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ALKENES --- COUPLING REACTION --- CYCLOADDITION REACTION --- ALKENES --- COUPLING REACTION --- CYCLOADDITION REACTION

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CROSS-COUPLING REACTION --- NANOSTRUCTURES --- CROSS-COUPLING REACTION --- NANOSTRUCTURES

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Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two reviews and two articles, focuses on recent promising research and novel trends in the field of cross-coupling reactions, employing a range of different catalysts. A review by Kostas and Steele provides a survey of the research in the area of cross-coupling catalytic reactions with transition metal complexes based on the thiosemicarbazone unit and a discussion of the prospects for future developments. Another review by Polychronopoulou, Shaya and co-authors describes the progress made over the 21st century concerning the utilization of C(sp3)–organoboranes as partners in metal-catalyzed C(sp3)–C(sp2) cross-couplings, such as B-alkyl Suzuki–Miyaura reactions. The article by Waldvogel, Breinbauer and co-authors demonstrates for the first time the synthetic potential of combining the electro-oxidative dehydrogenative cross coupling of ortho-substituted phenols with Pd-catalyzed cross-coupling reactions. In the second article, Štĕpnička and co-workers describe the preparation of palladium catalysts deposited over silica gel-bearing composite amide-donor functional moieties on the surface, which were evaluated in the Sonogashira-type cross-coupling of acyl chlorides with terminal alkynes.

Technology: general issues --- Suzuki-Miyaura cross-couplings --- C(sp3) -C(sp2) --- alkylboron reagents --- metal catalysis --- alpha-helix --- anode --- CH-activation --- cross-coupling --- electrosynthesis --- oligoarene --- peptidomimetics --- phenol --- protein-protein interactions --- triflate --- thiosemicarbazone --- metal complex --- transition metal catalysis --- cross-coupling reaction --- Heck reaction --- Suzuki reaction --- Sonogashira reaction --- Kumada reaction --- Buchwald-Hartwig reaction --- deposited catalysts --- palladium --- functional amides --- alkynyl ketone synthesis --- Suzuki-Miyaura cross-couplings --- C(sp3) -C(sp2) --- alkylboron reagents --- metal catalysis --- alpha-helix --- anode --- CH-activation --- cross-coupling --- electrosynthesis --- oligoarene --- peptidomimetics --- phenol --- protein-protein interactions --- triflate --- thiosemicarbazone --- metal complex --- transition metal catalysis --- cross-coupling reaction --- Heck reaction --- Suzuki reaction --- Sonogashira reaction --- Kumada reaction --- Buchwald-Hartwig reaction --- deposited catalysts --- palladium --- functional amides --- alkynyl ketone synthesis

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Transition metal-catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to materials. This book, consisting of an editorial, two reviews and two articles, focuses on recent promising research and novel trends in the field of cross-coupling reactions, employing a range of different catalysts. A review by Kostas and Steele provides a survey of the research in the area of cross-coupling catalytic reactions with transition metal complexes based on the thiosemicarbazone unit and a discussion of the prospects for future developments. Another review by Polychronopoulou, Shaya and co-authors describes the progress made over the 21st century concerning the utilization of C(sp3)–organoboranes as partners in metal-catalyzed C(sp3)–C(sp2) cross-couplings, such as B-alkyl Suzuki–Miyaura reactions. The article by Waldvogel, Breinbauer and co-authors demonstrates for the first time the synthetic potential of combining the electro-oxidative dehydrogenative cross coupling of ortho-substituted phenols with Pd-catalyzed cross-coupling reactions. In the second article, Štĕpnička and co-workers describe the preparation of palladium catalysts deposited over silica gel-bearing composite amide-donor functional moieties on the surface, which were evaluated in the Sonogashira-type cross-coupling of acyl chlorides with terminal alkynes.

Technology: general issues --- Suzuki–Miyaura cross-couplings --- C(sp3) –C(sp2) --- alkylboron reagents --- metal catalysis --- alpha-helix --- anode --- CH-activation --- cross-coupling --- electrosynthesis --- oligoarene --- peptidomimetics --- phenol --- protein-protein interactions --- triflate --- thiosemicarbazone --- metal complex --- transition metal catalysis --- cross-coupling reaction --- Heck reaction --- Suzuki reaction --- Sonogashira reaction --- Kumada reaction --- Buchwald–Hartwig reaction --- deposited catalysts --- palladium --- functional amides --- alkynyl ketone synthesis --- n/a --- Suzuki-Miyaura cross-couplings --- C(sp3) -C(sp2) --- Buchwald-Hartwig reaction

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Boron, a metalloid with rich chemistry, continues to offer a diverse platform in designing novel catalysts and materials for applications in a variety of areas. This book, while celebrating Professor Todd Marder’s contributions to boron chemistry, on the occasion of his 65th birthday in November 2020, highlights and brings into focus some of the important discoveries in this field, through state-of-the-art reviews and research articles

Technology: general issues --- 1,1,1-tri(boryl)alkanes --- 1,2,3-tri(boryl)alkanes --- 1,1,2-tri(boryl)alkanes --- 1,1,2-tri(boryl)alkenes --- synthetic approaches --- synthetic applications --- dicarbollide --- ruthenium --- metallodrug --- kinase inhibitor --- closo-o-carborane --- nido-o-carborane --- intramolecular charge transfer --- deboronation --- color change --- boron --- π-conjugated materials --- opto-electronics --- tetracoordinated --- m-carborane --- electrophilic substitution --- coupling reaction --- organic branches --- Hirshfield Study --- 1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes --- salt-free reduction --- rotational barrier --- B=N bond --- immobilization of antibodies --- IL-10 --- magnetic nanoparticles --- pre-concentration of antigens --- saliva matrix --- TNF-α --- fluorosulfanyl group --- fluorinated ligands --- phosphines --- rhodium --- iridium --- conjugated hydrocarbon --- isoelectronic molecule --- electronic structure --- quantum chemistry --- singlet-triplet gap --- 1,1,1-tri(boryl)alkanes --- 1,2,3-tri(boryl)alkanes --- 1,1,2-tri(boryl)alkanes --- 1,1,2-tri(boryl)alkenes --- synthetic approaches --- synthetic applications --- dicarbollide --- ruthenium --- metallodrug --- kinase inhibitor --- closo-o-carborane --- nido-o-carborane --- intramolecular charge transfer --- deboronation --- color change --- boron --- π-conjugated materials --- opto-electronics --- tetracoordinated --- m-carborane --- electrophilic substitution --- coupling reaction --- organic branches --- Hirshfield Study --- 1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes --- salt-free reduction --- rotational barrier --- B=N bond --- immobilization of antibodies --- IL-10 --- magnetic nanoparticles --- pre-concentration of antigens --- saliva matrix --- TNF-α --- fluorosulfanyl group --- fluorinated ligands --- phosphines --- rhodium --- iridium --- conjugated hydrocarbon --- isoelectronic molecule --- electronic structure --- quantum chemistry --- singlet-triplet gap