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Book
Colloids and the depletion interaction
Authors: ---
ISBN: 9400712227 9400712235 Year: 2011 Publisher: Dordrecht : Springer,

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Abstract

Colloids are submicron particles that are ubiquitous in nature (milk, clay, blood) and industrial products (paints, drilling fluids, food). It has been known for a long time that adding salt or polymer influences the characteristics of colloidal suspensions. Think of the Egyptians who engineered ink by adding gum Arabic to soot particles a few thousand years ago. Unknowingly, they were taking advantage of the anchoring of the polysaccharides onto the colloids to provide the stabilization of the soot particles that eventually provided an ink to write on papyrus. The effect of charges and polymers attached to the surface of colloidal particles on their stability has been understood and studied extensively in the last century. But the more elusive, albeit ubiquitous, effects of the addition of free polymers and small colloids as depletants to colloidal dispersions have become in focus recently. In recent decades it has become clear that adding such depletants allows one to tune the interactions between the colloids and in this way control the stability, structure and rheological properties of colloidal dispersions. This book offers a concise introduction to the fundamentals of depletion effects and their influence on the phase behavior of colloidal dispersions. These fundamental principles promote insight and the intuitive sense needed to isolate issues related to depletion effects in technological problems and design critical experiments. In an introductory chapter, the authors provide a historical perspective and the applications of depletion effects not only in colloid science but also in biology, medicine and technology. In the subsequent chapter they address the basics of depletion interactions, including the effects of anisotropic depletants. The next chapter covers the basics of phase behavior in colloidal dispersions, followed by extensions towards mixtures of spherical colloids with polymers or small colloids inducing depletion forces. Finally, the authors consider depletion effects in suspensions of rod-like colloids. Throughout the book, conceptual explanations are accompanied by experimental and computer simulation results. This is an ideal book for advanced undergraduates and graduate students in physical chemistry, chemical engineering and soft matter physics. It provides the basic knowledge of depletion interactions and phase behaviour in general. Experienced scientists and engineers working on polymers, particles or colloidal dispersions, may also find this book useful.

Keywords

Colloids --- Surface chemistry --- Chemical & Materials Engineering --- Physics --- Engineering & Applied Sciences --- Physical Sciences & Mathematics --- Chemical Engineering --- Atomic Physics --- Colloids. --- Dispersoids --- Gels --- Hydrogels --- Sols --- Physics. --- Physical chemistry. --- Polymers. --- Thermodynamics. --- Amorphous substances. --- Complex fluids. --- Materials --- Thin films. --- Soft and Granular Matter, Complex Fluids and Microfluidics. --- Polymer Sciences. --- Surfaces and Interfaces, Thin Films. --- Physical Chemistry. --- Surfaces. --- Films, Thin --- Solid film --- Solid state electronics --- Solids --- Surfaces (Technology) --- Coatings --- Thick films --- Surface phenomena --- Friction --- Surfaces (Physics) --- Tribology --- Complex liquids --- Fluids, Complex --- Amorphous substances --- Liquids --- Chemistry, Physical and theoretical --- Dynamics --- Mechanics --- Heat --- Heat-engines --- Quantum theory --- Polymere --- Polymeride --- Polymers and polymerization --- Macromolecules --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Natural philosophy --- Philosophy, Natural --- Physical sciences --- Surfaces --- Diffusion --- Matter --- Micelles --- Particles --- Rheology --- Solution (Chemistry) --- Properties --- Surfaces (Physics). --- Chemistry, Physical organic. --- Chemistry, Physical organic --- Chemistry, Organic --- Polymers  . --- Materials—Surfaces. --- Soft condensed matter


Digital
Colloids and the Depletion Interaction
Authors: ---
ISBN: 9789400712232 Year: 2011 Publisher: Dordrecht Springer Netherlands

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Book
Colloids and the Depletion Interaction
Authors: --- ---
ISBN: 9789400712232 9789400712225 Year: 2011 Publisher: Dordrecht Springer Netherlands

