface functionalization --- atmospheric pressure plasmas --- glow-like discharge --- single pin electrode --- PANI thin film --- polytetrafluoroethylene --- fluorine depletion --- hydrogen plasma --- VUV radiation --- surface modification --- hydrophilic --- polyamide --- gaseous plasma --- water contact angle --- XPS --- polyamide membranes --- magnetron sputtering --- TiO2 + AgO coatings --- low-pressure plasma --- plasma treatment --- polyaniline (PANI) --- conductive polymer --- plasma polymerization --- aniline --- atmospheric pressure plasma reactor (AP plasma reactor) --- in-situ iodine (I2) doping --- atmospheric pressure plasma --- filler --- polylactic acid --- polymer composite --- polyethylene --- corona discharge --- polyethylene glycol --- adhesion --- polymer --- biomedical applications --- additive manufacturing --- toluidine blue method --- enzymatic degradation --- microwave discharge --- discharges in liquids --- microwave discharge in liquid hydrocarbons --- methods of generation --- plasma properties --- gas products --- solid products --- plasma diagnostics --- plasma modeling --- room temperature growth --- porous polythiophene --- conducting polymer --- NO2 --- gas sensors --- ion beam sputtering --- continuum equation --- plasma --- sublimation --- PA6.6 --- cold plasma --- electrical discharges --- voltage multiplier --- polymers --- oleofobization --- paper --- cellulose --- HMDSO --- atmospheric-pressure plasma --- solution plasma --- polymer films --- nanoparticles --- surface wettability --- graphene oxide --- cyclic olefin copolymer --- GO reduction --- titanium (Ti) alloys --- low-temperature plasma polymerization --- plasma-fluorocarbon-polymer --- anti-adhesive surface --- inflammatory/immunological response --- intramuscularly implantation --- atmospheric pressure plasma jet --- dielectric barrier discharge --- piezoelectric direct discharge --- surface free energy --- test ink --- surface activation --- allyl-substituted cyclic carbonate --- free-radical polymerization --- plasma process --- plasma polymerisation --- plasma deposition --- poly(lactic acid) --- PLA --- ascorbic acid --- fumaric acid --- grafting --- wettability --- BOPP foil --- DCSBD --- VDBD --- ageing --- surface functionalization --- atmospheric pressure plasmas --- glow-like discharge --- single pin electrode --- PANI thin film

Choose an application

• Reference Manager
• EndNote
• RefWorks (Direct export to RefWorks)

Polymerized nanoparticles and nanofibers can be prepared using various processes, such as chemical synthesis, the electrochemical method, electrospinning, ultrasonic irradiation, hard and soft templates, seeding polymerization, interfacial polymerization, and plasma polymerization. Among these processes, plasma polymerization and aerosol-through-plasma (A-T-P) processes have versatile advantages, especially due to them being “dry", for the deposition of plasma polymer films and carbon-based materials with functional properties suitable for a wide range of applications, such as electronic and optical devices, protective coatings, and biomedical materials. Furthermore, it is well known that plasma polymers are highly cross-linked, pinhole free, branched, insoluble, and adhere well to most substrates. In order to synthesize the polymer films using the plasma processes, therefore, it is very important to increase the density and electron temperature of plasma during plasma polymerization.

polytetrafluoroethylene --- fluorine depletion --- hydrogen plasma --- VUV radiation --- surface modification --- hydrophilic --- polyamide --- gaseous plasma --- water contact angle --- XPS --- polyamide membranes --- magnetron sputtering --- TiO2 + AgO coatings --- low-pressure plasma --- plasma treatment --- polyaniline (PANI) --- conductive polymer --- plasma polymerization --- aniline --- atmospheric pressure plasma reactor (AP plasma reactor) --- in-situ iodine (I2) doping --- atmospheric pressure plasma --- filler --- polylactic acid --- polymer composite --- polyethylene --- corona discharge --- polyethylene glycol --- adhesion --- polymer --- biomedical applications --- additive manufacturing --- toluidine blue method --- enzymatic degradation --- microwave discharge --- discharges in liquids --- microwave discharge in liquid hydrocarbons --- methods of generation --- plasma properties --- gas products --- solid products --- plasma diagnostics --- plasma modeling --- room temperature growth --- porous polythiophene --- conducting polymer --- NO2 --- gas sensors --- ion beam sputtering --- continuum equation --- plasma --- sublimation --- PA6.6 --- cold plasma --- electrical discharges --- voltage multiplier --- polymers --- oleofobization --- paper --- cellulose --- HMDSO --- atmospheric-pressure plasma --- solution plasma --- polymer films --- nanoparticles --- surface wettability --- graphene oxide --- cyclic olefin copolymer --- GO reduction --- titanium (Ti) alloys --- low-temperature plasma polymerization --- plasma-fluorocarbon-polymer --- anti-adhesive surface --- inflammatory/immunological response --- intramuscularly implantation --- atmospheric pressure plasma jet --- dielectric barrier discharge --- piezoelectric direct discharge --- surface free energy --- test ink --- surface activation --- allyl-substituted cyclic carbonate --- free-radical polymerization --- plasma process --- plasma polymerisation --- plasma deposition --- poly(lactic acid) --- PLA --- ascorbic acid --- fumaric acid --- grafting --- wettability --- BOPP foil --- DCSBD --- VDBD --- ageing --- surface functionalization --- atmospheric pressure plasmas --- glow-like discharge --- single pin electrode --- PANI thin film