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Metal organic frameworks (MOFs) are a class of porous materials with a modular structure. This allows for very wide structural diversity and the possibility of synthesizing materials with tailored properties for advanced applications. Thus, MOF materials are the subject of intense research, with strong relevance to both science and technology. MOFs are formed by the assembly of two components: cluster or metal ion nodes, which are also called secondary building units (SBUs), and organic linkers between the SBUs, usually giving rise to crystalline structures with an open framework and significant porous texture development. The main aim of this Special Issue of Catalysts (ISSN 2073-4344) is to present the most relevant and recent insights in the field of the synthesis and characterization of MOFs and MOF-based materials for advanced applications, including adsorption, gas storage/capture, drug delivery, catalysis, photocatalysis, and/or chemical sensing.

Metal–organic framework --- Lewis acid --- fructose --- 5-hydroxymethyl furfural --- biomass --- Metal-organic frameworks (MOFs) --- photocatalysis --- carbon dioxide reduction --- renewable energy --- heterogeneous catalysis --- metal organic framework --- surface modification --- Zinc glutarate --- CO2 fixation --- polycarbonate --- Mn-MOF-74 --- modification --- water resistance --- NH3-SCR performance --- environmental pollution --- filter --- gas sorption --- sensor --- hydrogen storage --- electrospinning --- one-pot hydrothermal --- immobilizing recombinant --- His-hCA II --- Ni-BTC nanorods --- metal–organic frameworks --- polyoxometalates --- hybrid materials --- synthesis --- catalysis --- heterogeneous catalyst --- aerobic oxidation --- cyclohexene --- metal organic frameworks --- NH2-MIL-125(Ti) --- water stability --- purification --- layered coordination polymer --- oxidative desulfurization --- denitrogenation extraction --- hydrogen peroxide --- lanthanides --- MOF --- catalyst --- microreactor --- kinetic studies --- metal organic frame works --- CO2 adsorption --- pre combustion --- gas membrane separation --- metal halide perovskites --- metal-organic framework --- fuel cell --- oxygen reduction reaction (ORR) --- metal organic frameworks (MOFs) --- hydrothermal synthesis --- coordination polymers --- crystal structures --- metal-organic frameworks --- carboxylate ligands --- olefin paraffin separations --- propyne --- propylene --- adsorption isotherms --- dynamic breakthrough --- n/a --- Metal-organic framework

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The objective of this Special Issue is to provide new contributions in the area of biomass valorization using heterogeneous catalysts and focusing specifically on the structure/activity relationships of specific and important oxidation, hydrogenation, hydrodeoxygenation and biocatalytic processes. The issue emphasizes the influence of the design and morphology of the catalyst, in terms of particle size, redox and acid-base properties and catalyst stability. Finally, mechanistic studies and examples of design and optimization of industrial processes are presented.

