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ANIONIC POLYMERIZATION --- POLYMER MORPHOLOGY --- POLYOLEFINS --- ANIONIC POLYMERIZATION --- POLYMER MORPHOLOGY --- POLYOLEFINS

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66.095.26 --- Polymerization --- 66.095.26 Polymerization --- Anionic polymerization --- Cationic polymerization --- Radical polymerization

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The interest in what were known at first as Friedel-Crafts polymerisations started in the 1930s and grew rapidly from the 1940s under the influence of the US Synthetic Rubber Programme and from the 1950s as a result of the Ziegler-Natta and related polymer developments. From 1944 Professor Plesch has spent most of his academic life, studying the nature of what were later called cationic and, more recently still, cationoid polymerisations. The change of generic title reflects the growing insight into these reactions, much of which is due to Professor Plesch and his research group. Because of hi

Addition polymerization. --- Anionic polymerization --- Cationic polymerization --- Chain addition polymerization --- Chain-growth polymerization --- Free-radical polymerization --- Ionic polymerization --- Polymerization

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Polymers --- Polymerization --- Macromolecules --- Molecules --- Supramolecular chemistry --- Polymerisation --- Polymers and polymerization --- Synthesis of polymers --- Chemical reactions --- Polymere --- Polymeride --- Synthesis --- Radicals (Chemistry) --- Anionic polymerization --- Block polymerization --- Catalysis --- Cationic polymerization --- Polymerization, graft --- Stereochemistry

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This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supramolecular assemblies have been created and widely studied and are considered nanodevices in the fields of nanoscience and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.

Organic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Addition polymerization. --- Carbanions. --- Anionic polymerization --- Cationic polymerization --- Chain addition polymerization --- Free-radical polymerization --- Ionic polymerization --- Chemistry. --- Physical chemistry. --- Polymers. --- Nanotechnology. --- Polymer Sciences. --- Physical Chemistry. --- Ions --- Polymerization --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Molecular technology --- Nanoscale technology --- High technology --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Polymers  . --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry