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66.095.7 --- 66.095.7 Reactions involving organometallic compounds. Grignard reactions --- Reactions involving organometallic compounds. Grignard reactions

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Palladium is a remarkable metal. In particular, organopalladium chemistry has made remarkable progress over the last 30 years. That progress is still continuing, without any end in sight. This book presents a number of accounts and reviews on the novel Pd-catalyzed reactions discovered mainly in the last five years. The book covers Pd-catalyzed reactions that are new – entirely different from the more standard ones. Topics such as new reactions involving ß-carbon elimination and formation of palladacycles as key reactions, cross-coupling of unactivated alkyl electrophiles with organometallic compounds, arylation via C-H bond cleavage, Pd/norbornene-catalyzed aromatic functionalizations, three-component cyclizations of allenes, use of N-heterocyclic carbenes as ligands, asymmetric reactions catalyzed by Pd(II) compounds such as Lewis acids, cycloadditions of arynes and alkynes, and nucleophilic attack by Pd species are surveyed in detail by researchers who have made important contributions to these fields. The book addresses graduate students majoring in organic synthesis and researchers in academic and industrial institutes.

Palladium. --- Organic compounds --- Composés organiques --- Synthesis. --- Synthèse --- Chemistry. --- Chemistry, inorganic. --- Chemistry, Organic. --- Biochemistry. --- Catalysis. --- Organometallic Chemistry. --- Inorganic Chemistry. --- Medicinal Chemistry. --- Palladium --- Organic Chemistry --- Inorganic Chemistry --- Chemistry --- Physical Sciences & Mathematics --- Synthesis --- 66.095.7 --- 546.98 --- -Compounds, Organic --- Organic chemicals --- Carbon compounds --- Reactions involving organometallic compounds. Grignard reactions --- -Reactions involving organometallic compounds. Grignard reactions --- 546.98 Palladium --- 66.095.7 Reactions involving organometallic compounds. Grignard reactions --- -546.98 Palladium --- Compounds, Organic --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Organic chemistry --- Inorganic chemistry --- Composition --- Inorganic chemistry. --- Organometallic chemistry. --- Medicinal chemistry. --- Platinum group --- Chemistry, Organic --- Chemistry, Synthetic organic --- Organic synthesis (Chemistry) --- Synthetic organic chemistry --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Biology --- Medical sciences --- Inorganic compounds --- Organometallic chemistry . --- Chemistry, Medical and pharmaceutical --- Chemistry, Pharmaceutical --- Drug chemistry --- Drugs --- Medical chemistry --- Medicinal chemistry --- Pharmacochemistry --- Chemistry, Organometallic --- Metallo-organic chemistry

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Bioorganometallic Chemistry has become a mature area of science and is comprehensively covered by leading experts in this book. Naturally occuring bioorganometallic complexes, such as vitamin B12 and recently discovered iron and nickel hydrogenases, including a possible role of the latter in the geochemical theory of the origin of life, are considered. The possible formation of carbene complexes of cytochrome P450 enzymes in various metabolisms of xenobiotics is also discussed. The bioorganometallic chemistry is considered to provide not only organometallic receptors such as polynuclear organometallic macrocycles for biologically interesting molecules but also ferrocene-peptide bioconjugates giving a peptidomimetic basis for protein folding. The medicinal properties of organometallic compounds are reviewed, with notable applications in the treatment and diagnosis of cancer and in the treatment of viral, fungal, bacterial and parasitic infections. Therefore the reader will get a balanced view of this rapidly developing and promising area.

Bioorganic chemistry. --- Organometallic chemistry. --- Chimie bioorganique --- Chimie organométallique --- Chemistry. --- Chemistry, inorganic. --- Chemistry, Organic. --- Biochemistry. --- Catalysis. --- Organometallic Chemistry. --- Inorganic Chemistry. --- Biochemistry, general. --- Medicinal Chemistry. --- Organometallic compounds --- Biochemistry --- Organometallic Compounds --- Organic Chemicals --- Inorganic Chemicals --- Chemicals and Drugs --- Organic Chemistry --- Animal Biochemistry --- Chemistry --- Human Anatomy & Physiology --- Health & Biological Sciences --- Physical Sciences & Mathematics --- 66.095.7 --- Reactions involving organometallic compounds. Grignard reactions --- 66.095.7 Reactions involving organometallic compounds. Grignard reactions --- Chemicals, Organic --- Metalloorganic Compounds --- Metallo-Organic Compounds --- Compounds, Metallo-Organic --- Compounds, Metalloorganic --- Compounds, Organometallic --- Metallo Organic Compounds --- Chemicals, Inorganic --- Metallo-organic compounds --- Metalloids, Organic --- Metalorganic compounds --- Organometalloids --- Biological chemistry --- Chemical composition of organisms --- Organisms --- Physiological chemistry --- Organic chemistry --- Inorganic chemistry --- Composition --- Inorganic chemistry. --- Medicinal chemistry. --- Organic compounds --- Biology --- Medical sciences --- Activation (Chemistry) --- Chemistry, Physical and theoretical --- Surface chemistry --- Inorganic compounds --- Organometallic chemistry . --- Chemistry, Medical and pharmaceutical --- Chemistry, Pharmaceutical --- Drug chemistry --- Drugs --- Medical chemistry --- Medicinal chemistry --- Pharmacochemistry --- Chemistry, Organometallic --- Metallo-organic chemistry --- Chemistry, Organic