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Decreasing high ore grade deposits have exposed the need of processing more and more low grade, complex, not fully liberated and finely disseminated ores or even “urban mine” wastes, moreover combined with increasing comminution inefficiency in reducing particle size of conventional tumbling mills, have delivered the necessity to find distinct process or technology ensuring full liberation of minerals of interest. A new technology has been gaining popularity widely accepted in the last few decades, resulting in superior energy utilization and efficiency. The technology is known as stirrer mills, which are widely used for fine and ultrafine grinding (Gupta and Yan 2016). The present study is emphasized on the influence and the effect ultrafine grinding obtained from regrinding with RoStarMill® upon downstream processes, such as flotation. Further evaluation and modelling of bulk concentrate flotation performance in order to find out, understand and provide guidelines for floating ultrafine particles at Assarel beneficiation plant is targeted. Mineralogical characterization (Optical microscopy and SEM-ZEISS MINERALOGIC) and granulometry studies have been available for the bulk concentrate and RoStar output at 1 and 3 minutes. In order to replicate RoStar mill output (particle size distribution) a Magotteaux Mill® was implemented during the research work. All comminution and flotation experiments have been executed at the Research Laboratory of Mineral Processing in University of Liege in batch mode by using Magotteaux Mill® and Magottaux float cell™. The effect of specific energy input on Magotteaux mill performance was monitored and recorded, but it cannot be compared with RoStarMill®, prototype and pilot RoStarMill® are situated in TU Bergakademie Freiberg. In this study, flotation response was investigated by changing variety of parameters such as regrinding time, reagent consumption, and hydrodynamic conditions in the cell. Additionally, flotation trials were carried out separately with initial classification and separation of flotation feed to distinguish fine and ultrafine particle size classes via lab scale hydrocyclone (cut size 20 µm). Flotation response in terms of recovery are in the range of 75.1 to 84.5 % indicating that ultrafine particles float relatively easy at certain conditions, such as increased agitation and flotation time, intensive mixing, higher turbulence conditions in the cell and required dosage of collector (xanthate), but may lead to raising of collector addition. Moreover, regrinding with RoStar Mill shows improved liberation of chalcopyrite to 31.9 % after 1 min and 42.1 % after 3 min of regrinding respectively. Further test work is suggested to be carried out at Assarel mine site, after delivering containerized pilot plant of MMS RoStar to proceed with investigation of flotation response directly from RoStar output.
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The transportation sector is going through a big technological change and electronic mobile devices and vehicles are becoming increasingly important contributors to decrease the environmental impacts caused by the tailpipe emissions of internal combustion vehicles. Lithium-ion batteries (LIBs) are often used as electrochemical energy storage devices in powering electric transport systems. However, the increasing rate of production of LIBs is not followed by the rate of recycling. Moreover, the currently established processes are facing losses. The present study is based on the analysis of four battery modules of stand-up scooters. The investigations started by the pretreatment stage, where the e-scooters and battery modules were dismantled manually, followed by the depollution, conducted by discharging in a salt solution. As part of the processing stage, liberation included a single-stage size reduction using a cutting mill and separation using vibrational sieving with a set of custom sorting sieves. In addition, the liberation of the battery cells and pre-shredded material were tested using electric pulse fragmentation and attrition water washing. After shredding and sieving, on the generated mid and fine size fractions, microscopic investigations and chemical analysis were conducted. By chemical analysis, the segregation of the high-value materials to the fine size fractions was investigated. For microscopical investigations, optical and scanning electron microscopy (SEM) was employed, to analyze the relationship and liberation of the current collector foils and their active materials. Quantitative image analysis by segmentation and thresholding has been done using a collection of machine learning algorithms. The chemical analysis results were compared with the quantitative image analysis results. The development of lithium-ion batteries recycling has been industry-driven, unlike the development of new lithium-ion batteries, which are considering mainly the manufacturing cost and performance, without implementing strategies such as Design for Recycling (DfR). To develop efficient large-scale economical recycling facilities, battery researchers and manufacturers must focus more on improving the recyclability of lithium-ion batteries.
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