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Autoxidation of sulphur compounds
Authors: --- --- ---
ISBN: 0130535214 9780130535214 Year: 1992 Volume: vol *4 Publisher: New York London Tokyo Warsaw Ellis Horwood PWN-Polish Scientific Publishers

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Book
Autooxidation of unsaturated lipids
Author:
ISBN: 0121676307 Year: 1987 Volume: vol *19 Publisher: New York, NY ; London : Academic Press,


Book
Methods for the oxidation of organic compounds : alcohols, alcohol derivatives, alkyl halides, nitroalkanes, alkyl azides, carbonyl compounds, hydroxyarenes and aminoarenes
Author:
ISBN: 0123155029 0323148441 9780123155023 Year: 1988 Volume: vol *2 Publisher: London: Academic press,

Metal-oxo and metal-peroxo species in catalytic oxidations
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ISBN: 3540669434 3540465928 Year: 2000 Volume: 97 Publisher: New York, NY ; Berlin : Springer-Verlag,

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Abstract

The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.

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