Research & information: general --- Technology: general issues --- furfural --- MPV reaction --- acid-base characterization --- methylbutynol test reaction --- Fischer-Tropsch synthesis --- Co/SBA-15 --- pore size --- pore length --- dry gel conversion --- MFI zeolite --- particle sizes --- silica sources --- hydrodeoxygenation --- biocatalysis --- bio-based platform chemicals --- furans --- reduction --- whole cells --- nickel phosphide --- cellobiose --- sorbitol --- MCM-41 --- hydrolytic hydrogenation --- zeolites --- catalysis --- solid acid --- solid base --- chemical modification --- alkylation --- glycosidation --- 2 methyl-furan --- catalyst design --- iron --- magnesium oxide --- catalytic hydrogen transfer reduction --- methanol --- diffusion --- ab initio --- industrial design --- H-ZSM-5 --- multiscale modeling --- adiabatic reactor --- zeolite catalysis --- hydrogenation --- palladium --- nanoparticles --- capping agent --- sol-immobilization --- furoic acid --- gold --- hydrotalcite --- oxidation --- bimetallic nanoparticles --- base-free --- green oxidation --- embedded catalysts --- biomass --- Eucalyptus globulus wood --- cross-flow autohydrolysis --- kinetic modeling --- hemicellulose-derived products --- gold catalysis --- selective oxidation --- colloidal synthesis --- 5-(hydroxymethyl)furfural --- 2,5-furandicarboxylic acid --- particle size --- biomass conversion --- in-situ synthesis --- Sn-Beta zeolite --- isomorphous substitution --- glucose --- HMF --- oxidative condensation --- furan-2-acrolein --- Pd-based catalysts --- furfural --- MPV reaction --- acid-base characterization --- methylbutynol test reaction --- Fischer-Tropsch synthesis --- Co/SBA-15 --- pore size --- pore length --- dry gel conversion --- MFI zeolite --- particle sizes --- silica sources --- hydrodeoxygenation --- biocatalysis --- bio-based platform chemicals --- furans --- reduction --- whole cells --- nickel phosphide --- cellobiose --- sorbitol --- MCM-41 --- hydrolytic hydrogenation --- zeolites --- catalysis --- solid acid --- solid base --- chemical modification --- alkylation --- glycosidation --- 2 methyl-furan --- catalyst design --- iron --- magnesium oxide --- catalytic hydrogen transfer reduction --- methanol --- diffusion --- ab initio --- industrial design --- H-ZSM-5 --- multiscale modeling --- adiabatic reactor --- zeolite catalysis --- hydrogenation --- palladium --- nanoparticles --- capping agent --- sol-immobilization --- furoic acid --- gold --- hydrotalcite --- oxidation --- bimetallic nanoparticles --- base-free --- green oxidation --- embedded catalysts --- biomass --- Eucalyptus globulus wood --- cross-flow autohydrolysis --- kinetic modeling --- hemicellulose-derived products --- gold catalysis --- selective oxidation --- colloidal synthesis --- 5-(hydroxymethyl)furfural --- 2,5-furandicarboxylic acid --- particle size --- biomass conversion --- in-situ synthesis --- Sn-Beta zeolite --- isomorphous substitution --- glucose --- HMF --- oxidative condensation --- furan-2-acrolein --- Pd-based catalysts

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• Reference Manager
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The objective of this Special Issue is to provide new contributions in the area of biomass valorization using heterogeneous catalysts and focusing specifically on the structure/activity relationships of specific and important oxidation, hydrogenation, hydrodeoxygenation and biocatalytic processes. The issue emphasizes the influence of the design and morphology of the catalyst, in terms of particle size, redox and acid-base properties and catalyst stability. Finally, mechanistic studies and examples of design and optimization of industrial processes are presented.

Research & information: general --- Technology: general issues --- furfural --- MPV reaction --- acid–base characterization --- methylbutynol test reaction --- Fischer–Tropsch synthesis --- Co/SBA–15 --- pore size --- pore length --- dry gel conversion --- MFI zeolite --- particle sizes --- silica sources --- hydrodeoxygenation --- biocatalysis --- bio-based platform chemicals --- furans --- reduction --- whole cells --- nickel phosphide --- cellobiose --- sorbitol --- MCM-41 --- hydrolytic hydrogenation --- zeolites --- catalysis --- solid acid --- solid base --- chemical modification --- alkylation --- glycosidation --- 2 methyl-furan --- catalyst design --- iron --- magnesium oxide --- catalytic hydrogen transfer reduction --- methanol --- diffusion --- ab initio --- industrial design --- H-ZSM-5 --- multiscale modeling --- adiabatic reactor --- zeolite catalysis --- hydrogenation --- palladium --- nanoparticles --- capping agent --- sol-immobilization --- furoic acid --- gold --- hydrotalcite --- oxidation --- bimetallic nanoparticles --- base-free --- green oxidation --- embedded catalysts --- biomass --- Eucalyptus globulus wood --- cross-flow autohydrolysis --- kinetic modeling --- hemicellulose-derived products --- gold catalysis --- selective oxidation --- colloidal synthesis --- 5-(hydroxymethyl)furfural --- 2,5-furandicarboxylic acid --- particle size --- biomass conversion --- in-situ synthesis --- Sn-Beta zeolite --- isomorphous substitution --- glucose --- HMF --- oxidative condensation --- furan-2-acrolein --- Pd-based catalysts --- n/a --- acid-base characterization --- Fischer-Tropsch synthesis --- Co/SBA-15