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Increasing attention is being paid to the development of effective technologies for the sequestration of CO2 and its storage. Hopefully, this will result in processes that can lead to its valorisation as a chemical, e.g., for the regeneration of fuels, but also for the production of intermediates. These are usually energy demands and rather slow processes, requiring energy input and catalysts. Some examples are the innovative strategies for the hydrogenation, photoconversion, or electroreduction of carbon dioxide. This book collects original research papers, reviews, and commentaries focused on the challenges related to the valorisation and conversion of CO2.
microwaves --- dimethyl carbonate --- n/a --- dynamic reaction conditions --- catalysis --- water sorption --- alkali promoter --- Titania --- high pressure photocatalysis --- diatomite --- photoreduction --- catalyst preparation --- dehydration --- CO2 reduction --- photocatalysis --- CO2 hydrogenation --- carbon dioxide --- mechanochemistry --- CO2 electro-reduction --- surface oxidation-reduction --- operando XAS --- metal-carbon-CNF composites --- carbon nanofibers --- ultrasound --- carbon-based electrodes --- water diffusion --- alkali oxide --- quick-EXAFS --- H2 dropout --- CO2 methanation --- plastic waste
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This reprint contains contributions focusing on recent developments in the design, synthesis, and characterization of nanocatalysts intended for applications in environmental protection and low carbon footprint power generation processes thanks to the overall effort of scientists and researchers for a cleaner and more sustainable future. New synthetic approaches to the production and in-depth characterization of innovative nanostructured composites and hybrid materials with well-controlled textural and surface chemistry properties that give performance advantages in a variety of important environmental and energy applications such as CO2 utilization/recycling, hydrogen and syngas production, biosensing, and biocatalysis as well as in ways to obtain useful materials from waste are included, among others. This reprint is the result of one of the cutting-edge Special Issues in the field of Nanoscience and Nanotechnology organized by Nanomaterials to celebrate its 10th anniversary.
nanocarbon --- rocket fuels --- furfuryl alcohol --- fuming nitric acid --- waste --- hypergolics --- carbon materials --- CO2 methanation --- bimetallic catalysts --- Ni-based catalysts --- promoters --- alloy nanoparticles --- bimetallic synergy --- hybrid nanoflowers --- biosynthesis --- influencing factors --- biosensing cues --- bio-catalysis --- propane --- steam reforming --- hydrogen production --- perovskite --- ruthenium --- rhodium --- La2O2CO3 --- stability --- propane steam reforming --- H2 production --- Ni --- TiO2 --- CeO2 --- YSZ --- ZrO2 --- Al2O3 --- drifts --- n/a --- HDO reaction --- transition metal phosphides --- structure --- acidity --- characterization
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This reprint contains contributions focusing on recent developments in the design, synthesis, and characterization of nanocatalysts intended for applications in environmental protection and low carbon footprint power generation processes thanks to the overall effort of scientists and researchers for a cleaner and more sustainable future. New synthetic approaches to the production and in-depth characterization of innovative nanostructured composites and hybrid materials with well-controlled textural and surface chemistry properties that give performance advantages in a variety of important environmental and energy applications such as CO2 utilization/recycling, hydrogen and syngas production, biosensing, and biocatalysis as well as in ways to obtain useful materials from waste are included, among others. This reprint is the result of one of the cutting-edge Special Issues in the field of Nanoscience and Nanotechnology organized by Nanomaterials to celebrate its 10th anniversary.
Technology: general issues --- History of engineering & technology --- nanocarbon --- rocket fuels --- furfuryl alcohol --- fuming nitric acid --- waste --- hypergolics --- carbon materials --- CO2 methanation --- bimetallic catalysts --- Ni-based catalysts --- promoters --- alloy nanoparticles --- bimetallic synergy --- hybrid nanoflowers --- biosynthesis --- influencing factors --- biosensing cues --- bio-catalysis --- propane --- steam reforming --- hydrogen production --- perovskite --- ruthenium --- rhodium --- La2O2CO3 --- stability --- propane steam reforming --- H2 production --- Ni --- TiO2 --- CeO2 --- YSZ --- ZrO2 --- Al2O3 --- drifts --- HDO reaction --- transition metal phosphides --- structure --- acidity --- characterization
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This reprint is devoted to “greener catalysis for environmental applications”, and primarily covers the catalytic synthesis of value-added chemicals, as well as the catalytic removal of pollutants. The most important topics covered were the conversion of waste to the product, solvent-free conditions as well as toxicity assessment of the reaction products.
