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Dissertation
Master thesis : Geometallurgical analysis on the metallurgical behavior of the ore originating from selected block of the DPM Chelopech underground mine in Bulgaria (Université de Liège)
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Year: 2017 Publisher: Liège Université de Liège (ULiège)

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Abstract

Geological complexity of the Dundee Precious Metals (DPM) Chelopech mine, Bulgaria has motivated the proposal and development of a geometallurgical characterization of the new block 103, scheduled to start production in the second half of 2017. This project aimed to achieve such characterization by performing metallurgical test on samples selected from the block, such as lab scale batch sulphide flotation with copper and pyrite cleaning stages, drop weight and batch grinding tests. Optical microscopy, X-ray diffraction and ZEISS Mineralogic Mining Automated Mineralogy were used to identify mineralogical features in the samples tested. A geometallurgical methodology using a principal component analysis and linear modelling was followed. Sulphosalts recovery, Axb index and operating work index were correlated with mineral characteristics. As a result it was possible to identify that enargite, tennantite and chalcopyrite contents and grain sizes controlled copper recovery in the flotation circuit; gold recovery in the copper cleaning stage was influenced by sulphosalts – pyrite association. Pyrite, chalcopyrite and sulphosalts content controlled the recovery of pyrite in the pyrite cleaning stage. Gangue minerals such as quartz, kaolinite, alunite and enargite/tennantite controlled impact breakage and operating work index; however, it is believed that texture played an important role in rock comminution testing. A proposed sub-division of the block 103 in two geometallurgical domains, East and West, was performed following a previous delimitation by the geological team of DPM Chelopech. Further sub-domaining should be performed using extra sampling and tests.


Dissertation
Master thesis : Cross-validation of Automated Quantitative Mineralogical Analysis Results of Mixed Copper Ore and Developments in Methodologies Using Correlative Microscopy (Université de Liège)
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Year: 2019 Publisher: Liège Université de Liège (ULiège)

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The imminent challenge in geometallurgical characterization of today’s ore deposits is its inherent heterogeneity and complexity which demands fast, resource-efficient, robust, and cost-effective means of measurement and analysis. To address this concern, mining operations all over the world are incorporating SEM-based automated mineralogy systems. Next generation platforms have been developed to bring out these technologies from the laboratories unto the field for on-site mineralogical characterization. Its widespread use have established its significance in the mining industry, however, cross-validation of results between technologies has not been well studied. 
This study aims to compare and validate results gathered from two SEM platforms: the ZEISS SIGMA 300 Gemini (FEG) with the ZEISS MinSCAN (W-filament) both are coupled with the ZEISS Mineralogic Mining system. Three sets of mixed Cu ore samples (feed, concentrate, and tails) from the Kansanshi deposit were analyzed exploring the effects of SEM operating conditions and sample preparation. The work focused on comparison of the modal mineralogy. The quality of results were assessed by its repeatability and cross-validated with chemical assay (AR-AAS). The limitations of these SEM-based systems were defined and solutions were proposed involving correlative microscopy. The feasibility of employing machine learning algorithms in image classification techniques were proposed to improve data acquisition process and accuracy of results of automated mineralogy systems.
This study establishes the effect of the mineral recipe or SIP to the accuracy of results of a quantitative mineralogical analysis. Expertise in the deposit mineralogy as well as in the capabilities and limitations of the SEM is crucial in achieving reliable results. Cross-validation of back-calculated Mineralogic Cu and Fe grades from modal mineralogy with the measured AR-AAS chemical analysis shows that the error is minimized with the ZEISS SIGMA on samples prepared using carbon black. However, it must be noted that not all numerical values can be directly compared between the results and should be treated merely as indications of accuracy.
Combined features from images obtained from the optical microscope (RGB) and the SEM (BSE) showed the least error in classification using a support vector machine algorithm. The segmented image shows mineral domains where EDX analysis can be performed on a set amount of points veering away from the pixel-by-pixel full mapping acquisition mode. This methodology can be developed and applied to automated mineralogy image processing systems as a domain-based acquisition mode. This has the potential to improve quantitative mineralogical analysis results accuracy while reducing acquisition time and resource costs.