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Abstract

Colloids are submicron particles that are ubiquitous in nature (milk, clay, blood) and industrial products (paints, drilling fluids, food). It has been known for a long time that adding salt or polymer influences the characteristics of colloidal suspensions. Think of the Egyptians who engineered ink by adding gum Arabic to soot particles a few thousand years ago. Unknowingly, they were taking advantage of the anchoring of the polysaccharides onto the colloids to provide the stabilization of the soot particles that eventually provided an ink to write on papyrus. The effect of charges and polymers attached to the surface of colloidal particles on their stability has been understood and studied extensively in the last century. But the more elusive, albeit ubiquitous, effects of the addition of free polymers and small colloids as depletants to colloidal dispersions have become in focus recently. In recent decades it has become clear that adding such depletants allows one to tune the interactions between the colloids and in this way control the stability, structure and rheological properties of colloidal dispersions. This book offers a concise introduction to the fundamentals of depletion effects and their influence on the phase behavior of colloidal dispersions. These fundamental principles promote insight and the intuitive sense needed to isolate issues related to depletion effects in technological problems and design critical experiments. In an introductory chapter, the authors provide a historical perspective and the applications of depletion effects not only in colloid science but also in biology, medicine and technology. In the subsequent chapter they address the basics of depletion interactions, including the effects of anisotropic depletants.  The next chapter covers the basics of phase behavior in colloidal dispersions, followed by extensions towards mixtures of spherical colloids with polymers or small colloids inducing depletion forces. Finally, the authors consider depletion effects in suspensions of rod-like colloids. Throughout the book, conceptual explanations are accompanied by experimental and computer simulation results. This is an ideal book for advanced undergraduates and graduate students in physical chemistry, chemical engineering and soft matter physics. It provides the basic knowledge of depletion interactions and phase behaviour in general. Experienced scientists and engineers working on polymers, particles or colloidal dispersions, may also find this book useful.


Book
Colloids and the Depletion Interaction
Authors: --- ---
ISBN: 3031521315 Year: 2024 Publisher: Cham : Springer International Publishing : Imprint: Springer,

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Abstract

This open access book provides a detailed exploration of the phase behaviour of, and interfacial properties in, complex colloidal mixtures (e.g., clay, milk, blood). Insights into colloids have been at the heart of many innovations in different industries. The big question underlying these innovations is how can colloidal systems be formulated and designed towards the desired properties? To do this, the forces between the colloidal particles need to be controlled. Adding depletants (non-adsorbing polymers or small colloids) is key to controlling the attractive interactions. Colloids and the Depletion Interaction provides the qualitative insights and quantitative tools to understand and predict such forces in colloidal dispersions. It offers a concise introduction to the history and fundamentals of the depletion interaction in, and phase behaviour of, colloidal dispersions. Why does adding polymers lead to attractive forces between colloidal particles? What determines the phase stability of multi-component colloidal systems? These include colloid—polymer mixtures, binary colloidal mixtures, and anisotropic particles such as clay platelets, cubes and rod-like viruses. Conceptual explanations are accompanied by experimental and computer simulation results throughout. Illustrations of depletion effects in colloid science, biology and technology demonstrate its wider significance. The concluding outlook provides the scope of challenges and possibilities in this exciting field of science. This second updated and enlarged edition contains 12 Chapters. It is an ideal book for advanced undergraduates and graduate students in physical chemistry, chemical engineering and soft matter physics. Besides providing a fundamental understanding of depletion interactions in colloidal mixtures, it gives background information on colloidal stability and phase behaviour in general. For experienced scientists and engineers working on mixtures of colloids and non-adsorbing (bio)polymers or colloidal particles, this book serves as a reference for understanding depletion interactions in systems of their specific interest.


Book
Polymer coatings : a guide to chemistry, characterization, and selected applications
Authors: --- --- --- --- --- et al.
ISBN: 9783527342105 9783527806317 9783527806324 Year: 2018 Publisher: Weinheim : Wiley-VCH,

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"Polymer Coatings" is a practical resource that offers an overview of the fundamentals to the synthesis, characterization, deposition methods, and recent developments of polymer coatings. The text includes information about the different polymers and polymer networks in use, resins for solvent- and water-based coatings, and a variety of additives. It presents deposition methods that encompass frequently used mechanical and electrochemical approaches, in addition to the physical-chemical aspects of the coating process. The author covers the available characterization methods including spectroscopic, morphological, thermal and mechanical techniques.The comprehensive text also reviews developments in selected technology areas such as electrically conductive, anti-fouling, and self-replenishing coatings. The author includes insight into the present status of the research field, describes systems currently under investigation, and draws our attention to yet to be explored systems

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