Research & information: general --- Chemistry --- selectivity tuning --- CO2 methanation --- reverse water gas shift --- photocatalysis --- dye --- UV --- peroxydisulfate --- advanced oxidation process --- Fischer-Tropsch --- jet fuel --- gasoline --- CoMn --- hydrotalcite-like precursors --- heterogeneous catalysis --- montmorillonite --- benzimidazoles --- gallium --- vanadium --- hydrodesulfurization --- hydrogenation --- synthesis method --- catalysis --- zero valent iron --- de-chlorination --- borohydride --- sol-gel --- ferromagnetic --- glycine–nitrate process --- copper-based nanoparticles --- photocatalysis activity --- NP9EO --- Fenton degradation --- ofloxacin --- Fe3O4 --- zeolite --- heterogeneous --- ion exchange resins --- waste cooking oil --- reuse of catalyst --- epoxidation --- Circular Economy --- contaminants of emerging concern --- advanced oxidation processes --- by-products --- n/a --- glycine-nitrate process
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In this book, we propose a collection of scientific and review articles on the production of hydrogen. The articles focus on the controlled storage and release of hydrogen; on the production of hydrogen from reforming from renewable sources, water splitting, and biological and photonic methods; on the intensification of the water gas shift process; and on the integration with purification methods such as pressure swing adsorption.
Technology: general issues --- Chemical engineering --- CO-PROX --- CO-SMET --- CO2 methanation --- hydrogen purification --- process integration --- microalgae --- acetic acid --- steam reforming --- hydrogen --- cobalt --- mesostructured materials --- biomass conversion --- hydrogen production --- kinetic models --- lignocellulosic residue --- thermal degradation --- water–gas shift --- process intensification --- structured catalysts --- kinetics --- aluminum alloy foam --- ceria --- platinum --- rhenium --- bioalcohol --- reforming --- coke --- catalyst stability --- active phase --- support --- promoter --- ammonia borane --- noble metal catalysts --- chemical hydrogen --- sulfurization --- NiS-NiS2 --- stainless steel 304 --- hydrogen evolution --- hydrogen energy and fuel cells --- impurity --- gasification --- water splitting --- dark-fermentation --- photo-fermentation --- CO gas-fermentation --- bio-photolysis --- electrolysis --- n/a --- water-gas shift
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This reprint is devoted to “greener catalysis for environmental applications”, and primarily covers the catalytic synthesis of value-added chemicals, as well as the catalytic removal of pollutants. The most important topics covered were the conversion of waste to the product, solvent-free conditions as well as toxicity assessment of the reaction products.
selectivity tuning --- CO2 methanation --- reverse water gas shift --- photocatalysis --- dye --- UV --- peroxydisulfate --- advanced oxidation process --- Fischer-Tropsch --- jet fuel --- gasoline --- CoMn --- hydrotalcite-like precursors --- heterogeneous catalysis --- montmorillonite --- benzimidazoles --- gallium --- vanadium --- hydrodesulfurization --- hydrogenation --- synthesis method --- catalysis --- zero valent iron --- de-chlorination --- borohydride --- sol-gel --- ferromagnetic --- glycine–nitrate process --- copper-based nanoparticles --- photocatalysis activity --- NP9EO --- Fenton degradation --- ofloxacin --- Fe3O4 --- zeolite --- heterogeneous --- ion exchange resins --- waste cooking oil --- reuse of catalyst --- epoxidation --- Circular Economy --- contaminants of emerging concern --- advanced oxidation processes --- by-products --- n/a --- glycine-nitrate process
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In this book, we propose a collection of scientific and review articles on the production of hydrogen. The articles focus on the controlled storage and release of hydrogen; on the production of hydrogen from reforming from renewable sources, water splitting, and biological and photonic methods; on the intensification of the water gas shift process; and on the integration with purification methods such as pressure swing adsorption.
CO-PROX --- CO-SMET --- CO2 methanation --- hydrogen purification --- process integration --- microalgae --- acetic acid --- steam reforming --- hydrogen --- cobalt --- mesostructured materials --- biomass conversion --- hydrogen production --- kinetic models --- lignocellulosic residue --- thermal degradation --- water–gas shift --- process intensification --- structured catalysts --- kinetics --- aluminum alloy foam --- ceria --- platinum --- rhenium --- bioalcohol --- reforming --- coke --- catalyst stability --- active phase --- support --- promoter --- ammonia borane --- noble metal catalysts --- chemical hydrogen --- sulfurization --- NiS-NiS2 --- stainless steel 304 --- hydrogen evolution --- hydrogen energy and fuel cells --- impurity --- gasification --- water splitting --- dark-fermentation --- photo-fermentation --- CO gas-fermentation --- bio-photolysis --- electrolysis --- n/a --- water-gas shift
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This reprint is devoted to “greener catalysis for environmental applications”, and primarily covers the catalytic synthesis of value-added chemicals, as well as the catalytic removal of pollutants. The most important topics covered were the conversion of waste to the product, solvent-free conditions as well as toxicity assessment of the reaction products.