Book
Applications of SEM Automated Mineralogy : From Ore Deposits over Processing to Secondary Resource Characterization
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Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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During the last decade, software developments in Scanning Electron Microscopy (SEM) provoked a notable increase of applications to the study of solid matter. The mineral liberation analysis (MLA) of processed metal ores was an important drive for innovations that led to QEMSCAN, MLA and other software platforms. These combine the assessment of the backscattered electron (BSE) image to the directed steering of the electron beam for energy dispersive spectroscopy (EDS) to automated mineralogy. However, despite a wide distribution of SEM instruments in material research and industry, the potential of SEM automated mineralogy is still under-utilised. The characterisation of primary ores, and the optimisation of comminution, flotation, mineral concentration and metallurgical processes in the mining industry by generating quantified data, is still the major application field of SEM automated mineralogy. However, there is interesting potential beyond these classical fields of geometallurgy and metal ore fingerprinting. Slags, pottery and artefacts can be studied in an archeological context for the recognition of provenance and trade pathways; soil, and solid particles of all kinds, are objects in forensic science. SEM automated mineralogy allows new insight in the fields of process chemistry and recycling technology.


Book
Applications of SEM Automated Mineralogy : From Ore Deposits over Processing to Secondary Resource Characterization
Author:
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

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Abstract

During the last decade, software developments in Scanning Electron Microscopy (SEM) provoked a notable increase of applications to the study of solid matter. The mineral liberation analysis (MLA) of processed metal ores was an important drive for innovations that led to QEMSCAN, MLA and other software platforms. These combine the assessment of the backscattered electron (BSE) image to the directed steering of the electron beam for energy dispersive spectroscopy (EDS) to automated mineralogy. However, despite a wide distribution of SEM instruments in material research and industry, the potential of SEM automated mineralogy is still under-utilised. The characterisation of primary ores, and the optimisation of comminution, flotation, mineral concentration and metallurgical processes in the mining industry by generating quantified data, is still the major application field of SEM automated mineralogy. However, there is interesting potential beyond these classical fields of geometallurgy and metal ore fingerprinting. Slags, pottery and artefacts can be studied in an archeological context for the recognition of provenance and trade pathways; soil, and solid particles of all kinds, are objects in forensic science. SEM automated mineralogy allows new insight in the fields of process chemistry and recycling technology.


Book
Applications of SEM Automated Mineralogy : From Ore Deposits over Processing to Secondary Resource Characterization
Author:
Year: 2021 Publisher: Basel, Switzerland MDPI - Multidisciplinary Digital Publishing Institute

Loading...
Export citation

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Bookmark

Abstract

During the last decade, software developments in Scanning Electron Microscopy (SEM) provoked a notable increase of applications to the study of solid matter. The mineral liberation analysis (MLA) of processed metal ores was an important drive for innovations that led to QEMSCAN, MLA and other software platforms. These combine the assessment of the backscattered electron (BSE) image to the directed steering of the electron beam for energy dispersive spectroscopy (EDS) to automated mineralogy. However, despite a wide distribution of SEM instruments in material research and industry, the potential of SEM automated mineralogy is still under-utilised. The characterisation of primary ores, and the optimisation of comminution, flotation, mineral concentration and metallurgical processes in the mining industry by generating quantified data, is still the major application field of SEM automated mineralogy. However, there is interesting potential beyond these classical fields of geometallurgy and metal ore fingerprinting. Slags, pottery and artefacts can be studied in an archeological context for the recognition of provenance and trade pathways; soil, and solid particles of all kinds, are objects in forensic science. SEM automated mineralogy allows new insight in the fields of process chemistry and recycling technology.

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