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Organomagnesium methods in organic synthesis
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ISBN: 0127309454 9786611033750 1281033758 0080538177 9780127309453 9780080538174 Year: 1995 Publisher: London ; San Diego : Academic Press,

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Abstract

The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized.The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as

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