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The aim of this volume is to offer a balanced overview of molecular Rydberg spectroscopy as it has developed over recent decades. Recent evolution has split Rydberg spectroscopy into two apparently distinct fields: the one concerns the low (n=3-5) Rydberg states, the other the very high (typically n>150) Rydberg states. The former is aimed at spectral levels where Rydberg, valence-shell, and intermediate-type states interact, with a variety of photochemical consequences. The latter considers states extremely close to the ionization limit, from whereionization is possible with a very slight amount of additional energy. Recently developed techniques make it possible to produce ions in well-defined electronic, vibrational and rotational states, including states resulting from spin-orbit or Jahn-Teller splitting. It is then possible to study the structure and reactions of such state-selected ions as well as those of the corresponding neutral molecules. These techniques amount to badly needed high resolution photoelectron spectroscopy.

Rydberg states. --- Spectrum analysis --- Photochemistry --- High resolution spectroscopy --- Technique. --- Chemistry, Physical organic. --- Physical Chemistry. --- Atomic, Molecular, Optical and Plasma Physics. --- Astrophysics and Astroparticles. --- Physical chemistry. --- Atoms. --- Physics. --- Astrophysics. --- Astronomical physics --- Astronomy --- Cosmic physics --- Physics --- Natural philosophy --- Philosophy, Natural --- Physical sciences --- Dynamics --- Chemistry, Physical and theoretical --- Matter --- Stereochemistry --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Constitution --- Spectroscopy, High resolution --- Resolution (Optics) --- Analysis, Spectrum --- Spectra --- Spectrochemical analysis --- Spectrochemistry --- Spectrometry --- Spectroscopy --- Analytical chemistry --- Interferometry --- Optics --- Radiation --- Wave-motion, Theory of --- Absorption spectra --- Light --- Spectroscope --- Rydberg atoms --- Rydberg series --- Atomic spectra --- Energy levels (Quantum mechanics) --- Qualitative

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CHEMISTRY, PHYSICAL AND THEORETICAL --- SPECTRUM ANALYSIS

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Photochemistry --- Vacuum ultraviolet spectroscopy --- Quantum chemistry --- Photochimie --- Spectroscopie ultraviolette sous vide --- Chimie quantique --- Congresses --- Congrès --- 541.14 <063> --- -Quantum chemistry --- -Vacuum ultraviolet spectroscopy --- -Far ultraviolet spectroscopy --- Ultraviolet spectroscopy --- Chemistry, Quantum --- Chemistry, Physical and theoretical --- Quantum theory --- Excited state chemistry --- Light --- Photolysis (Chemistry) --- Photochemistry--Congressen --- Chemical action --- -Photochemistry--Congressen --- 541.14 <063> Photochemistry--Congressen --- Congrès --- Far ultraviolet spectroscopy --- Molecular orbitals. --- Optical properties. --- Radicals (Chemistry) --- Circular dichroism --- Fragmentation reaction --- Photoelectron spectra --- Photoionization --- Quantum transition