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Two Studies in Gas-Phase Ion Spectroscopy : Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics
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ISBN: 3642231284 9786613450852 1283450852 3642231292 Year: 2012 Publisher: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer,

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Abstract

In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules.  The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals.


Digital
Two Studies in Gas-Phase Ion Spectroscopy : Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics
Author:
ISBN: 9783642231292 Year: 2012 Publisher: Berlin, Heidelberg Springer Berlin Heidelberg

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Abstract


Book
Two Studies in Gas-Phase Ion Spectroscopy : Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics
Authors: ---
ISBN: 9783642231292 Year: 2012 Publisher: Berlin Heidelberg Springer Berlin Heidelberg

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Export citation

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Bookmark

Abstract

In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules.  The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals.

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