Research & information: general --- Chemistry --- selectivity tuning --- CO2 methanation --- reverse water gas shift --- photocatalysis --- dye --- UV --- peroxydisulfate --- advanced oxidation process --- Fischer-Tropsch --- jet fuel --- gasoline --- CoMn --- hydrotalcite-like precursors --- heterogeneous catalysis --- montmorillonite --- benzimidazoles --- gallium --- vanadium --- hydrodesulfurization --- hydrogenation --- synthesis method --- catalysis --- zero valent iron --- de-chlorination --- borohydride --- sol-gel --- ferromagnetic --- glycine-nitrate process --- copper-based nanoparticles --- photocatalysis activity --- NP9EO --- Fenton degradation --- ofloxacin --- Fe3O4 --- zeolite --- heterogeneous --- ion exchange resins --- waste cooking oil --- reuse of catalyst --- epoxidation --- Circular Economy --- contaminants of emerging concern --- advanced oxidation processes --- by-products
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In this book, we propose a collection of scientific and review articles on the production of hydrogen. The articles focus on the controlled storage and release of hydrogen; on the production of hydrogen from reforming from renewable sources, water splitting, and biological and photonic methods; on the intensification of the water gas shift process; and on the integration with purification methods such as pressure swing adsorption.
Technology: general issues --- Chemical engineering --- CO-PROX --- CO-SMET --- CO2 methanation --- hydrogen purification --- process integration --- microalgae --- acetic acid --- steam reforming --- hydrogen --- cobalt --- mesostructured materials --- biomass conversion --- hydrogen production --- kinetic models --- lignocellulosic residue --- thermal degradation --- water-gas shift --- process intensification --- structured catalysts --- kinetics --- aluminum alloy foam --- ceria --- platinum --- rhenium --- bioalcohol --- reforming --- coke --- catalyst stability --- active phase --- support --- promoter --- ammonia borane --- noble metal catalysts --- chemical hydrogen --- sulfurization --- NiS-NiS2 --- stainless steel 304 --- hydrogen evolution --- hydrogen energy and fuel cells --- impurity --- gasification --- water splitting --- dark-fermentation --- photo-fermentation --- CO gas-fermentation --- bio-photolysis --- electrolysis
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This Special Issue on “New Trends in Catalysis for Sustainable CO2 Conversion”, released in the Catalysts open access journal, shows new research about the development of catalysts and catalytic routes for CO2 valorization, in addition to the optimization of the reaction conditions for the process. This issue includes ten articles and three reviews about different innovative processes for CO2 conversion.Carbon capture and storage (CCS) is a physical process consisting of the separation the CO2 (emitted by industry and the combustion processes for energy generation) and its transportation to geological storage isolates it from the atmosphere in the long term. However, the most promising routes for CO2 mitigation are those pursuing its catalytic valorization. By applying specific catalysts and suitable operating conditions, CO2 molecules react with other components to form longer chains (i.e., hydrocarbons). Accordingly, effort should be made to catalytically valorize CO2 (alone or co-fed with syngas) as an alternative way of reducing greenhouse gas emissions and obtaining high-value fuels and chemicals. Carbon capture and utilization (CCU) is a developing field with significant demand for research in the following aspects:The development of new catalysts, catalytic routes, and technologies for CO2 conversion;The study of new processes for obtaining fuels and chemicals from CO2;Optimization of the catalysts and the reaction conditions for these processes;Further steps in advanced processes using CO2-rich feeds (H2+CO2 or CO2 mixed with syngas), increasing product yields.
Technology: general issues --- History of engineering & technology --- Environmental science, engineering & technology --- carbon dioxide --- hydrogenation --- catalyst --- gas hourly space velocity (GHSV) --- fixed-bed reactor --- CO2–H2O photo-co-processing --- VIS-light driven reactions --- CO2 reduction --- photocatalysts properties --- soft oxidant --- oxidation --- dehydrogenation --- nano-catalyst --- electrochemical reduction of CO2 --- ionic liquids --- propylene carbonate --- imidazolium cation --- greenhouse gas --- climate change --- CO2 decomposition --- CO2 utilization --- SrFeO3−x --- CO2 methanation --- Ni-xSi/ZrO2 --- Si promotion --- oxygen vacancies --- CO2 hydrogenation --- light olefins --- catalyst deactivation --- CO2-Fischer-Tropsch (CO2-FT) --- iron-based catalysts --- methanol to olefins --- bifunctional composite catalysts --- SAPO-34 --- photocatalysis --- carbon-TiO2 --- nanocarbon --- carbon allotropes --- carbon nanotubes --- carbon nanofibers --- carbon nano-onions --- carbon dioxide electrolysis --- molten carbonate --- greenhouse gas mitigation --- cycloaddition --- ionic liquid --- deep eutectic solvents --- onium salt --- homogeneous catalysts --- heterogeneous catalysis --- CO2 conversion --- methane --- hydrocarbons --- iron oxide --- copper nanoparticles --- biomass --- Fischer–Tropsch synthesis --- carbon-supported iron catalyst --- gasoline --- diesel --- n/a --- CO2-H2O photo-co-processing --- Fischer-Tropsch synthesis
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